臺灣博碩士論文加值系統

摘要 i
Abstract iii
誌謝 v
目錄 vi
表目錄 ix
圖目錄 x
第一章 緒論 1
1.1 前言 1
1.2 研究動機 3
1.3 研究架構 4
第二章 文獻回顧 5
2.1 燃料電池的發展 5
2.2 燃料電池發電原理 6
2.3 燃料電池優點介紹 7
2.4 陰離子交換膜燃料電池(AEMFC) 10
2.4.1 AEMFC之原理與構造 10
2.4.2 陰離子交換膜(AEM) 13
2.4.3 觸媒層(Catalyst Layer；CL) 14
2.4.4 氣體擴散層(Gas Diffusion Layer; GDL) 15
2.4.5 雙極板(Bipolar Plates; BP) 16
2.4.6 膜電極組(Membrane Electrode Assembly; MEA) 17
2.5 氧化還原反應(Oxygen Reduction Reaction; ORR) 18
2.5.1 電子轉移數 20
2.6 非貴金屬觸媒 21
2.6.1 氮摻雜於碳材料(Nitrogen-doped carbon materials) 23
2.6.2 聚脲化合物應用於觸媒 25
第三章 實驗 27
3.1 實驗藥品 27
3.2 儀器設備 32
3.3 實驗步驟 36
3.3.1 觸媒製備 36
3.3.2 循環掃描伏安法(CV) 及線性掃描伏安法(LSV)測定 41
3.3.2.1 漿料製備 41
3.3.2.2 循環掃描伏安法(CV) 及線性掃描伏安法(LSV)分析 41
3.3.3 膜電極組(MEA)製作 43
3.3.3.1 陰離子交換膜活化處理 43
3.3.3.2 觸媒漿料製備 43
3.3.3.3 觸媒層與氣體擴散層之製備 43
3.3.3.4 燃料電池膜電池組裝及分析參數 44
第四章 結果與討論 48
4.1 熱重分析(TGA) 48
4.2 官能基分析(FT-IR) 49
4.3 表面型態分析 51
4.3.1 TEM分析 51
4.3.2 SEM分析 54
4.4 結晶性分析(XRD) 57
4.5 有序性分析(Raman) 59
4.6 表面性質分析(BET) 61
4.7 電化學分析 67
4.7.1 循環伏安法(Cyclic Voltammetry，CV) 67
4.7.2 線性掃描伏安法(Linear Sweep Voltammetrys，LSV) 69
4.7.3 電子轉移數 71
4.7.4 塔佛斜率(Tafel slope) 76
4.7.5 耐久性測試 77
4.7.6 導電度測試 78
4.7.7 單電池效率分析 79
第五章 結論 81
第六章 參考文獻 82

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