染料敏化太陽能電池(DSSCs)是第三世代多晶矽太陽能電池，其優點在於成本低、製成容易且具有未來發展性的太陽能電池。而奈米銀線具有良好的表面電漿共振、導電性佳、低電阻，使電子能夠快速傳遞，適合用於製作光陽極的複合材料。
　　本研究中將不同濃度的奈米銀線添加至二氧化鈦醬料中，並以刮刀法塗布於Indium tin oxide (ITO)導電玻璃基板上，進行壓模處理，壓完膜後整體厚度平均約為10μm左右，之後再放到高溫爐進行退火，再利用三明治堆疊法將光陽極、熱塑性薄膜、背電極，以完成染料敏化太陽能電池的製作，之後將不同濃度的染料敏化太陽能電池進行量測分析得到結果。
　　研究結果表明，未添加奈米銀線的染料敏化太陽能電池，短路電流密度(Jsc)只有7.71%，其光電轉換效率為3.54%，相較添加奈米銀線濃度為0.05wt%的染料敏化太陽能電池，短路電流密度提升到了8.14%，光電轉換效率來達到4.14%，效率約提升了0.6%。

　　DSSCs are third-generation polycrystalline silicon solar cells, which have the advantages of low cost, easy preparation and future development of solar cells. The silver nanowire has good surface plasmon resonance, good conductivity, low resistance, so that electrons can be transferred quickly, and it is suitable for making composite materials for photo anodes.
　　In this study, different concentrations of silver nanowires were added to the titanium dioxide sauce, and coated on the Indium tin oxide (ITO) conductive glass substrate by a doctor blade method, and then subjected to compression molding. After the compression, the overall thickness of the film was about 10μm on average. Then put it in a high-temperature furnace for annealing, and then use the sandwich stack method to combine the photoanode, thermoplastic film, and back electrode to complete the production of dye-sensitized solar cells. Then, the dye-sensitized solar cells of different concentrations are measured and analyzed. got the answer.
　　The research results show that the short-circuit current density (Jsc) of the dye-sensitized solar cell without adding silver nanowires is only 7.71%, and its photoelectric conversion efficiency is 3.54%, which is compared with dye-sensitized solar cells with a concentration of 0.05wt% silver nanowires. For solar cells, the short-circuit current density has increased to 8.14%, the photoelectric conversion efficiency has reached 4.14%, and the efficiency raised 0.6%.

摘要...i
Abstract...ii
誌謝...iii
目錄...iv
表目錄...vi
圖目錄...vii
第一章 緒論...1
1.1前言...1
1.2研究動機與目的...2
第二章 文獻回顧...3
2.1染料敏化太陽能電池(Dye-sensitized solar cells, DSSCs)...3
2.1.1 太陽能電池發展歷史...3
2.1.2 染料敏化太陽能電池的基本結構...4
2.1.2.1 透明導電膜玻璃（Transparent Conducting Oxide, TCO）...4
2.1.2.2半導體工作電極薄膜（Working Electrode, WE）...4
2.1.2.3 染料（Dye）...5
2.1.2.4電解液（Electrolyte）...8
2.1.2.5 鉑金對電極（Pt Counter Electrode）...9
2.1.3　染料敏化太陽能電池工作原理...10
2.2 二氧化鈦應用與基本特性簡介...12
2.3銀基本特性簡介 (Sliver)...14
2.3.1 奈米銀線之表面電漿共振效應...14
第三章 實驗方法...16
3.1 實驗藥品與儀器設備...16
3.1.1實驗藥品...16
3.1.2實驗儀器設備...17
3.2實驗流程...18
3.2.1製備染料敏化太陽能電池...19
3.2.1.1 ITO透明導電玻璃基板清洗...19
3.2.2製備二氧化鈦與奈米銀線複合漿料...20
3.2.2.1奈米銀線規格...20
3.2.2.2調配奈米銀線與二氧化鈦複合漿料...21
3.2.2.3 製備奈米銀線與二氧化鈦複合薄膜...22
3.2.2.4 調配染料與工作電極敏化...23
3.2.2.5調配電解液...23
3.2.2.6 製備對電極...23
3.2.2.7 染料敏化太陽能電池的封裝...24
3.3 實驗儀器與特性分析...25
3.3.1 複合薄膜之特性分析...25
3.3.1.1場發射掃描式電子顯微鏡(FE-SEM)...25
3.3.1.2油壓機...28
3.3.2 染料敏化太陽能電池之特性分析...29
3.3.2.1 紫外光/可見光光譜儀(UV-Vis)...29
3.3.2.2電壓–電流特性量測...30
3.3.2.3全波段入射光子轉換效率量測...33
3.3.2.4 電化學阻抗頻譜分析量測...34
3.3.2.5 能量色散X射線光譜(Energy Dispersive Spectrometer, EDS)...39
第四章 結果與討論...40
4.1 場發射掃描式電子顯微鏡之複合薄膜分析...40
4.1.1二氧化鈦與奈米銀線複合薄膜表面分析...40
4.1.2 摻雜奈米銀線於DSSCs之EDS分析...42
4.2 染料敏化太陽能電池量測分析...43
4.2.1添加不同濃度奈米銀線對染料敏化太陽能電池特性的影響...43
第五章 結論...50
參考文獻...51
Extended Abstract...53

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