在本研究中提出一種新式D型雷射輔助蝕刻長週期光纖光柵感測器(D-Shaped Laser-Assisted Etching Long-Period Fiber Gratings，DE-LPFGs)之製作方式。在單模光纖(Corning SM1500 9/125) 纖殼上利用KrF準分子雷射寫入，再結合雷射輔助蝕刻技術，在光纖上蝕刻出D型的結構，最後在D型光纖表面上利用相位光罩，濺鍍(Sputtering Coating)製作出光柵，製造出直徑60 μm、週期620 μm的DE-LPFGs。
在溫度實驗中，以DE-LPFGs進行溫度量測，記錄溫度上升與下降過程，溫度量測範圍為30 oC到100 oC。在溫度上升實驗中，平均共振波長靈敏度最高可達0.017 nm/oC，平均傳輸損耗靈敏度最高可達0.062 dB/oC，其平均共振波長線性度最高可達0.68，平均傳輸損耗線性度最高可達0.899；在溫度下降過程，平均共振波長靈敏度最高可達0.009 nm/oC，平均傳輸損耗靈敏度最高可達0.035 dB/oC，其平均共振波長線性度最高可達0.239，平均傳輸損耗線性度最高可達0.932。
在類風溼性關節炎(Rheumatoid Arthritis，RA)生醫實驗中，以雷射輔助蝕刻長週期光纖光柵感測器(Laser-Assisted Etching Long-Period Fiber Gratings，LLPFGs)量測不同的抗原濃度(0.1 / 0.01 / 0.001 µg/ml)，分析其共振波長與傳輸損耗變化。實驗結果發現，當抗原濃度越低時，波長變化時間越短、波長飄移量越小。

In the study propose a new fabrication method of D-shaped laser assisted etching long period fiber gratings sensor (DE-LPFGs). Using KrF excimer laser to make ablation area on the single-mode optical fiber (Corning SM1500 9/125) to destroy the cladding structure and making D-shaped structure on optical fiber with laser-assisted etching technology. And use phase mask cover on the D-shaped optical fiber surface structure, coat Ag gating with sputtering. The DE-LPFGs diameter is 60 μm and grating period is 620 μm.
In the temperature experiment used DE-LPFGs. Record temperature rise and drop process. the range of temperature is from 30 oC to 100 oC. In the temperature rises experiment, the result showd that average resonance wavelength sensitivity can reach 0.017 nm/oC, average transmission loss sensitivity can reach 0.062 dB/oC, average resonance wavelength linearity can reach 0.68, average transmission loss linearity can reach 0.899. In the temperature drops experiment, the result showd that average resonance wavelength sensitivity can reach 0.009 nm/oC, average transmission loss sensitivity can reach 0.035 dB/oC, average resonance wavelength linearity can reach 0.239, average transmission loss linearity can reach 0.932.
In the Rheumatoid arthritis(RA) biomedicine experiment used laser assisted etching long period fiber gratings sensor (LLPFGs). Measurement of different antigen concentrations (0.1 / 0.01 / 0.001 µg/ml) and analyze the resonance wavelength and transmission loss variation. The results showed that the antigen concentration is lower, the wavelength variation time is shorter and the wavelength drift is smaller.

目錄
摘要 i
ABSTRACT ii
目錄 iv
圖目錄 vi
表目錄 xvii
第一章 序論 1
1.1 研究動機 1
1.2 研究背景 2
1.3 研究目的 57
第二章 基礎理論 58
2.1 光纖傳輸基本原理 58
2.2 光彈理論 66
2.3 光纖光柵基礎理論 69
2.4 長週期光纖光柵耦合模態理論分析 71
2.5 長週期光纖光柵應變靈敏度分析 75
2.6 長週期光纖光柵尺寸靈敏度分析 77
第三章 研究方法與步驟 80
3.1 雷射輔助蝕刻長週期光纖製程 80
3.2 光纖濕蝕刻光柵製程 85
3.3 長週期光纖光柵感測器之拉伸實驗 88
3.4 D型雷射輔助蝕刻光纖製程 91
3.5 D型光纖濕蝕刻製程 93
3.6 D型雷射輔助蝕刻光纖長週期光柵製程 95
3.7 D型雷射輔助蝕刻長週期光纖光柵感測器之拉伸實驗 97
3.8 長週期光纖光柵感測器食人魚溶液蝕刻與奈米金塗覆實驗 99
3.9 長週期光纖光柵感測器類風濕性關節炎生醫量測實驗 101
3.10 D型雷射輔助蝕刻長週期光纖光柵感測器之封裝製程 105
3.11 D型雷射輔助蝕刻長週期光纖光柵感測器溫度量測實驗 107
第四章 實驗結果與討論 109
4.1 D型光纖不同燒熔深度的探討 110
4.2 D型光纖的雷射燒熔與蝕刻情形 113
4.3 D型雷射輔助蝕刻長週期光纖光柵感測器製作 115
4.4 探討D型雷射輔助蝕刻長週期光纖光柵感測器溫度量測數據 128
4.5 探討類風溼性關節炎抗體與抗原生醫量測數據 139
第五章 結論 160
5.1 D型長週期光纖光柵感測器結論 160
5.2 D型長週期光纖光柵感測器之溫度量測結論 161
5.3 長週期光纖光柵感測器之類風濕性關節炎抗原體與抗原量測結論 161
第六章 未來展望 162
6.1 D型雷射輔助蝕刻長週期雙種光柵光纖感測器 162
6.2 D型雷射輔助蝕刻長週期雙層光柵光纖感測器 162
參考文獻 164

圖目錄
圖1. 1 飛秒雷射在石英玻璃內寫入三維圖案示意圖[3] 2
圖1. 2 石英玻璃(二氧化矽)的蝕刻速率[3] 2
圖1. 3 長50 mm、寬40 mm的微通道顯微示意圖[4] 3
圖1. 4 電子顯微鏡下的橫截面示意圖，環氧樹脂支撐通道的情況下， 3
圖1. 5 實驗裝置示意圖[5] 4
圖1. 6 不同方向性與雷射能量之蝕刻深度比較[5] 4
圖1. 7 經飛秒雷射後形成的損傷線圖像[6] 5
圖1. 8 蝕刻24小時後，X型切割基片上的損傷線的光學顯微圖[6] 5
圖1. 9 LIBWE製程示意圖[7] 6
圖1. 10 蝕刻石英玻璃斷面SEM圖[7] 6
圖1. 11 LIBDE製程架構圖[8] 7
圖1. 12 以LIBWE方法生產的微結構實例[8] 7
圖1. 13 熔融石英玻璃中雷射切割軌跡的電子顯微鏡 (SEM) 圖像[9] 8
圖1. 14 （a）脈衝時間600 fs和（b）8 ps時延遲與雷射重複率的關係[9] 8
圖1. 15 光纖光流體裝置示意圖[10] 9
圖1. 16 蝕刻後製造的光纖流道顯微鏡(a)示意圖；(b)俯視圖[10] 9
圖1. 17 感測器在中心波長1567.6 nm量測不同蔗糖濃度之分析圖[10] 9
圖1. 18 玻璃基板雷射燒熔製程架構圖[11] 10
圖1. 19 厚度100 μm玻璃基板上的通孔OM圖[11] 10
圖1. 20 石英材質ULI製程架構圖[12] 11
圖1. 21 不同化學蝕刻劑原始熔融石英材質蝕刻速率[12] 11
圖1. 22 雷射裝置系統示意圖[13] 12
圖1. 23 雷射在基板背面燒融後的光學顯微圖[13] 12
圖1. 24 遠端探針部件顯微圖，(a)蝕刻前；(b)蝕刻後[14] 13
圖1. 25 使用拉曼探針5 秒內用 25 mW 的雷射功率傳送到樣品上測量獲得的常見拉曼活性參比材料的拉曼光譜[14] 13
圖1. 26 週期性矽結構製造示意圖及SEM圖[15] 14
圖1. 27 PSN高度隨雷射通量的變化圖[15] 14
圖1. 28 實驗流程示意圖(a)用波長1030 nm（光斑尺寸為1.5 μm）、光束脈衝能量為 230 nJ、頻率1 MHz的飛秒雷射導致玻璃材料上的結構破壞，(b)再以85∘C 的KOH 溶液進行濕式蝕刻，(c)最後再通過CO2 局部加熱來拋光組件的表面進行(d)拋光後的光學元件[16] 15
圖1. 29 (a)3-D表面形貌 (b)在濕蝕刻後立即測量的橫截面輪廓；RC = 28.2 μm ???? = 5.12∘ (c) 粗糙度輪廓，從中得出RMS 粗糙度Rq =94 nm[16] 15
圖1. 30 長週期光纖光柵透射光譜[17] 16
圖1. 31 階躍式LPG的折射率設定示意圖[18] 17
圖1. 32 階躍式LPGs的實驗（實線）和理論（虛線）光譜(L = 2.0 cm , γ = 1.6 ( a ) α = 0 , ( b ) α = 0.25，（c）α= 0.4 , ( d ) α = 0.525 , ( e ) α = 0.62)[18] 17
圖1. 33 準分子雷射製作長週期光纖結構示意圖[19] 18
圖1. 34 LPFG的共振峰深度和最大PDL的測量結果[19] 18
圖1. 35 環氧樹脂包層BCB脊形波導的SEM圖像[20] 19
圖1. 36 LPWG的傳輸光譜圖[20] 19
圖1. 37 濕度感測器示意圖: (a) 結構圖 ；(b) 折射率分佈[21] 20
圖1. 38 相對濕度感測器的峰值偏移從 40% 到 95%[21] 20
圖1. 39 準分子雷射寫入光纖感測器示意圖[22] 21
圖1. 40 光柵週期為 365μm 的長週期光纖傳輸波長和損耗圖[22] 21
圖1. 41 雙面長週期光纖光柵感測器製程實驗架構圖[23] 22
圖1. 42 (a)波長飄移分析圖，間隔10 oC的三循環溫度量測頻譜圖；(b)傳輸損耗飄移分析圖[23] 22
圖1. 43 準分子雷射通過掩模寫入光纖架構圖[24] 23
圖1. 44 (a)隨時間變化的LPG透射光譜(b)HE17模態與光柵長度的關係[24] 23
圖1. 45 (a)去除 PI 光纖塗層流程圖；(b) PI 光纖塗層的濕蝕刻蝕流程圖[25] 24
圖1. 46 長週期光纖光柵 (LPFG) 傳感器的拉伸頻譜圖(光纖直徑範圍為 100 至 50 µm，光柵週期為 620 µm) [25] 24
圖1. 47 FBG的退火裝置實驗架構圖[26] 25
圖1. 48 退火過程中 (a) FBG (I, III & V) 和 (b) FBG (II, IV & VI)的光柵對比度對溫度的依賴性[26] 25
圖1. 49 飛秒雷射製造長週期光纖光柵製程架構圖[27] 26
圖1. 50 長週期光纖光柵頻譜圖[27] 26
圖1. 51 實驗架構示意圖[28] 27
圖1. 52 波長264 nm飛秒雷射打出的LPFG頻譜圖[28] 27
圖1. 53 波長400 nm飛秒雷射打出的LPFG頻譜圖[28] 27
圖1. 54 飛秒雷射寫入長週期光纖光柵實驗架構圖[29] 28
圖1. 55 長週期光纖光柵頻譜圖(實線/圓：測量/計算的光柵透射率) [29] 28
圖1. 56 飛秒雷射製造長週期光纖光柵實驗架構圖[30] 29
圖1. 57 長週期光纖光柵頻譜圖 (a)SMF-28 (b)SMF-28e損耗值皆為26 dB[30] 29
圖1. 58 長週期光纖光柵表面燒熔痕跡[30] 29
圖1. 59 LPFG實體圖 (a)側視圖 (b)截面圖 (c)基本模態 (d)高階模態[31] 30
圖1. 60 長週期光纖光柵透射光譜演變頻譜圖[31] 30
圖1. 61 製造LPFG和頻譜量測實驗架構圖[32] 31
圖1. 62 在不同雷射脈衝能量下製造的LPFG的頻譜[32] 31
圖1. 63 LPFG扭轉實驗架構圖[33] 32
圖1. 64 (a)順時針方向和(b)逆時針方向共振峰波長分析圖[33] 32
圖1. 65 飛秒雷射製作SP-LPG的顯微圖[34] 33
圖1. 66 (a) SP-LPG 的透射和反射光譜。(b) 1523nm 附近的放大光譜，可以看到對應於布拉格共振峰的一些小凹陷[34] 33
圖1. 67 ( a )LPFG製造示意圖；( b ) RI調製逐點生成（放大倍數：100 倍）；( c ) 方波調製LPFG的顯微鏡圖像（放大倍數：100 倍）[35] 34
圖1. 68 LPFG 製造過程中的光譜變化（週期：560 μm；佔空比：50%）[35] 34
圖1. 69 飛秒雷射在POF中寫入FBG的頻譜變化[36] 35
圖1. 70 飛秒雷射在POF中寫入FBG的光學顯微鏡圖像[36] 35
圖1. 71 LPFG實驗架構示意圖[37] 36
圖1. 72 在線 EDFA有無過濾的光譜之間的比較[37] 36
圖1. 73 以CO2雷射製造的長週期光纖光柵感測器[38] 37
圖1. 74 溫度量測頻譜圖與分析圖[38] 37
圖1. 75 TAP-LPFG在空氣和水中的量測頻譜(週期 = 228.3 μm)[39] 38
圖1. 76 週期為230 μm的TAP-LPFG不同折射率響應。(a)透射光譜(b)在波長1501 nm的歸一化傳輸功率與折射率變化的關係[39] 38
圖1. 77 諧振波長對光柵間距的依賴性，插圖顯示了不同間距製造的 TMF-LPFG 的透射光譜[40] 39
圖1. 78 TMF-LPFG隨掃描週期增加的透射光譜 (a) TMF-LPFG (b) 傾斜的 TMF-LPFG[40] 39
圖1. 79 螺旋拋光結構製程架構圖[41] 40
圖1. 80 扭轉頻譜圖(a) R-HPLPFG (b) L-HPLPFG [41] 40
圖1. 81 (a) PMF-LPFG製程架構圖(b) CO2雷射光束路徑[42] 41
圖1. 82 快軸和慢軸的LP15模式頻譜圖 (a)軸向應變(b)溫度[42] 41
圖1. 83 (a)採用二維高速掃描振鏡的LPFG實驗架構示意圖；(b)具有光柵間距的CO 2雷射寫入LPFG的圖像；(c)雷射打入凹槽的顯微照片[43] 42
圖1. 84 有無LPFG情況下輸出光譜的比較(a)沒有LPFG；(b)有LPFG；(c)在最大雷射功率下兩者比較；(d)在最大輸出功率下插入LPFG抑制頻譜[43] 42
圖1. 85 D型光纖結構示意圖[44] 43
圖1. 86 D型光纖結構SEM圖[44] 43
圖1. 87 D型光纖結構SEM圖[44] 44
圖1. 88 感測器在不同折射率環境下的頻譜變化[45] 44
圖1. 89 D型光纖表面上的金屬光柵是意圖[46] 45
圖1. 90 分別在(A)純水、(B)水和異丙酮(1:1)和(C)異丙醇中的測量頻譜圖[46] 45
圖1. 91 由(a)單層石墨烯和PMMA堆疊；(b)雙石墨烯/PMMA堆疊塗覆的D型光纖(c)提出的偏振器的縱向剖面；(d)橫截面[47] 46
圖1. 92 TE和TM模式的限制損耗與(a) PMMA的厚度和單層石墨烯偏光片的拋光深度關係圖；(b)雙層石墨烯和PMMA的厚度( d = 62.5 um)關係[47] 46
圖1. 93 感測器橫截面示意圖[48] 47
圖1. 94 纖心引導模態（黑色虛線）、表面等離子體模態（紅色虛線）和限制損耗光譜（藍線）的色散關係(當兩條線相交時，損失最大)[48] 47
圖1. 95 砂輪側磨加工示意圖[49] 48
圖1. 96 (a) SPR (b) LRSPR感測器橫截面SEM圖[49] 48
圖1. 97 D型感測器的橫截面(圖左)和放大視圖(圖右)[50] 49
圖1. 98 纖芯模態的色散關係與其損耗曲線與相應的模態場分佈[50] 49
圖1. 99 (a)一般D型光纖的橫切面；(b)RT增強D型SMF的橫向平面；(c)RT增強D型SMF的等距視圖；(d)RT增強D型SMF的前視圖[51] 50
圖1. 100 (a)RT 增強D型SMF示意圖；(b)CD-SMF無芯平面截面通過SEM觀察；(c)CD-SMF無芯平面截面用顯微鏡觀察；（d）用AFM觀察到的CD-SMF的無芯平面截面[51] 50
圖1. 101 CO2雷射加工示意圖[52] 51
圖1. 102 D-LPFG結構圖[52] 51
圖1. 103 PS薄膜塗覆裝置示意圖[53] 52
圖1. 104 光纖外部結合BBSA及SA層示意圖[53] 52
圖1. 105 T7噬菌體檢測的塗層步驟示意圖[54] 53
圖1. 106 (A)藍噬菌體檢測後的共振波長；(B)加入T7噬菌體之前和之後的量測光譜[54] 53
圖1. 107 (a) D型感測器架構圖；(b) D型感測器拋光後圖像[55] 54
圖1. 108 感測器靈敏度與MoS2層數的關係[55] 54
圖1. 109 μIMZI結構(A)側視圖示意圖(B) SEM圖[56] 55
圖1. 110 μIMZI的MS2噬菌體與肽適體透射光譜[56] 55
圖1. 111 U型光纖塗層實驗架構示意圖[57] 56
圖1. 112 等離子體光纖夾心免疫生物傳感器的劑量反應曲線[57] 56
圖1. 113 論文架構圖 57

圖2. 1 階式折射光纖橫截面[58] 58
圖2. 2 光在不同密度介質中的折射示意圖[59] 59
圖2. 3 光纖折射和反射角關係圖[59] 61
圖2. 4 (a)階梯式折射光纖的折射率分佈 (b) 與 之間的關係[58] 63
圖2. 5 光柵原理示意圖[65] 69
圖2. 6 因數與纖殼模態階數的關係[83] 78
圖2. 7 峰值波長與光柵週期的關係[83] 79

圖3. 1 雷射輔助蝕刻長週期光纖製程實驗架構圖 81
圖3. 2 雷射輔助蝕刻長週期光纖製程架構實體圖 82
圖3. 3 微動平臺參數設定圖 84
圖3. 4 準分子雷射參數設定圖 84
圖3. 5 雷射加工示意圖 85
圖3. 6 長週期光纖濕蝕刻光纖步驟圖 87
圖3. 7 LLPFGs光纖光柵長週期結構圖 87
圖3. 8 長週期光纖光柵感測器拉伸實驗架構圖 89
圖3. 9 長週期光纖光柵感測器拉伸實驗實體圖 90
圖3. 10 長週期光纖光柵感測器拉伸頻譜圖 90
圖3. 11 D型雷射輔助蝕刻長週期光纖製程實驗架構圖 92
圖3. 12 雷射加工示意圖 92
圖3. 13 D型光纖濕蝕刻光纖步驟 94
圖3. 14 D型光纖結構側面圖 94
圖3. 15 D型光纖結構截面圖 94
圖3. 16 D型光纖濺鍍金屬製程圖 96
圖3. 17 D型長週期光纖光柵感測器拉伸實驗架構圖 98
圖3. 18 D型長週期光纖光柵感測器拉伸頻譜圖 98
圖3. 19 食人魚溶液蝕刻與奈米金塗覆實驗流程圖 100
圖3. 20 生醫晶片量測架構圖 103
圖3. 21 類風溼性關節炎實驗流程圖 104
圖3. 22 D-LLPFGs封裝製程圖 106
圖3. 23 D-LLPFGs溫度實驗架構圖 108

圖4. 1 未燒熔前的光纖纖殼直徑OM圖 110
圖4. 2 光纖燒熔後深度1.5 μm側面OM圖 111
圖4. 3 光纖燒熔後深度3 μm側面OM圖 111
圖4. 4 光纖經掃描後燒熔深度3 μm 側面OM圖 112
圖4. 5 光纖燒熔深度3 μm正面OM圖 112
圖4. 6 光纖燒熔深度3 μm背面OM圖 112
圖4. 7 燒熔光纖蝕刻時損耗變化與時間響應圖 113
圖4. 8 準分子雷射掃描1次光纖經蝕刻後側面OM圖 114
圖4. 9 準分子雷射掃描2次光纖經蝕刻後側面OM圖 114
圖4. 10 蝕刻後的D型結構OM圖 114
圖4. 11 D型結構直徑為45 μm的OM圖 115
圖4. 12 蝕刻直徑45 μm的波長與損耗關係頻譜圖 115
圖4. 13 D型結構直徑為40 μm的OM圖 116
圖4. 14 蝕刻直徑40 μm的波長與損耗關係頻譜圖 116
圖4. 15 D型結構直徑為35 μm的OM圖 116
圖4. 16 蝕刻直徑35 μm的波長與損耗關係頻譜圖 116
圖4. 17 D型結構直徑為30 μm的OM圖 117
圖4. 18 蝕刻直徑30 μm的波長與損耗關係頻譜圖 117
圖4. 19 蝕刻後不同直徑的D型結構光纖頻譜 117
圖4. 20 直徑45 μm D型光纖噴塗前與噴塗後的頻譜變化 119
圖4. 21 直徑40 μm D型光纖噴塗前與噴塗後的頻譜變化 119
圖4. 22 直徑35 μm D型光纖噴塗前與噴塗後的頻譜變化 120
圖4. 23 直徑30 μm D型光纖噴塗前與噴塗後的頻譜變化 121
圖4. 24 D型長週期光纖光柵塗附(側面)OM圖 121
圖4. 25 D型長週期光纖光柵塗附(側面)OM圖 123
圖4. 26 D型光纖濺鍍前與濺鍍後的頻譜變化 124
圖4. 27 D型光纖表面上厚度為40 nm的光柵，拉伸實驗頻譜變化 125
圖4. 28 D型光纖表面上厚度為100 nm的光柵，拉伸實驗頻譜變化 126
圖4. 29 D型光纖表面上厚度為200 nm的光柵，拉伸實驗頻譜變化 127
圖4. 30 D型長週期光纖光柵感測器溫度上升實驗三循環頻譜圖 129
圖4. 31 D型長週期光纖光柵感測器溫度上升實驗三循環分析圖 131
圖4. 32 D型長週期光纖光柵感測器溫度上升實驗標準差圖 132
圖4. 33 D型長週期光纖光柵感測器溫度下降實驗三循環頻譜圖 134
圖4. 34 D型長週期光纖光柵感測器溫度下降實驗三循環分析圖 136
圖4. 35 D型長週期光纖光柵感測器溫度下降實驗標準差圖 137
圖4. 36 LLPFGs感測器浸泡奈米金後拉伸頻譜圖 139
圖4. 37 LLPFGs量測3-MPA實驗頻譜圖 140
圖4. 38 LLPFGs量測CCP抗原濃度0.1µg/ml實驗三循環頻譜圖 142
圖4. 39 LLPFGs量測CCP抗原濃度0.1µg/ml實驗三循環分析圖 143
圖4. 40 LLPFGs量測CCP抗原濃度0.1µg/ml實驗三循環分析放大圖 144
圖4. 41 LLPFGs量測CCP抗原濃度0.1µg/ml實驗三循環歷程圖 145
圖4. 42 LLPFGs量測CCP抗原濃度0.01µg/ml實驗三循環頻譜圖 147
圖4. 43 LLPFGs量測CCP抗原濃度0.01µg/ml實驗三循環分析圖 148
圖4. 44 LLPFGs量測CCP抗原濃度0.01µg/ml實驗三循環分析放大圖 149
圖4. 45 LLPFGs量測CCP抗原濃度0.01µg/ml實驗三循環歷程圖 150
圖4. 46 LLPFGs量測CCP抗原濃度0.001µg/ml實驗三循環頻譜圖 152
圖4. 47 LLPFGs量測CCP抗原濃度0.001µg/ml實驗三循環分析圖 153
圖4. 48 LLPFGs量測CCP抗原濃度0.001µg/ml實驗三循環分析放大圖 154
圖4. 49 LLPFGs量測CCP抗原濃度0.001µg/ml實驗三循環歷程圖 155
圖4. 50 量測CCP固定抗體1.5 µg/ml(0~1.5分鐘)波長變化量與標準差分析圖 158
圖4. 51 量測CCP固定抗體1.5 µg/ml(0~1.5分鐘)損耗變化量與標準差分析圖 158

圖6. 1 D型雷射輔助蝕刻長週期雙種光柵光纖感測器示意圖 162
圖6. 2 D型雷射輔助蝕刻長週期雙層光柵光纖感測器示意圖 163

表目錄
表3. 1 KrF準分子雷射參數表 81
表3. 2 蝕刻液化學品資訊表 86

表4. 1 溫度上升實驗三循環頻譜圖數據統計表 130
表4. 2 溫度上升實驗三循環分析圖數據統計表 132
表4. 3 溫度上升實驗三循環頻譜圖數據統計表 135
表4. 4 溫度下降實驗三循環分析圖數據統計表 137
表4. 5 CCP固定抗體1.5µg/ml(0~1.5分鐘)抗原波長變化量與標準差分析表 156
表4. 6 CCP固定抗體1.5µg/ml(0~1.5分鐘)抗原損耗變化量與標準差分析表 157

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