臺灣博碩士論文加值系統

摘要 I
Abstract III
致謝 V
目錄 VI
表目錄 IX
圖目錄 X
第一章 緒論 1
1-1 研究動機 1
1-2 研究目的及內容 2
第二章 文獻回顧 4
2-1 高級氧化處理法 4
2-1.1 光催化法(Photocatalysis) 4
2-2 偶氮染料 5
2-3 磷酸銀(Ag3PO4) 9
2-3.1 Ag3PO4金屬氧化物複合 11
2-4 鉬酸鉍(Bi2MoO6) 15
2-4.1 Bi2MoO6金屬氧化物複合 17
第三章 實驗方法 21
3-1 研究架構 21
3-2 藥品及儀器 24
3-3 觸媒命名及實驗流程 26
3-3.1 觸媒之命名 26
3-3.2 觸媒合成流程 28
3-4 物性分析 47
3-4.1 紫外光-可見光譜儀(Ultraviolet-Visible Spectroscopy, UV-Vis) 47
3-4.2 X光射線光電子能譜(X-Ray Photoelectron Spectroscopy, XPS) 48
3-4.3 X光繞射分析儀(X-Ray Diffraction, XRD) 49
3-4.4 掃描式電子顯微鏡(Scanning Electron Microscope, SEM) 49
3-4.5 穿透式電子顯微鏡(Transmission Electron Microscope, TEM) 50
3-4.6 光激螢光分光光譜儀(Photoluminescence, PL) 50
3-4.7 比表面積分析儀(Brunauer-Emmett-Teller, BET) 50
3-4.8 感應耦合電將發射光譜儀(Inductively Coupled Plasma Optical Emission Spectrometry, ICP-OES) 52
3-4.9 粒徑分析儀(Particle Size Analyzer) 52
3-4.10 界達電位(Zeta Potential) 52
3-5 光催化活性實驗 53
3-5.1 直接光解實驗 55
3-5.2 吸附實驗 56
3-5.3 紫外光催化實驗 56
3-5.4 可見光催化實驗 57
3-5.5 pH效應實驗 57
3-5.6 活性物種捕捉實驗 58
3-5.7 重複再使用性實驗 58
3-5.8 金屬溶出實驗 59
3-5.9 太陽光催化實驗 59
3-5.10 反應動力學模擬 60
第四章 結果與討論 61
4-1 觸媒樣品說明 61
4-2 表面特性分析 62
4-2.1 晶相分析 62
4-2.2 掃描式電子顯微鏡分析 69
4-2.3 穿透式電子顯微鏡 75
4-2.4 比表面積分析 80
4-2.5 電子電洞再結合率分析 80
4-2.6 表面電性分析 81
4-2.7 觸媒光譜吸收範圍及能隙值鑑定 83
4-2.8 元素組成與鍵結分析 85
4-3 光催化活性實驗 95
4-3.1 直接光解 95
4-3.2 Ag3PO4之光催化實驗結果 96
4-3.3 Bi2MoO6之光催化實驗結果 102
4-3.4 單一觸媒之合成方法比較 106
4-3.5 A/B系觸媒之光催化實驗結果 108
4-3.6 A/B之三重複實驗 116
4-3.7 pH效應實驗 117
4-3.8 重複再使用實驗 118
4-3.9 金屬溶出分析 121
4-3.10 活性物種捕捉實驗 124
4-3.11 觸媒光催化反應動力學模擬 126
4-3.12 太陽光實驗 129
4-4 光觸媒催化反應機制 132
4-5 光催化反應實驗後之表面分析 134
4-5.1 反應後觸媒之晶相分析 134
4-5.2 反應後觸媒之掃描式電子顯微鏡分析 138
4-5.3 反應後觸媒之穿透式電子顯微鏡分析 148
4-5.4 反應後觸媒之比表面積分析 155
第五章 結論與建議 157
5-1 結論 157
5-2 建議 158
參考文獻 159

Ahn, Y. K., Jeong, Y. K., Kim, T. Y., Cho, J. U. & Hwang, N. M. (2020). Texture evolution of non-oriented electrical steel analyzed by EBSD and insitu XRD during the phase transformation from γ to α. Materials Today Communications, 25, 101307.

Akbarzadeh, R., Fung, C. S. L., Rather, R. A. & Lo, I. M. C. (2018). One-pot hydrothermal synthesis of g-C3N4/Ag/AgCl/BiVO4 micro-flower composite for the visible light degradation of ibuprofen. Chemical Engineering Journal, 341, 248-261.

Akel, S., Dillert, R., Balayeva, N. O., Boughaled, R., Koch, J., Azzouzi, M. E. & Bahnemann, D. W. (2018). Ag/Ag2O as a co-catalyst in TiO2 photocatalysis effect of the co-catalyst/photocatalyst mass ratio. Catalys, 8, 647.

Biswas, M. C., Tiimob, B. J., Abdela, W., Jeelani, S. & Rangari, V. K. (2019). Nano silica-carbon-silver ternary hybrid induced antimicrobial composite films for food packaging application. Food Packaging and Shelf Life, 19, 104-113.

Chen, X., Li, R., Pan, X., Huang, X. & Yi, Z. (2017a). Fabrication of In2O3-Ag-Ag3PO4 composites with Z-scheme configuration for photocatalytic ethylene degradation under visible light irradiation. Chemical Engineering Journal, 320, 644-652.

Chen, Q., Wang, Y., Wang, Y., Zhang, X., Duan, D. & Fan, C. (2017b). Nitrogen-doped carbon quantum dots Ag3PO4 complex photocatalysts with enhanced visible light driven photocatalytic activity and stability. Journal of Colloid and Interface Science, 491, 238-245.

Chen, F., Niu, C., Yang, Q., Li, X. & Zeng, G. (2016). Facile synthesis of visible-light-active BiOI modified Bi2MoO6 photocatalysts with highly enhanced photocatalytic activity. Ceramics International, 42, 2515-2525.

Cheng, M., Zeng, G., Huang, D., Lai, C., Xu, P., Zhang, C. & Liu, Y. (2016). Hydroxyl radicals based advanced oxidation processes (AOPs) for remediation of soils contaminated with organic compounds A review. Chemical Engineering Journal, 284, 582-598.

Cui, D. H., Zheng, Y. F. & Song, X. H. (2017). A novel visible-light-driven photocatalyst Ag2O/AgI with highly enhanced photocatalytic performances. Journal of Alloys and Compounds, 701, 163-169.

Deng, M. & Huang, Y. (2020). The phenomena and mechanism for the enhanced adsorption and photocatalytic decomposition of organic dyes with Ag3PO4/graphene oxide aerogel composites. Ceramics International, 46, 2565-2570.

Deonikar, V. G., Reddy, K. K., Chung, W. J. & Kim, H. (2019). Facile synthesis of Ag3PO4/g-C3N4 composites in various solvent systems with tuned morphologies and their efficient photocatalytic activity for multi-dye degradation. Journal of Photochemistry & Photobiology A: Chemistry, 368, 168-181.

Ding, F., Chen, P., Liu, F., Chen, L., Guo, J. K., Shen, S., Zhang, Q., Meng, L. H., Au, C. T. & Yin, S. F. (2019). Bi2MoO6/g-C3N4 of 0D/2D heterostructure as efficient photocatalyst for selective oxidation of aromatic alkanes. Applied Surface Science, 490, 102-108.

Du, X., Wan, J., Jia, J., Pan, C., Hu, X., Fan, J. & Liu E. (2017). Photocatalystic degradation of RhB over highly visible-light-active Ag3PO4-Bi2MoO6 heterojunction using H2O2 electron capturer. Materials and Design, 119, 113-123.

Ge, M. & Li, Z. (2017). Recent progress in Ag3PO4‐based all‐solid‐state Z‐scheme photocatalytic systems. ScienceDirect, 38, 1794-1803.

Geng, B., Wei, B., Gao, H. & Xu, L. (2017). Ag2O nanoparticles decorated hierarchical Bi2MoO6 microspheres for efficient visible light photocatalysts. Journal of Alloys and Compounds, 699, 783-787.

Gui, M. S. & Zhang, W. D. (2011). Preparation and modification of hierarchical nanostructured Bi2WO6 with high visible light-induced photocatalytic activity. Nanotechnology, 22, 265601-265609.

Gui, M. S., Zhang, W. D., Su, Q. X. & Chen, C. H. (2011). Preparation and visible light photocatalytic activity of Bi2O3/Bi2WO6 heterojunction photocatalysts. Journal of Solid State Chemistry, 184, 1977-1982.

Guo, N., Li, H. Xu, X. & Yu, H. (2016). Hierarchical Fe3O4@MoS2/Ag3PO4 magnetic nanocomposites: enhanced and stable photocatalytic performance for water purification under visible light irradiation. Applied Surface Science, 389, 227-239.

Guo, J., Shi, H., Huang, X., Shi, H. & An, Z. (2017). AgCl/Ag3PO4: A stable Ag-based nanocomposite photocatalyst with enhanced photocatalytic activity for the degradation of parabens. Journal of Colloid and Interface Science, 515, 10-17.

Huang, H., Liu, L., Zhang, Y. & Tian, N. (2015). One pot hydrothermal synthesis of a novel BiIO4/Bi2MoO6 heterojunction photocatalyst with enhanced visible-light-driven photocatalytic activity for Rhodamine B degradation and photocurrent generation. Journal of Alloys and Compounds, 619, 807-811.

Jiang, L., Chen, D. Qin, L., Liang, J., Sun, X. & Huang, Y. (2019). Enhanced photocatalytic activity of hydrogenated BiVO4 with rich surface-oxygen-vacancies for remarkable degradation of tetracycline hydrochloride. Journal of Alloys and Compounds, 783, 10-18.

Jonjana, S., Phuruangrat, A., Thongtem, T., Thongtem S., Wiranwetchayan, O. & Thongtem T. (2016a). Preparation and characterization of Ag3VO4/Bi2MoO6 nanocomposites with highly visible-light-induced photocatalytic properties. Materials Letters, 180, 93-96.

Jonjana, S., Phuruangrat, A., Thongtem, T. & Thongtem T. (2016b). Synthesis of AgI/Bi2MoO6 heterojunctions and their photoactivity enhancement driven by visible light. Materials Letters, 175, 75-78.

Karunakaran, C., Kalaivani, S. & Vinayagamoorthy, P. (2014). Optical, electrical and visible light-photocatalytic properties of yttrium-substituted BiVO4 nanoparticles. Materials Letters, 122, 21-24.

Katsumata, H., Hayashi, T., Taniguchi, M., Suzuki, T. & Kaneco, S. (2015). AgI/Ag3PO4 hybrids with highly efficient visible-light driven photocatalytic activity. Materials Research Bulletin, 63, 116-122.

Kausor, M. A., Gupta, S. S. & Chakrabortty, D. (2019). Ag3PO4-based nanocomposites and their applications in photodegradation of toxic organic dye contaminated wastewater: review on material design to performance enhancement. Journal of Saudi Chemical Society, 23, 20-41.

Lai, C., Zhang M., Li, B., Huang, D., Zeng, G., Qin, L., Liu, X. Yia, H., Cheng, M. Li, L., Chenc, Z. & Chen L. (2019). Fabrication of CuS/BiVO4 (0 4 0) binary heterojunction photocatalysts with enhanced photocatalytic activity for Ciprofloxacin degradation and mechanism insight. Chemical Engineering Journal, 358, 891-902.

Lee, J.W., Choi, S.P., Thiruvenkatachari, R., Shim, W.G. & Moon, H. (2006). Evaluation of the performance of adsorption and coagulation processes for the maximum removal of reactive dyes. Dyes and Pigme, 69, 196-203.

Li, H., Cui, Y. & Hong W. (2013). High photocatalytic performance of BiOI/Bi2WO6 toward toluene and Reactive Brilliant Red. Applied Surface Science, 264, 581-588.

Li, S., Hu, S., Jiang, W., Liu, Y., Zhou, Y., Liu, Y. & Mo, L. (2018). Hierarchical architectures of bismuth molybdate nanosheets onto nickel titanate nanofibers: Facile synthesis and efficient photocatalytic removal of tetracycline hydrochloride. Journal of Colloid and Interface Science, 521, 42-49.

Li, T., Hu, X., Liu, C., Tang, C., Wang, X. & Luo, S. (2016). Efficient photocatalytic degradation of organic dyes and reaction mechanism with Ag2CO3/Bi2O2CO3 photocatalyst under visible light irradiation. Journal of Molecular Catalysis A: Chemical, 425, 124-135.

Li, H., Liu, J., Hou, W., Du, N., Zhang, R. & Tao, X. (2014). Synthesis and characterization of g-C3N4/Bi2MoO6 heterojunctions with enhanced visible light photocatalytic activity. Applied Catalysis B: Environmental, 160-161, 89-97.

Li, Q., Wang, F., Hua, Y., Luo, Y., Liu, X., Duan, G. & Yang, X. (2017). Deposition-precipitation preparation of Ag/Ag3PO4/WO3 nanocomposites for efficient visible-light degradation of Rhodamine B under strongly acidic/alkaline conditions. Journal of Colloid and Interface Science, 506, 207-216.

Li, Y., Xiao, X. & Ye, Z. (2019). Fabrication of BiVO4/RGO/Ag3PO4 ternary composite photocatalysts with enhanced photocatalytic performance. Applied Surface Science, 467-468, 902-911.

Liu, Y., Tang, H., Lv, H., Zhang, P., Ding, Z., Li, S. & Guang, J. (2015). Facile hydrothermal synthesis of TiO2/Bi2WO6 hollow microsphere with enhanced visible-light photoactivity. Powder Technology, 283, 246-253.

Liu, S., Tang, H., Zhou, H., Daia, G. & Wang, W. (2016). Photocatalytic perfermance of sandwich-like BiVO4 sheets by microwave assisted synthesis. Applied Surface Science, 391, 542-547.

Lu, J., Wang, Y., Liu, F., Zhang, L. & Chai, S. (2017a). Fabrication of a direct Z-scheme type WO3/Ag3PO4 composite photocatalyst with enhanced visible-light photocatalytic performances. Applied Surface Science, 393, 180-190.

Lu, G., Wang, F. & Zou, X. (2017b). Hydrothermal synthesis of m-BiVO4 and m-BiVO4/BiOBr with various facets and morphologies and their photocatalytic performance under visible light. Journal of Alloys and Compounds, 697, 417-426.

Ma, X., Ma, Z., Liao, T., Liu, X., Zhang, Y., Li, L. L., Li, W. & Hou, B. (2017). Preparation of BiVO4/BiOCl heterojunction photocatalyst by in-situ transformation method for norfloxacin photocatalytic degradation. Journal of Alloys and Compounds, 702, 68-74.

Ma, D., Wu, J., Gao, M., Xin, Y., Ma, T. & Sun, Y. (2016). Fabrication of Z-scheme g-C3N4/RGO/Bi2WO6 photocatalyst with enhanced visible-light photocatalytic activity. Chemical Engineering Journal, 209, 136-146.

Malathia, A., Madhavana, J., Ashokkumar, M. & Arunachalam, P. (2018). A review on BiVO4 photocatalyst: Activity enhancement methods for solar photocatalytic applications. Applied Catalysis A, General, 555, 47–74.

Martinez, C. M., Zhu, X. & Logan B. E. (2017). AQDS immobilized solid-phase redox mediators and their role during bioelectricity generation and RR2 decolorization in air-cathode single-chamber microbial fuel cells. Bioelectrochemistry, 118, 123-130.

Martin-Gomeza, A. N., Navíoa, J. A., Jaramillo-Paeza, C., Sanchez-Cida, P. & Hidalgo, M. C. (2020). Hybrid ZnO/Ag3PO4 photocatalysts, with low and high phosphate molar percentages. Journal of Photochemistry & Photobiology A: Chemistry, 388, 112196.

Mei, J., Zhang, D., Li, N., Zhang, M., Gu, X., Miao, S., Cui, S. & Yang, J. (2018). The synthesis of Ag3PO4/g-C3N4 nanocomposites and the application in the photocatalytic degradation of bisphenol A under visible light irradiation. Journal of Alloys and Compounds, 749, 715-723.

Ouyang, K., Jiang, N., Xue, W., & Xie, S. (2020). Enhanced photocatalytic activities of visible light-responsive Ag3PO4-GO photocatalysts for oxytetracycline hydrochloride degradation. Colloids and Surfaces A, 604, 125312.

Phuruangrat, A., Dumrongrojthanath, P., Thongtem, S. & Thongtem, T. (2017). Synthesis and characterization of visible light-driven W-doped Bi2MoO6 photocatalyst and its photocatalytic activities. Materials Letters, 194, 114-117.

Phuruangrat, A., Maneechote, M., Dumrongrojthanath, P., Ekthammathat, N., Thongtemd, S. & Thongtem, T. (2015). Visible-light driven photocatalytic degradation of rhodamine B by Ag/Bi2WO6 heterostructures. Materials Letters, 159, 289-292.

Ran, R., McEvoy, J. G. & Zhang, Z. (2016). Ag2O/Ag3VO4/Ag4V2O7 eterogeneous photocatalyst prepared by a facile hydrothermal synthesis with enhanced photocatalytic performance under visible light irradiation. Materials Research Bulletin, 74, 140-150.

Sedaghati, N., Habibi-Yangjeh, A., Pirhashemi, M., Asadzadeh-Khaneghah, S. & Ghosh, S. (2020). Integration of BiOI and Ag3PO4 nanoparticles onto oxygen vacancy rich-TiO2 for efficient visible-light photocatalytic decontaminations. Journal of Photochemistry & Photobiology A: Chemistry, 400, 112659.

Shen, Y., Zhu, Z., Wang, X., khan, A., Gong, J. & Zhang, Y. (2018). Synthesis of Z-scheme g-C3N4/Ag/Ag3PO4 composite for enhanced photocatalytic degradation of phenol and selective oxidation of gaseous isopropanol. Materials Research Bulletin, 107, 407-415.

Shi, Y., Luo, L., Zhang, Y., Chen, Y., Wang, S., Li, L., Long, Y. & Jiang, F. (2017). Synthesis and characterization of αβ-Bi2O3 with enhanced photocatalytic activity for 17α-ethynylestradiol. Ceramics International, 43, 7627-4635.

Shi, H., Zhang, C. & Zhou, C. (2015). g-C3N4 hybridized with AgVO3 nanowires preparation and its enhanced visible-light-induced photocatalytic activity. RSC Advances, 5, 50146-50154.

Sirajudheen, P., Nikitha, M. R., Karthikeyan, P. & Meenakshi, S. (2020). Perceptive removal of toxic azo dyes from water using magnetic Fe3O4 reinforced graphene oxide–carboxymethyl cellulose recyclable composite: Adsorption investigation of parametric studies and their mechanisms. Surfaces and Interfaces, 21, 100648.

Tao, R., Shao, C., Li, X., Li, X., Liu, S., Yang, S., Zhao, C. & Liu, Y. (2018). Bi2MoO6/BiFeO3 heterojunction nanofibers: Enhanced photocatalytic activity, charge separation mechanism and magnetic separability. Journal of Colloid and Interface Science, 529, 404-414.

Varma, R., Chaurasia, S., Patel, N. & Bhanage, B. M. (2020). Interplay of adsorption, photo-absorption, electronic structure and charge carrier dynamics on visible light driven photocatalytic activity of Bi2MoO6/rGO (0D/2D) heterojunction. Journal of Environmental Chemical Engineering, 8, 104551.

Wan, J., Dua, X., Liu, E., Hu, Y., Fan, J. & Hu, X. (2017). Z-scheme visible-light-driven Ag3PO4 nanoparticle@MoS2 quantum dot/few-layered MoS2 nanosheet heterostructures with high efficiency and stability for photocatalytic selective oxidation. Journal of Catalysis, 345, 281-294.

Wang, X., Gu, F., Li, L., Fang, G. & Wang, X. (2013). A facile mixed-solvothermal route to g-Bi2MoO6 nanoflakes and their visible-light-responsive photocatalytic activity. Materials Research Bulletin, 48, 3761-3765.

Wang, S., Guan, G., Wang, L., Zhao, W., He,H., Xiao, J., Yang, S. & Sun, C. (2015). Fabrication of a novel bifunctional material of BiOI/Ag3VO4 with high adsorption– photocatalysis for efficient treatment of dye wastewater. Applied Catalysis B: Environmental, 168, 448-457.

Wang, Z., Lv, J., Dai, K., Lu, L., Liang, C. & Geng, L. (2016). Large scale and facile synthesis of novel Z-scheme Bi2MoO6/Ag3PO4 composite for enhanced visible light photocatalyst. Materials Letters, 169, 250-253.

Wang, D., Shen, H., Guo, L., Wang, C., Fu, F. & Liang, Y. (2018). Ag/Bi2MoO6-x with enhanced visible-light-responsive photocatalytic activities via the synergistic effect of surface oxygen vacancies and surface Plasmon. Applied Surface Science, 436, 536-547.

Wang, Q., Zheng, Q., Jin, R., Gao, S., Yuan, Q., Rong, W. & Wang, R. (2017a). Photoelectrocatalytic removal of organic dyes and Cr(VI) ions using Ag3PO4 nanoparticles sensitized TiO2 nanotube arrays. Materials Chemistry and Physics, 199, 209-215.

Wang, M., You, M., Guo, P., Tang, H., Lv, C., Zhang, Y., Zhu, T. & Han, J. (2017b). Hydrothermal synthesis of Sm-doped Bi2MoO6 and its high photocatalytic performance for the degradation of Rhodamine B. Journal of Alloys and Compounds, 728, 739-746.

Wu, C. H. (2004). Comparison of azo dye degradation efficiency using UV/single semiconductor and UV/coupled semiconductor system. Chemosphere, 57, 601–608.

Xie, L., Yang, Z., Xiong, W., Zhou, Y., Cao, J., Peng, Y., Li, X., Zhou, C., Xu, R. & Zhang, Y. (2019). Construction of MIL-53(Fe) metal-organic framework modified by silver phosphate nanoparticles as a novel Z-scheme photocatalyst: Visible-light photocatalytic performance and mechanism investigation. Applied Surface Science, 465, 103-115.

Yin, J., Xing, Z., Kuang, J., Li, Z., Zhu, Q. & Zhou, W. (2019). Dual oxygen vacancy defects-mediated efficient electron-hole separation via surface engineering of Ag/Bi2MoO6 nanosheets/TiO2 nanobelts ternary heterostructures. Journal of Industrial and Engineering Chemistry, 78, 155-163.

Yin, J., Xing, Z., Kuang, J., Li, Z., Li, M., Jiang, J., Tan, S., Zhu, Q. & Zhou, W. (2018). Bi plasmon-enhanced mesoporous Bi2MoO6/Ti3+ self-doped TiO2 microsphere heterojunctions as efficient visible-light-driven photocatalysts. Journal of Alloys and Compounds, 750, 659-668.

Yu, M., Shang, C., Ma, G. Meng, Q., Chen, Z., Jin, M., Shui, L., Zhang, Y., Zhang, Z., Yuan, M., Wang, X. & Zhou, G. (2019). Synthesis and characterization of mesoporous BiVO4 nanofibers with enhanced photocatalytic water oxidation performance. Applied Surface Science, 481, 255-261.

Yuan, H., Liu, J., Li, J., Li, Y., Wang, X., Zhang, Y., Jiang, J., Chen, S., Zhao, C. & Qian, D. (2015). Designed synthesis of a novel BiVO4-Cu2O-TiO2 as an efficient visible-light-resonding photocatalyst. Journal of Colloid and Interface Science, 444, 58-66.

Yuan, X., Shen, D., Zhang, Q., Zou, H., Liu, Z., &Peng, F. (2019).Z-scheme Bi2WO6/CuBi2O4 heterojunction mediated by interfacial electricfield for efficient visible-light photocatalytic degradation of tetracycline. Chemical Engineering Journal, 369, 292-301.

Yue, L., Wang, S., Shan, G., Wu, W., Qiang, L. & Zhu, L. (2015). Novel MWNTs-Bi2WO6 composites with enhanced simulated solar photoactivity toward adsorbed and free tetracycline in water. Applied Catalysis B: Environmental, 176, 11-19.

Zeng, J., Zhong, J., Li, L., Xiang, Z., Liu, X. & Chen, J. (2014). Improvement of photocatalytic activity under solar light of BiVO4 microcrystals synthesized by surfactant-assisted hydrothermal method. Materials Science in Semiconductor Processing, 27, 41-46.

Zhang, X. B., Dong, W. Y., Sun, F. Y., Yang, W. & Dong J. (2014). Degradation efficiency and mechanism of azo dye RR2 by a novelozone aerated internal micro-electrolysis filter. Journal of Hazardous Materials, 276. 77-87.

Zhang, X. B., Dong, W. Y. & Yang, W. (2013). Decolorization efficiency and kinetics of typical reactive azo dye RR2 in the homogeneous Fe (II) catalyzed ozonation process. Chemical Engineering Journal, 233, 14–23.

Zhang, C., Wang, L., Yuan, F., Meng, R., Chen, J., Hou, W. & Zhu, H. (2020a). Construction of p-n type Ag3PO4/CdWO4 heterojunction photocatalyst for visible-light-induced dye degradation. Applied Surface Science, 534, 147544.

Zhang, X., Li, M., He, L., Tian, D., Zhang, L., Zhang, J. & Liu, M. (2020b). Highly sensitive and selective photoelectrochemical sensor for mercury (II) detection based on efficient Bi2MoO6 photoanode decorated with CuS. Journal Pre-proof, 864, 157905.

Zhang, J., Yan, M., Yuan, X., Si, M., Jiang, L., Wu, Z., Wang, H. & Zeng, G. (2018a). Nitrogen doped carbon quantum dots mediated silver phosphate/bismuth vanadate Z-scheme photocatalyst for enhanced antibiotic degradation. Journal of Colloid and Interface Science, 529, 11-22.

Zhang, T., Liu, M., Meng, Y., Huang, B., Pu, X. & Shao, X. (2018b). A novel method for the synthesis of Ag3VO4/Ag2VO2PO4 heterojunction photocatalysts with improved visible-light photocatalytic properties. Separation and Purification Technology, 206, 149-157.

Zhang, J. & Ma, Z. (2017a). Enhanced visible-light photocatalytic performance of Ag3VO4/Bi2WO6 heterojunctions in removing aqueous dyes and tetracycline hydrochloride. Journal of the Taiwan Institute of Chemical Engineers, 78, 212-218.

Zhang, J. & Ma, Z. (2017b). Flower-like Ag3VO4/BiOBr n-p heterojunction photocatalysts with enhanced visible-light-driven catalytic activity. Molecular Catalysis, 436, 190-198.

Zhao, W., Feng, Y., Huang, H., Zhou, P., Li, J., Zhang, L., Dai, B., Xu, J., Zhu, F., Sheng, N. & Leung, D. Y. C. (2019). A novel Z-scheme Ag3VO4/BiVO4 heterojunction photocatalyst Study on the excellent photocatalytic performance and photocatalytic mechanism. Applied Catalysis B: Environmental, 245, 448-458.

Zhao, J., Lu, Q., Wang, Q. & Ma, Q. (2016). α-Fe2O3 nanoparticles on Bi2MoO6 nanofibers: Onedimensional heterostructures synergistic system with enhanced photocatalytic activity. Superlattices and Microstructures, 91, 148-157.

Zhao,W., Wang, A., Wang, Y., Lv, C., Zhu, W., Dou, S., Wang, Q. & Zhong, Q. (2017). Accessible fabrication and mechanism insight of heterostructured BiOCl/Bi2MoO6/g-C3N4 nanocomposites with efficient photosensitized activity. Journal of Alloys and Compounds, 726, 164-172.

Zhou, G., Tian, Z., Sun, H., Zhang, J., Zhao, H., Li, P. & Sun, H. (2020). Understanding the photocatalytic mechanisms of the BiOI/Bi2MoO6 and BiOCl/Bi2MoO6 heterostructures: First-principles study. Journal of Physics and Chemistry of Solids, 146, 109557.

Zhou, L., Zhang, W., Chen, L. & Deng, H. (2017). Z-scheme mechanism of photogenerated carriers for hybrid photocatalyst Ag3PO4/g-C3N4 in degradation of sulfamethoxazole. Journal of Colloid and Interface Science, 487, 410-417.

Zhu, Z., Li, Y., Wang, C., Liang, L., Yu, D., Sun, J., Gao, P. & Liu, B. (2018). Facile synthesis and characterization of Bi2MoO6/Ag3PO4/RGO composites with enhanced visible-light-driven photocatalytic activity. Materials Letters, 227, 296-300.

Zhu, C., Zhang, L., Jiang, B., Zheng, J., Hu, P., Li, S., Wu, M. & Wu, W. (2016). Fabrication of Z-scheme Ag3PO4/MoS2 composites with enhanced photocatalytic activity and stability for organic pollutant degradation. Applied Surface Science, 377, 99-108.

Zou, X., Dong, Y., Zhang, X. & Cui, Y. (2016). Synthesize and characterize of Ag3VO4/TiO2 nanorods photocatalysts and its photocatalytic activity under visible light irradiation. Applied Surface Science, 366, 173-180.

林永輝，(2018)三氧化二鉍複合釩酸鹽氧化物為可見光激發觸媒之研究，國立高雄應用科技大學，碩士論文。

李國翊，(2019)三氧化二鉍複合釩酸鉍/釩酸銀複合材料之光催化應用及表面特性分析，國立高雄科技大學，碩士論文。

朱軒儒，(2020)釩酸銀/鎢酸鉍複合材料之光催化應用及表面特性分析，國立高雄科技大學，碩士論文。