目錄
摘要 I
Abstract II
致謝 IV
目錄 VI
表目錄 XI
圖目錄 XIII
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
1.3 研究目的 3
1.4 研究範圍 3
第二章 文獻回顧 4
2.1 瀝青材料 4
2.1.1 瀝青物理性質 4
2.1.2 瀝青化學性質 5
2.1.3 瀝青化學型態組成成分 7
2.2 瀝青膠漿 10
2.2.1 礦物填充料 10
2.2.2 填充料SSA對瀝青膠漿性能之影響 11
2.2.3 填充料對瀝青膠漿加勁性能之影響 12
2.3 高爐石 15
2.3.1 水淬高爐石粉物理性質 16
2.3.2 水淬高爐石粉活性指數 17
2.3.3 水淬高爐石粉化學性質 17
2.4 瀝青質流性質 19
2.4.1 質流學 19
2.4.2 動態剪切質流儀(Dynamic Shear Rheometer, DSR) 20
2.4.3 質流參數分析 22
2.4.4 時間-溫度疊加原理 23
2.4.5 主曲線的建構與平移因子 24
2.4.6 黏彈性質流模型 26
2.5 多重應力潛變恢復試驗(Multiple stress creep recovery test) 28
2.5.1 MSCR評估瀝青等級 32
2.5.2 MSCR標準曲線 33
2.6 線性振幅掃描試驗(Linear Amplitude Sweep test) 34
2.6.1 VECD黏彈性損傷理論 36
2.6.2 LAS小結 43
2.7 接觸角(Contact Angle) 44
2.7.1 表面自由能(Surface Free Energy) 46
2.7.2 小結 52
第三章 研究計劃 55
3.1 研究方法 55
3.2 研究架構與流程 56
3.3 試驗材料性質與規範 58
3.3.1 基底瀝青 58
3.3.2 礦物填充料 59
3.4 試驗拌合與編碼 60
3.4.1 膠漿拌合 60
3.4.2 試體編號 61
3.5 填充料物性試驗及設備 62
3.5.1 比重試驗 62
3.5.2 比表面積試驗 64
3.6 瀝青物性試驗及設備 66
3.6.1 軟化點試驗 66
3.6.2 Brookfield黏滯度試驗 67
3.7 瀝青質流試驗及設備 70
3.7.1 頻率掃描試驗 70
3.7.2 多重應力潛變恢復試驗(MSCR) 72
3.7.3 線性振幅掃描(LAS) 74
3.8 接觸角試驗及設備 76
第四章 試驗結果與分析 78
4.1 瀝青基本性質 78
4.2 填充料物性試驗 78
4.3 瀝青物性試驗 80
4.3.1 軟化點試驗 80
4.3.2 黏滯度試驗 81
4.4 瀝青質流試驗 85
4.4.1 頻率掃描試驗(FS) 85
4.4.2 Superpave車轍參數（| G * |/sinδ） 88
4.4.3 Superpave疲勞參數（| G * |·sinδ） 89
4.5 多重應力潛變恢復試驗(MSCR) 90
4.5.1 不可恢復潛變柔度 90
4.5.2 恢復率 91
4.5.3 累積應變率 93
4.5.4 MSCR標準曲線 94
4.6 線性振幅掃描試驗(LAS) 95
4.6.1 10hz下疲勞性能 96
4.6.2 1.6hz下疲勞性能 109
4.6.3 10hz與1.6hz下應變水平2.5%與5%疲勞壽命之比較 122
4.6.4 小結 123
4.7 質流參數相關性分析 124
4.7.1 軟化點、黏滯度與Jnr相關性 124
4.7.2 Jnr、R、黏滯度與Nf相關性 125
4.8 瀝青接觸角試驗 128
4.8.1 接觸角顯著性分析 130
第五章 結論與建議 131
5.1 結論 131
5.2 建議 133
參考文獻 134
附錄一 動黏滯度試驗結果 143
附錄二 線性振幅掃描測試參數 147
附錄三 口試委員審查建議與說明對照表 149

中華民國國家標準(2010)。瀝青軟化點試驗法，CNS 2486。
中華民國國家標準(2015)。無填充料瀝青黏度測定法，CNS 14186。
中國鋼鐵公司(2002)。「爐石利用推廣手冊」。
台灣鋼鐵工業同業公會(2019)。「台灣鋼鐵工業使手冊」。
翁浚誠(2020)。水淬爐石粉瀝青膠漿之質流性研究(碩士論文)。國立高雄科技大學營建工程研究所。
蔡長展(2002)。瀝青流變行為對鋪面車轍變形之影響(博士論文)。國立成功大學土木工程研究所。
蔡攀鰲(1984)。瀝青混凝土材料試驗與配合設計。三民書局。
AASHTO T 315-10. (2010). Determining the Rheological Properties of Asphalt Binder Using a Dynamic Shear Rheometer(DSR).
AASHTO TP101-12. (2018). Standard Method of Test for Estimating Fatigue Resistance of Asphalt Binders Using Cheng Linear Amplitude Sweep.
AASHTO M332. (2014). Standard Specification for Performance-Graded Asphalt Binder Using Multiple Stress Creep Recovery (MSCR) Test.
ASTM D7405-20. (2020). Multiple Stress Creep and Recovery (MSCR) of Asphalt Binder Using a Dynamic Shear Rheometer.
ASTM D242. (2019). Standard Specification for Mineral Filler for Asphalt Mixtures.
ASTM D3381/D3381M. (2018). Viscosity-Graded Asphalt Binder for Use in Pavement Construction.
Ameri, M., Nowbakht, S., Molayem, M., & Mirabimoghaddam, M.H. (2016). A study on fatigue modeling of hot mix asphalt mixtures based on the viscoelastic continuum damage properties of asphalt binder. Construction and Building Materials, Vol.106, P.243-252.
Alhaddad, A.H.A. (2018). Predicted Fatigue Performance of Modified Asphalt Binder Using Linear Amplitude Sweep. 4th Conference of the Middle East Society of Asphalt Technologists.
Anderson, D., Martin, D., Planche, J.P., & Gauthier, G. (2001). Evaluation of Fatigue Criteria for Asphalt Binders. Transportation Research Record Journal of the Transportation Research Board 1766, P.48-56.
Anderson, D. A., & Goetz, W.H. (1973). Machanical behavior and reinforcement of mineral filler-asphalt mixtures. JTRP Technical Reports, Vol.42, P.37-66.
Anderson, D.A., Christensen, D.W., Bahia, H.U., Dongre, R., Sharma, M.G., Antle, C.E., & Button, J. (1994). Binder Characterization and Evaluation Volume 3: Physical Characterization. Strategic Highway Research Program, SHRP-A-369.
Arshad, A.K., Samsudin, S., & Masri, K.A. (2017). Multiple Stress Creep and Recovery of Nanosilica Modified Asphalt Binder. MATEC Web of Conferences, Vol.103, P.01-08.
Aschenbrener, T. (2003). Moisture Sensitivity of Asphalt Pavements. Transportation Research Board.
Apeagyei, A., Grenfell, J., & Airey, G.D. (2014). Moisture-Induced Strength Degradation of Aggregate-Asphalt Mastic Bonds. Road Materials and Pavement Design, P.239-262.
Alhaddad, A.H.A. (2015). Construction of a Complex Shear Modulus Master Curve for Iraqi Asphalt Binder using a Modified Sigmoidal Fitting. International Journal of Scientific Engineering and Techology Research, Vol.04, P.682-690.
Branthaver, J.F., Petersen, J.C., Robertson, R.E., & Duvall, J.J. (1993). Binder Characteriza And Evaluation. Strategic Highway Research Program, Vol.2.
Buttlar, G. W., Bozkurt, D., Al-Khateeb, G.G., & Waldhoff, A.S. (1999). Understanding Asphalt Mastic Behavior Through Micromechanics. Transportation Research Board, Issue1681, P.157-169.
Bhat, F., & Mir, M.S. (2020). Rheological investigation of asphalt binder modified with nanosilica. International Journal of Pavement Research and Technology,Vol.14, P.276-287.
Bahia, H.U., Hanson, D.I., Zeng, M., Zhai, H., & Khatri, M.A. (2001). NCHRP Report 459:Characterization of modified asphalt binders in superpave mix design. Transportation Research Board, P.01-53.
Carreau, P. J., & Bousmina, M. (2009). The viscoelastic properties of polymer‐modified asphalts. The Canadian Journal of Chemical Engineering ,Vol.78, Issue 3.
Cheng, Y., Tao, J., Jiao, Y., Tan, G., Guo, Q., Wang, S., & Ni, P. (2016). Influence of the properties of filler on high and medium temperature performances of asphalt mastic. Construction and Building Materials, Vol.118, P.268-275.
Chang, X., Wang, J., Zhang, X., Liu, H., Tong, J., & Zhao, R. (2020). Evaluating the Physical and Rheological Properties of Rejuvenated Styrene-Butadiene-Styrene-Modified Asphalt Binders. Advances in Materials Science and Engineering, Vol.2020, P.01-14.
Colak, A. (2002). The long-term durability performance of gypsum–Portland cement–natural pozzolan blends,” Cement and Concrete Research, Vol.32, P.109-115.
D'Angelo, J., Robert, K., Raj, D., Keith, S., & Ludo, Z. (2007). Revision of the Superpave High Temperature Binder Specification: The Multiple Stress Creep Recovery Test. Journal of the Association of Asphalt Paving Technologists, Vol.76.
Gue, M., Tan, Y., Yu, J., Hou, Y., & Wang, L. (2017). A direct characterization of interfacial interaction between asphalt binder and mineral fillers by atomic force microscopy. Materials and Structures, Vol.50, P.01-11.
Ghabchi, R., Singh, D., Zaman, M., & Tian, Q. (2013). Application of Asphalt-aggregates Interfacial Energies to Evaluate Moisture-induced Damage of Warm Mix Asphalt. Social and Behavioral Sciences, Vol.104, P.29-38.
Gabriel, J., Ouintana, H.A.R., & Farias, M.M.D. (2020). Behavior of asphalt mastics containing different materials as filler. Canadian Journal of Civil Engineering, Vol.48, P.01-41.
Gundla, A., Campillo, J.R.M., Gudipudi, P., Stevens, R., Salim, R., Zeiada, W., & Underwood, S. (2016). Investigation of Aging in Hydrated Lime and Portland Cement Modified Asphalt Concrete at Multiple Length Scales. Journal of Materials in Civil Engineering, Vol.28 , P.01-10.
Giustozzi, F., Mansour, K., Patti, F., Pannirselvam, M., & Fiori, F. (2018). Shear rheology and microstructure of mining material-bitumen composites as filler replacement in asphalt mastics. Construction and Building Materials, Vol.171, P.726-735.
Holy, M., & Remisova, E. (2019). Analysis of influence of bitumen composition on the properties represented by empirical andviscosity test,” Transportation Research Procedia, Vol.40, P.34-41.
Hermadi, M. (2013). Developing New Chemical-Rheologocal Models And Chemical-Durability Indices Of Bitumen. Materials of engineering and construction.
Hintz, C., & Bahia, H. (2012). Understanding mechanisms leading to asphalt binder fatigue in the dynamic shear rheometer. Road Materials and Pavement Design, Vol.14, P.231-251.
Han, S., Dong, S., Yin, Y., Liu, M., & Liu, Y. (2020). Study on the effect of hydrated lime content and fineness on asphalt properties. Construction and Building Materials, Vol.244, P.01-009.
Hashminejad, N., Vuye, C., Margaritis, A., & Dirckx, J. (2019). Characterizing the Complex Modulus of Asphalt Concrete Using a Scanning Laser Doppler Vibrometer. Materials (Basel), Vol.21.
Huang, J., Xing, X., Cai, J., Pei, J., Li, R., & Wen, Y. (2019). Utilization of water-quenching blast furnace slag as alternative filler in asphalt mastic. Canadian Journal of Civil Engineering, Vol.47, P.01-37.
Jattak, Z. A., Hassan, N.A., Shukry, N.A.M., & Yunus, N.Z.M. (2019). Characterization of industrial by-products as asphalt paving material. Earth and Environmental Science, Vol.220, P.01-09.
Kong, X., Zhao, J., Zhang, L.J., Liang, Z., & Wang, J. (2018). Design, Synthesis and Characterization of Bitumen Emulsifiers Based on Molecular Simulation. Chemical Engineering and Environmental Engineering, Vol.68, P.01-06.
Kakade, V. B., Reddy, M.A., & Reddy, K.S. (2018). Rutting performance of hydrated lime modified bituminous mixes. Construction and Building Materials, Vol.186, P.01-10.
Klinsky, L.M.G., Bardini, V.S.D.S., & Faria, V.C.D. (2020). Evaluation of permanent deformation of asphalt rubber using multiple stress creep recovery tests and flow numbertests. Transportes, Vol.28, P.01-11.
Kim, H.H., Mazumder, M., Lee, M.S., & Lee, S.J. (2019). Evaluation of High-Performance Asphalt Binders Modified with SBS, SIS, and GTR. Advances in Civil Engineering, Vol.2019.
Kim, Y., Lee, H.J., & Little, D. (2006). A simple testing method to evaluate fatigue fracture and damage performance of asphalt mixtures. Asphalt Paving Technology, Vol.75, P.755-788.
Kuchiishi, K., Bessa, I., Carvalho, J.P.B., & Vasconcelos, K. (2019). Effect of temperature on the fatigue behavior of asphalt binder, Vol.29, P.30-40.
Kieiziene, R., Paliukaite, M., & Vaitkus, A. (2020). Effect of Nano SiO2, TiO2and ZnO Modification to Rheological Properties of Neat and Polymer Modified Bitumen. Proceedings of the 5th International Symposium on Asphalt Pavements & Environment (APE).
Lesueur, D. (2009). The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification. Advances in Colloid and Interface Science, Vol.145, P.42-82.
Liao, M. C., Airey, G., & Chen, J.S. (2013). Mechanical Properties of Filler-Asphalt Mastics. International Journal of Pavement Research and Technology, Vol.6, P.576-581.
Liu, H., Luo, R., Xi, L., & Hu, L. (2020). Development of Two-Step Secant Method to Interpret the Flow Number Test Data of Asphalt Mixtures. Journal of Materials in Civil Engineering, Vol.32, Issue4.
Liao, M.C. (2007). Small and Large Strain Rheological and Fatigue Characterisation of Bitumen-Filler Mastics[Doctoral dissertation]. The University of Nottingham thesis.
Laukkanen, O.V., & Soenen, H. (2015). Rheological characterization of wax modified bituminous binders: Effect of specimen preparation and thermal history. Construction and Building Materials, Vol.95, P.269-278.
Mirhosseini, A.F., Khabiri, M.M., Kavussi, A., & Kamali, M.H.J. (2016). Applying surface free energy method for evaluation of moisture damage in asphalt mixtures containing date seed ash. Construction and Building Materials, Vol.125, P.408-416.
Miró, R., Martínez, A., Botella, R., & Alvarez, A. (2016). Effect of filler nature and content on the bituminous mastic behaviour under cyclic loads. Construction and Building Materials, Vol.132, P.33-42.
Mohsen, A.E., & Basij, J. (2017). The effect of BOFS and GGBFS on the mechanical properties of RCCP. Road Materials and Pavement Design, Vol.20, P.479-489.
Moya, J.P., Delgado, J.S., Sevilla, A.B., Villacorta, F.L., & Salazar, L. (2015). Effect of Aging on Adhesion Properties of Asphalt Mixtures with the Use of Bitumen Bond Strength and Surface Energy Measurement Tests. Transportation Research Record Journal of the Transportation Research Board, Vol.2505, P.57-65.
Masad, E., Somadevan, N., & Bahia, H. (2001). Modeling and Experimental Measurements of Strain Distribution in Asphalt Mixes. Journal of Transportation Engineering, Vol.127, P.477-485.
National Cooperative Highway Research Program (NCHRP). (2017). Relationship Between Chemical Makeup of Binders and Engineering Performance. A Synthesis of Highway Practice– SYNTHESIS 511.
Norouzi, A., Sabouri, M., & Kim, Y.R. (2016). Fatigue life and endurance limit prediction of asphalt mixtures using energy-based failure criterion. International Journal of Pavement Engineering, P.990-1003.
Oss, C. J. V., Chaudhury, M.K., & Good, R. J. (1988). Interfacial Lifshitz-van der Waals and polar interactions in macroscopic systems. American Chemical Society, Vol.88.
Petersen, J.C. (1984). Chemical Composition of Asphalt as Related to Asphalt Durability: State of the Art. Transportation Research Record 999, Vol.40 , P.13-40.
Pereira, A., Micaelo, R., Quaresma, L., & Cidase, M.T. (2016). Evaluation of different methods for the estimation of the bitumen fatigue life with DSR testing. RILEM Bookseries.
Poel, C.V.D. (1954). A general system describing the viscoelastic properties of bitumen and its relation to routine test data. Journal of Applied Chemistry, Vol.4, p.221–236.
Rochlani, M., Leischner, S., Falla, G. C., Wang, D., Car, S., & Wellner, F. (2019). Influence of filler properties on the rheological,cryogenic,fatigue and rutting performance of mastics. Construction and Building Materials, Vol.227, P.01-011.
Robertson, R.E. (1991). Chemical Properties of Asphalts and Their Relationship to Pavement Performance, Strategic Highway Research Program, UWP-91-510.
Rowe, G., & Sharrock, M.J. (2011). Alternate Shift Factor Relationship for Describing Temperature Dependency of Viscoelastic Behavior of Asphalt Materials. Transportation Research Record Journal of the Transportation Research Board, Vol.2207, P.125-135.
Rieksts, K., Pettinari, M., & Haritonovs, V. (2019). The influence of filler type and gradation on the rheological performance of mastics. Road Materials and Pavement Design, Vol.20, P.01-15.
Remisova, E. (2015). Study of mineral filler effect on asphalt mixtures properties. Conference: 6th Bituminous Mixtures & Pavements.
Remisova, E., Zatkalikova, V., & Schlosser, F. (2016). Study of Rheological Properties of Bituminous Binders in Middle and High Temperatures. Civil and environmental Engineering, Vol.12, Issue 1.
Sabouri, M., Mirzaiyan, D., & Moniri, A. (2018). Effectiveness of Linear Amplitude Sweep (LAS) asphalt binder test in predicting asphalt mixtures fatigue performance. Materials and Structures, Vol.171, P.281-290.
Safaei, F. (2016). Specification of Linear Amplitude Sweep Test Temperature and Modeling Temperature Effects on Asphalt Binder Fatigue, Vol.2574.
Safaei, F., & Castorena, C. (2016). Temperature Effects of Linear Amplitude Sweep Testing and Analysis. Transportation Research Board, Vol.2574, P.92-100.
Saboo, N., & Sukhija, M. (2020). Effect of Analysis Procedures in Linear Amplitude Sweep Test on the Fatigue Resistance of Nanoclay-Modified Asphalt Binders. Journal of Materials in Civil Engineering, Vol.33, Issue 1.
Schapery, R.A. (1997). Nonlinear Viscoelastic and Viscoplastic Constitutive Equations Based on Thermodynamics. Mechanics of Time-Dependent Materials, Vol.1, P.209-240.
Tanzadeh, R., & Shafabakhsh, G. (2020). Surface free energy and adhesion energy evaluation of modified bitumen with recycled carbon black (micro-nano) from gases and petrochemical waste. Construction and Building Materials, Vol.245.
Wang, C., Chen, Y., & Xie, W. (2016). A comparative study for fatigue characterization of asphalt binder using the linear amplitude sweep test. Materials and Structures, Vol.53.
Yusoff, N.L.M., Hainin, M.R., & Airey, G.D. (2011). What You Need to Know about Bitumen rheology .
Yusoff, N.I.M., Hainin, M.R., & Airey, G.D. (2013). The Use of Inter-conversion Equations on Bituminous Binder Data (Penggunaan Persamaan Antara-Penukaran ke Atas Data Pengikat Berbitumen. Sains Malaysiana, Vol.42, P.1647-1654.
Yosoff, N.I.M., Chailleux, E., & Airey, G.D. (2011). A comparative study of the influence of shift factor equations on master curve construction. International Journal of Pavement Research and Technology.
Yao, H., Dai, Q., You, Z., Zhang, J., Lv, S., & Xiao, X. (2019). Evaluation of contact angle between asphalt binders and aggregates using Molecular Dynamics (MD) method. Construction and Building Materials, Vol.2019, p.727–736.
Zyl, S.V. (2018). Relationship Between the Age Related Performance of a Typical Bituminous Binder in South Africa and the Fatigue Performance of the Asphalt Mixture [Master’s thesis]. Master Thesis of Engineering.