臺灣博碩士論文加值系統

摘要 I
Abstract III
致謝 V
目錄 VI
表目錄 IX
圖目錄 X
第一章 緒論 1
1-1 研究動機 1
1-2 研究目的及內容 2
第二章 文獻回顧 3
2-1 抗生素 3
2-1.1 抗生素簡介 3
2-1.2 磺胺甲噁唑簡介 5
2-2 水中抗生素的去除方法 7
2-2.1 去除程序簡介 7
2-2.2 類芬頓處理法 9
2-2.3 SMX去除之相關類芬頓處理 10
第三章 實驗方法 19
3-1 實驗架構 19
3-2 藥品與儀器 21
3-3 催化劑處理流程及物性分析 24
3-3.1 催化劑處理流程 24
3-3.2 掃描式電子顯微鏡（Scanning Electron Microscope, SEM) 25
3-3.3 能量散射X射線光譜儀（Energy Dispersive X-ray Spectroscopy, EDX) 25
3-3.4 X射線繞射儀（X-Ray Diffraction, XRD) 25
3-4 實驗裝置架設 26
3-5 降解實驗分析方法 26
3-5.1 高效液相層析儀（High Performance Liquid Chromatography, HPLC) 26
3-5.2 光電二極體陣列偵測器（Photodiode Array, PDA) 27
3-5.3 分析方法 27
3-6 活性氧化物種捕捉實驗 29
3-7 催化劑劑量實驗 29
3-7.1 催化劑吸附實驗 30
3-7.2 反應動力學模擬 30
3-8 pH效應實驗 31
3-8.1 無催化劑降解系統 31
3-8.2 有催化劑降解系統 32
3-9 溫度效應實驗 32
3-10 溶液環境影響實驗 33
3-10.1 曝氣實驗 33
3-10.2 還原劑影響實驗 33
3-10.3 陰離子干擾實驗 35
3-11 再現性實驗 35
3-12 催化劑回收再利用實驗 36
第四章 結果與討論 37
4-1 催化劑物性分析結果 37
4-1.1 催化劑外觀 37
4-1.2 掃描式電子顯微鏡分析結果 37
4-1.3 能量散射X射線光譜儀分析結果 38
4-1.4 X射線繞射儀分析結果 39
4-2 活性氧化物種捕捉實驗結果 41
4-3 催化劑劑量實驗結果 42
4-3.1 催化劑吸附實驗結果 43
4-3.2 反應動力學模擬結果 44
4-4 pH效應實驗結果 46
4-4.1 無催化劑降解系統實驗結果 46
4-4.1 有催化劑降解系統實驗結果 49
4-5 溫度效應實驗結果 51
4-6 溶液環境影響實驗結果 54
4-6.1 曝氣實驗結果 54
4-6.2 還原劑影響實驗結果 56
4-6.3 陰離子干擾實驗結果 60
4-7 再現性實驗結果 63
4-8 催化劑回收再利用實驗結果 64
第五章 結論及建議 67
5-1 結論 67
5-2 建議 68
參考文獻 69

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