摘要 i
Abstract iii
誌謝 v
目錄 vi
表目錄 ix
圖目錄 x
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
1-3 研究架構 3
第二章 文獻回顧 4
2.1 燃料電池之歷史及發展 4
2.2 燃料電池發電相關原理 6
2.3燃料電池的優點 7
2.4 燃料電池的種類 8
2.5 陰離子交換膜燃料電池 (AEMFC) 14
2.5.1. 陰離子交換膜燃料電池介紹 14
2.5.2. 陰離子交換膜燃料電池之工作原理 15
2.5.3. 燃料電池極化 16
2.5.4. 陰離子交換膜燃料電池之構造及元件 18
2.5.5. 陰離子交換膜 (Anion Exchange Membrane；AEM) 19
2.5.6. 觸媒層 (Catalyst Layer；CL) 20
2.5.7. 氣體擴散層 (Gas Diffusion Layer；GDL) 21
2.5.8. 雙極板 (Bipolar Plates；BP) 22
2.5.9. 氣密墊片 22
2.5.10. 集電板 (Current Collector) 23
2.5.11. 膜電極組 (Membrane Electrode Assembly；MEA) 24
2.6 氧氣還原反應(Oxygen Reduction Reaction；ORR) 26
2.7 電子轉移數 26
2.8 非貴金屬觸媒 27
2.9 氮摻雜於碳材料 29
2.10 殼聚醣 30
2.10.1. 殼聚醣介紹 30
2.10.2. 殼聚醣磺化 31
2.10.3. 殼聚醣磷酸化 32
2.10.4. 殼聚醣四級胺化 33
2.10.5. 殼聚醣亞胺化 33
2.10.6. 殼聚醣特性表 34
2.10.7. 殼聚醣陰極觸媒相關文獻 35
第三章 研究材料與實驗方法 36
3.1 實驗藥品 36
3.2 實驗儀器 38
3.3 實驗步驟 41
3.3.1. 觸媒製備流程 41
3.3.2. 不同鍛燒溫度之觸媒製備 41
3.4 線性掃描伏安法(LSV)測定 44
3.5膜電極組(MEA)製作 45
3.5.1. 陰離子子交換膜之前處理 45
3.5.2. 觸媒漿料配製 45
3.5.3. 氣體擴散層電極製作 (GDE，Gas diffusion electrolyte) 45
3.6 燃料電池之單電池測試 46
3.6.1 燃料電池單電池組裝 46
3.6.2 燃料電池測試 46
第四章 結果與討論 47
4.1 官能基分析 (FTIR) 47
4.2 熱重量分析 (TGA) 49
4.3 表面型態分析 50
4.3.1 SEM分析 50
4.3.2 SEM 之能量色散X-射線光譜分析 (EDS，mapping) 51
4.3.3 TEM 分析 (Transmission Electron Microscopy) 54
4.4 結晶性分析 (XRD) 56
4.5 表面性質分析(BET) 57
4.6 體積電阻分析 59
4.7 有序性分析 (Raman) 60
4.8 電化學分析 61
4.8.1 線性掃描伏安法 (Liner sweep Voltammetry ； LSV) 61
4.8.2 循環伏安法 (Cyclic Voltammetry ； CV) 62
4.8.3 電子轉移數與塔佛斜率 63
4.8.4 耐久度測試 64
4.8.5 單電池分析 65
第五章 結論 66
第六章 參考文獻 67

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