臺灣博碩士論文加值系統

中文摘要……………………………………………………………………………..I
Abstract………………………………………….………………………………….II
誌謝………………………………………………………………………………....III
目錄………………………………………………………………………………....IV
圖目錄…………………………………………………………..………………....VII
表目錄……………………………………………………………..……………….IX
第一章 緒論……………………………………………………………………….1
1-1 前言……………………………………………………………………….1
1-2研究動機……………………………………………………………………...4
第二章 基礎理論與文獻回顧…………………………………………………….5
2-1 鈣鈦礦太陽能電池元件之材料與結構…..…………………………………..5
2-1-1 陰極-氧化錫摻氟透明導電層( Fluorine-doped tin oxide , FTO )……...5
2-1-2 電子傳輸層-二氧化錫( SnO2 )………………………………………….5
2-1-3三元有機-無機鈣鈦礦光吸收層………………………………………...6
2-1-4 電洞傳輸層- Spiro-OmeTAD…………………………………………...7
2-1-5 陽極-金屬電極…………………………………………………………..7
2-2 太陽能電池之工作原理與量測標準……………………………………..…..8
2-2-1 光伏效應………………………………………………………………...8
2-2-2 太陽能電池之量測標準………………………………………………...8
2-2-3 太陽能電池之量測特性………………………………………………...9
2-3文獻回顧與實驗設計………………………………………………………...12
2-3-1 文獻回顧……………………………………………………………….12
2-3-2 實驗設計……………………………………………………………….14
第三章 實驗製程與設備……….………………………………………………..23
3-1 製程材料與設備…………………………………………………..…………23
3-1-1 製程材料……………………………………………...……………......23
3-1-2 製程設備………………………………………...……………………..25
3-2 鈣鈦礦太陽能電池元件元件之製程…………………………………..……26
3-2-1 鈣鈦礦前驅溶液的配置…………………...……………...…………...26
3-2-2 蝕刻與清洗基板……………………………………………...….…….26
3-2-3 基板上TiO2致密層…………………………………………………...26
3-2-4 基板上SnO2薄膜……………………………………………………...27
3-2-5 元件的製程…………………………………………………………….27
3-3 實驗分析設備…………………………………………………………....…..28
3-3-1 太陽光模擬系統……………………………………………………….28
3-3-2 外部量子效率量( External Quantum Efficiency , EQE )……………..28
3-3-3時間解析光激螢光( Time-Resolved Photoluminescence，TRPL )..…28
3-3-4 掃描式電子顯微鏡( Scanning Electron Micrope , SEM )…………….29
3-3-5 X光繞射儀( X-Ray Diffration , XRD )………………………………...29
第四章 實驗結果與討論…………………………………………………….......34
4-1鈣鈦礦薄膜厚度分析…………………………………………….…………..34
4-2 溫度分析……………………………………………………………………..34
4-3 鈣鈦礦前驅溶液添加氯苯(CB)之實驗……………………………………..36
4-4 添加反溶劑氯苯( CB )之實驗結論………………………….……...………43
4-5鈣鈦礦前驅溶液添加乙酸乙酯( EA )之實驗…………………….…………45
4-6添加反溶劑乙酸乙酯( EA )之實驗結論……………..…………….………..52
第五章 結論與未來工作………………………………………………………...80
5-1 結論…………………………………………………………………………88
5-2 未來工作……………………………………………………………………89
參考文獻…………………………………………………………………………...90
作者簡介…………………………………………………………………………...95

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