臺灣博碩士論文加值系統

摘要 i
Abstract iii
誌謝 vi
目錄 vii
表目錄 x
圖目錄 xi
第一章 緒論 1
1.1 前言 1
1.2 鋅離子電池 1
第二章 文獻回顧與原理 4
2.1水性鋅離子於陽極的化學反應 4
2.2 鹽包水電解質 6
2.3 鋅離子電池有機電解質 16
2.4 鋅離子二次電池之陰極材料 23
2.4.1 陰極材料- Na3V2(PO4)3 24
2.4.2 陰極材料- 鋰錳氧/磷酸鐵鋰LiMn2O4/LiFePO4 26
2.5 研究動機 28
第三章 實驗部份 30
3.1 實驗材料 30
3.2 實驗儀器 31
3.3 實驗流程圖 32
3.4 實驗步驟 32
3.4.1 陰極的製備 32
3.4.2 電解質的製備 33
3.4.3 軟包電池組裝 34
3.5 結構鑑定 35
3.5.1 拉曼光譜儀(Raman Spectroscopy) 35
3.5.2 掃描電子顯微鏡 (Scanning Electron Microscope, SEM) 35
3.5.3 能量散射光譜儀 (Energy-dispersive X-ray spectroscopy, EDS) 35
3.5.4 X射線繞射儀 (X-ray diffractometer, XRD) 36
3.6 電化學量測 36
3.6.1 循環伏安法(Cyclic voltammetry, CV) 36
3.6.2 循環充放電測試(Cyclic charging-discharging test) 36
第四章 結果與討論 38
4.1對稱電池 38
4.1.1 Zn//Zn對稱電池之電化學測試 38
4.1.2 Zn//Zn對稱電池之表徵分析 39
4.2非對稱電池 41
4.2.1非對稱電池之測試 41
4.2.2 Zn//Cu非對稱電池之電化學測試 42
4.2.3 Zn//Cu非對稱電池之表徵分析 45
4.2.4 Zn//Pb、In非對稱電池之電化學測試 48
4.3電解質性質分析 53
4.3.1電解質之拉曼光譜分析 53
4.4 Zn//NVP混合電池系統的電化學研究 56
4.4.1 Zn//NVP混合電池系統的表徵分析 61
4.5 Zn//LMO混合電池系統的電化學研究 63
4.5.1 Zn//LMO混合電池系統的表徵分析 65
4.6 Zn//LFP混合電池系統的電化學研究 68
4.6.1 Zn//LFP混合電池系統的表徵分析 69
4.7無陽極混合電池系統 71
4.7.1 Anode-free//NVP混合電池系統的電化學研究 71
4.7.2 Cu//LMO混合電池系統的電化學研究 76
4.8電化學分析結果 78
第五章 結論 79
第六章 未來工作 81
參考文獻 82

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