臺灣博碩士論文加值系統

摘要 I
Abstract III
致謝 V
目錄 VI
表目錄 IX
圖目錄 X
第一章 緒論 1
1-1 研究動機 1
1-2 研究目的及內容 2
第二章 文獻回顧 3
2-1 高級氧化處理法 3
2-1.1光催化法(Photocatalysis) 3
2-2 偶氮染料 4
2-3 磷酸銀(Ag3PO4) 8
2-3.1 Ag3PO4金屬氧化物改質 10
2-4 鉬酸鉍(Bi2MoO6) 12
2-4.1 Bi2MoO6金屬氧化物改質 14
2-5 氧化銅鉍(CuBi2O4) 17
2-5.1 CuBi2O4金屬氧化物改質 20
第三章 實驗方法 23
3-1 研究架構 23
3-2 藥品與儀器 26
3-3 觸媒命名及實驗流程 28
3-3.1 觸媒之命名 28
3-3.2 觸媒合成流程 31
3-4 物性分析 51
3-4.1 紫外-可見光光譜儀(Ultraviolet-Visible Spectroscopy, UV-Vis) 51
3-4.2 X射線光電子能譜(X-Ray Photoelectron Spectroscopy, XPS) 52
3-4.3 X光繞射分析儀(X-Ray Diffraction, XRD) 52
3-4.4 掃描式電子顯微鏡(Scanning Electron Microscope, SEM) 52
3-4.5 穿透式電子顯微鏡(Transmission Electron Microscope, TEM) 52
3-4.6 光激螢光光譜儀(Photoluminescence, PL) 53
3-4.7 比表面積分析儀(Brunauer-Emmett-Teller, BET) 53
3-4.8 感應耦合電漿發射光譜儀(Inductively Coupled Plasma Optical Emission Spectrometry, ICP-OES) 54
3-4.9 粒徑分析儀(Particle Size Analyzer) 55
3-4.10 界達電位(Zeta Potential) 55
3-5 光催化活性實驗 55
3-5.1 直接光解實驗 57
3-5.2 暗吸附實驗 57
3-5.3 紫外光催化實驗 58
3-5.4 可見光催化實驗 58
3-5.5 pH效應實驗 58
3-5.6 活性物種捕捉實驗 59
3-5.7 重複使用性實驗 59
3-5.8 金屬溶出試驗 60
3-5.9 太陽光催化實驗 60
3-5.10 反應動力學模擬 60
第四章 實驗結果 61
4-1 觸媒樣品粉末說明 61
4-2 表面特性分析 62
4-2.1 晶相分析 62
4-2.2 掃描式電子顯微鏡分析 71
4-2.3 穿透式電子顯微鏡分析 81
4-2.4 比表面積分析 86
4-2.5 電子-電洞再結合率分析 87
4-2.6 表面電性分析 88
4-2.7 觸媒光譜吸收範圍及能隙值鑑定 90
4-2.8 元素組成與鍵結分析 92
4-3 光催化活性實驗 104
4-3.1 直接光解 104
4-3.2 Ag3PO4之光催化實驗結果 105
4-3.3 Bi2MoO6之光催化實驗結果 107
4-3.4 CuBi2O4之光催化實驗結果 108
4-3.5 液-液一步驟之合成方法測試 109
4-3.6 固-液二步驟之合成方法測試 113
4-3.7 ABC-3, ABC-6三重複實驗 117
4-3.8 pH效應實驗 119
4-3.9 重複再使用實驗 119
4-3.10 金屬溶出分析 123
4-3.11 活性物種捕捉實驗 126
4-3.12 觸媒光催化反應動力學模擬 127
4-3.13 太陽光實驗 130
4-4 光觸媒催化反應機制 132
4-5 光催化反應實驗後之表面分析 134
4-5.1 反應後觸媒之晶相分析 134
4-5.2 反應後觸媒之掃描式電子顯微鏡分析 137
4-5.3 反應後觸媒之穿透式電子顯微鏡分析 148
4-5.4 反應後觸媒之比表面積分析 156
第五章 結論與建議 157
5-1 結論 157
5-2 建議 158
參考文獻 159

Abdulkarem, A. M., Li, J., Aref, A. A., Ren, L., Elssfah, E. M., Wang, H., Ge, Y., & Yu, Y. (2011). CuBi2O4 single crystal nanorods prepared by hydrothermal method: Growth mechanism and optical properties. Materials Research Bulletin, 46, 1443-1450.

Abroshan, E., Farhadi, S., & Zabardasti, A. (2018). Novel magnetically separable Ag3PO4/MnFe2O4 nanocomposite and its high photocatalytic degradation performance for organic dyes under solar-light irradiation. Solar Energy Materials and Solar Cells, 178, 154-163.

Ahn, Y. K., Jeong, Y. K., Kim, T. Y., Cho, J. U., & Hwang, N. M. (2020). Texture evolution of non-oriented electrical steel analyzed by EBSD and in-situ XRD during the phase transformation from γ to α. Materials Today Communications, 25, 101307.

Akbarzadeh, R., Fung, C. S. L., Rather, R. A., & Lo, I. M. C. (2018). One-pot hydrothermal synthesis of g-C3N4/Ag/AgCl/BiVO4 micro-flower composite for the visible light degradation of ibuprofen. Chemical Engineering Journal, 341, 248-261.

Akel, S., Dillert, R., Balayeva, N. O., Boughaled, R., Koch, J., Azzouzi, M. E., & Bahnemann, D. W. (2018). Ag/Ag2O as a co-catalyst in TiO2 photocatalysis: effect of the co-catalyst/photocatalyst mass ratio. Catalysts, 8, 647.

Amornpitoksuk, P., Intarasuwan, K., Suwanboon, S., & Baltrusaitis, J. (2013). Effect of phosphate salts (Na3PO4, Na2HPO4, and NaH2PO4) on Ag3PO4 morphology for photocatalytic dye degradation under visible light and toxicity of the degraded dye products. Industrial & Engineering Chemistry, 52, 17369-17375.

Biswas, M. C., Tiimob, B. J., Abdela, W., Jeelani, S., & Rangari, V. K. (2019). Nano silica-carbon-silver ternary hybrid induced antimicrobial composite films for food packaging application. Food Packaging and Shelf Life, 19, 104-113.

Chen, J., Yao, L., Chen, X., Li, N., Yu, C., Zhang, Y., & Lai, Y. (2022). Hydrothermal synthesis of dendritic CuBi2O4 and its photocatalytic performance towards tetracycline degradation under different light conditions. Materials Science in Semiconductor Processing, 142, 106503.

Chen, X., Dai, Y., & Wang, X. (2015). Methods and mechanism for improvement of photocatalytic activity and stability of Ag3PO4: A review. Journal of Alloys and Compounds, 649, 910-932.

Cheng, M., Zeng, G., Huang, D., Lai, C., Xu, P., Zhang, C., & Liu, Y. (2016). Hydroxyl radicals based advanced oxidation processes (AOPs) for remediation of soils contaminated with organic compounds A review. Chemical Engineering Journal, 284, 582-598.

Choi, Y. H., Yang, K. D., Kim, D. H., Nam, K. T., & Hong, S. H. (2017). p-Type CuBi2O4 thin films prepared by flux-mediated one-pot solution process with improved structural and photoelectrochemical characteristics. Materials Letters, 188, 192-196.

Dasgupta, J., Sikder, J., Chakraborty, S., Curcio, S., & Drioli, E. (2015). Remediation of textile effluents by membrane based treatment techniques: A state of the art review. Journal of Environmental Management, 147, 55-72.

Deng, Y., Chen, Y., Chen, B., & Ma, J. (2013). Preparation, characterization and photocatalytic activity of CuBi2O4/NaTaO3 coupled photocatalysts. Journal of Alloys and Compounds, 559, 116-122.

Ding, F., Chen, P., Liu, F., Chen, L., Guo, J. K., Shen, S., Zhang, Q., Meng, L. H., Au, C. T., & Yin, S. F. (2019). Bi2MoO6/g-C3N4 of 0D/2D heterostructure as efficient photocatalyst for selective oxidation of aromatic alkanes. Applied Surface Science, 490, 102-108.

Dong, C., Wu, K. L., Li, M. R., Liu, L., & Wei, X. W. (2014). Synthesis of Ag3PO4-ZnO nanorod composites with high visible-light photocatalytic activity. Catalysis Communications, 46, 32-35.

Dong, P., Wang, Y., Li, H., Li, H., Ma, X., & Han, L. (2013). Shape-controllable synthesis and morphology dependent photocatalytic properties of Ag3PO4 crystals. Journal of Materials Chemistry A, 10, 1039.

Dou, X., Chen, Y., & Shi, H. (2022). CuBi2O4/BiOBr composites promoted PMS activation for the degradation of tetracycline: S-scheme mechanism boosted Cu2+/Cu+ cycle. Chemical Engineering Journal, 431, 134054.

Du, X., Wan, J., Jia, J., Pan, C., Hu, X., Fan, J., & Liu, E. (2017). Photocatalystic degradation of RhB over highly visible-light-active Ag3PO4-Bi2MoO6 heterojunction using H2O2 electron capturer. Materials and Design, 119, 113-123.

Gao, B., Dong, S., Liu, J., & Sillanpää, M. (2018). PEDOT: PSS decorated ZnIn2S4 for reduced recombination of photogenerated electron-hole pairs. Materials Letters, 224, 64-66.

Gao, H., Wang, F., Wang, S., Wang, X., Yi, Z., & Yang, H. (2019). Photocatalytic activity tuning in a novel Ag2S/CQDs/CuBi2O4 composite: Synthesis and photocatalytic mechanism. Materials Research Bulletin, 115, 140-149.

Gui, M. S., Zhang, W. D., Su, Q. X., & Chen, C. H. (2011). Preparation and visible light photocatalytic activity of Bi2O3/Bi2WO6 heterojunction photocatalysts. Journal of Solid State Chemistry, 184, 1977-1982.

Guo, F., Shi, W., Wang, H., Han, M., Guan, W., Huang, H., Liu, Y., & Kang, Z. (2018). Study on highly enhanced photocatalytic tetracycline degradation of type Ⅱ AgI/CuBi2O4 and Z-scheme AgBr/CuBi2O4 heterojunction photocatalysts. Journal of Hazardous Materials, 349, 111-118.

Guo, W., Zhao, S., Li, G., Li, J., Chen, F., & Chen, R. (2021). Chlorine-enhanced photocatalytic degradation of PPCPs over Bi2MoO6/(BiO)2CO3 heterostructures. Journal of Environmental Chemical Engineering, 9, 106597.

Han, W., Wu, T., & Wu, Q. (2021). Fabrication of WO3/Bi2MoO6 heterostructures with efficient and highly selective photocatalytic degradation of tetracycline hydrochloride. Journal of Colloid and Interface Science, 602, 544-552.

Ismail, G. A., & Sakai, H. (2022). Review on effect of different type of dyes on advanced oxidation processes (AOPs) for textile color removal. Chemosphere, 291, 132906.

Jin, S., Hao, H., Gan, Y., Guo, W., Li, H., Hu, X., Hou, H., Zhang, G., Yan, S., Gao, W., & Liu, G. (2017). Preparation and improved photocatalytic activities of Ho3+/Yb3+ co-doped Bi2MoO6. Materials Chemistry and Physics, 199, 107-112

Jonjana, S., Phuruangrat, A., Thongtem, T., & Thongtem, S. (2016). Synthesis, analysis and photocatalysis of AgBr/Bi2MoO6 nanocomposites. Materials Letters, 172, 11-14.

Karunakaran, C., Kalaivani, S., & Vinayagamoorthy, P. (2014). Optical, electrical and visible light-photocatalytic properties of hydrothermally synthesized amorphous BiVO4 nanoparticles. Materials Letters, 122, 21-24.

Kimura, S. I., Kitagawa, M., Kusano, H., & Kobayashi, H. (2001). In and out plane X-ray diffraction of cellulose LB films. Studies in Interface Science, 11, 255-264.

Lai, C., Zhang M., Li, B., Huang, D., Zeng, G., Qin, L., Liu, X. Yi, H., Cheng, M., Li, L., Chen, Z., & Chen, L. (2019). Fabrication of CuS/BiVO4 (0 4 0) binary heterojunction photocatalysts with enhanced photocatalytic activity for Ciprofloxacin degradation and mechanism insight. Chemical Engineering Journal, 358, 891-902.

Li, H., Cui, Y., & Hong, W. (2013). High photocatalytic performance of BiOI/Bi2WO6 toward toluene and Reactive Brilliant Red. Applied Surface Science, 264, 581-588.

Li, H., Liu, J., Hou, W., Du, N., Zhang, R., & Tao, X. (2014). Synthesis and characterization of g-C3N4/Bi2MoO6 heterojunctions with enhanced visible light photocatalytic activity. Applied Catalysis B: Environmental, 160-161, 89-97.

Li, Q., Wang, F., Hua, Y., Luo, Y., Liu, X., Duan, G., & Yang, X. (2017). Deposition-precipitation preparation of Ag/Ag3PO4/WO3 nanocomposites for efficient visible-light degradation of rhodamine B under strongly acidic/alkaline conditions. Journal of Colloid and Interface Science, 506, 207-216.

Li, T., Hu, X., Liu, C., Tang, C., Wang, X., & Luo, S. (2016). Efficient photocatalytic degradation of organic dyes and reaction mechanism with Ag2CO3/Bi2O2CO3 photocatalyst under visible light irradiation. Journal of Molecular Catalysis A: Chemical, 425, 124-135.

Li, Y., Xiao, X., & Ye, Z. (2019). Fabrication of BiVO4/RGO/Ag3PO4 ternary composite photocatalysts with enhanced photocatalytic performance. Applied Surface Science, 467-468, 902-911.

Li, Z., Zheng, R., Dai, S., Zhao, T., Chen, M., & Zhang, Q. (2021). In-situ mechanochemical fabrication of p-n Bi2MoO6/CuBi2O4 heterojunctions with efficient visible light photocatalytic performance. Journal of Alloys and Compounds, 882, 160681.

Liang, C., Zhang, L., Guo, H., Niu, C. G., Wen, X. J., Tang, N., Liu, H. Y., Yang, Y. Y., Shao, B. B., & Zeng, G. M. (2019). Photo-removal of 2,2’4,4’-tetrabromodiphenyl ether in liquid medium by reduced graphene oxide bridged artificial Z-scheme system of Ag@Ag3PO4/g-C3N4. Chemical Engineering Journal, 361, 373-386.

Liu, Y., Fang, L., Lu, H., Li, Y., Hu, C., & Yu, H. (2012). One-pot pyridine-assisted synthesis of visible-light-driven photocatalyst Ag/Ag3PO4. Applied Catalysis B: Environmental, 115-116, 245-252.

Lu, J., Wang, Y., Liu, F., Zhang, L., & Chai, S. (2017). Fabrication of a direct Z-scheme type WO3/Ag3PO4 composite photocatalyst with enhanced visible-light photocatalytic performances. Applied Surface Science, 393, 180-190.

Ma, D., Wu, J., Gao, M., Xin, Y., Ma, T., & Sun, Y. (2016). Fabrication of Z-scheme g-C3N4/RGO/Bi2WO6 photocatalyst with enhanced visible-light photocatalytic activity. Chemical Engineering Journal, 209, 136-146.

Malathi, A., Madhavan, J., Ashokkumar, M., & Arunachalam, P. (2018). A review on BiVO4 photocatalyst: Activity enhancement methods for solar photocatalytic applications. Applied Catalysis A, General, 555, 47-74.

Martín-Gómez, A. N., Navío, J. A., Jaramillo- Páez, C., Sánchez-Cid, P., & Hidalgo, M. C. (2020). Hybrid ZnO/Ag3PO4 photocatalysts, with low and high phosphate molar percentages. Journal of Photochemistry & Photobiology A: Chemistry, 388, 112196.

Mei, J., Zhang, D., Li, N., Zhang, M., Gu, X., Miao, S., Cui, S., & Yang, J. (2018). The synthesis of Ag3PO4/g-C3N4 nanocomposites and the application in the photocatalytic degradation of bisphenol A under visible light irradiation. Journal of Alloys and Compounds, 749, 715-723.

Ng, W. C., Chong, M. N., Ilankoon, I.M.S.K., & Ocon, J. D. (2022). Controlled synthesis of high-performance silver/silver orthophosphate (Ag/Ag3PO4) interfaced photoanode with porous tetrahedrons layer for photoelectrochemical water splitting. Journal of Environmental Chemical Engineering, 10, 107161.

Ning, B., Xu, Q., Liu, M., Jiang, H., Hu, Y., & Li, C. (2022). Bismuthene with stable Bi-O bonds for efficient CO2 electroreduction to formate. Chemical Engineering Science, 251, 117409.

Ouyang, K., Jiang, N., Xue, W., & Xie, S. (2020). Enhanced photocatalytic activities of visible light-responsive Ag3PO4-GO photocatalysts for oxytetracycline hydrochloride degradation. Colloids and Surfaces A, 604, 125312.

Phuruangrat, A., Klangnoi, T., Patiphatpanya, P., Dumrongrojthanath, P., Thongtem, S., & Thongtem, T. (2020). Synthesis of Pd nanoparticles modified Bi2MoO6 nanoplates by microwave-assisted deposition with their enhanced visible-light-driven photocatalyst. Optik, 212, 164674.

Ran, R., McEvoy, J. G., & Zhang, Z. (2016). Ag2O/Ag3VO4/Ag4V2O7 heterogeneous photocatalyst prepared by a facile hydrothermal synthesis with enhanced photocatalytic performance under visible light irradiation. Materials Research Bulletin, 74, 140-150.

Sabri, M., Habibi-Yangjeh, A., & Ghosh, S. (2020). Novel ZnO/CuBi2O4 heterostructures for persulfate-assisted photocatalytic degradation of dye contaminants under visible light. Journal of Photochemistry & Photobiology A: Chemistry, 391, 112397.

Sangiorgi, N., Aversa, L., Tatti, R., Verucchi, R., & Sanson, A. (2017). Spectrophotometric method for optical band gap and electronic transitions determination of semiconductor materials. Optical Materials, 64, 18-25.

Shabbir, S., Faheem, M., Ali, N., Kerr, P. G., & Wu, Y. (2017). Evaluating role of immobilized periphyton in bioremediation of azo dye amaranth. Bioresource Technology, 225, 395-401.

Shao, B., Liu, X., Liu, Z., Zeng, G., Liang, Q., Liang, C., Cheng, Y., Zhang, W., Liu, Y., & Gong, S. (2019). A novel double Z-scheme photocatalyst Ag3PO4/Bi2S3/Bi2O3 with enhanced visible-light photocatalyst performance for antibiotic degradation. Chemical Engineering Journal, 368, 730-745.

Shi, W., Guo, F., & Yuan, S. (2017a). In situ synthesis of Z-scheme Ag3PO4/CuBi2O4 photocatalysts and enhanced photocatalytic performance for the degradation of tetracycline under visible light irradiation. Applied Catalysis B: Environmental, 209, 720-728

Shi, Y., Luo, L., Zhang, Y., Chen, Y., Wang, S., Li, L., Long, Y., & Jiang, F. (2017b). Synthesis and characterization of α/β-Bi2O3 with enhanced photocatalytic activity for 17α-ethynylestradiol. Ceramics International, 43, 7627-4635.

Sun, L., Mo, Y., & Zhang, L. (2022). A mini review on bio-electrochemical systems for the treatment of azo dye wastewater: State-of-the-art and future prospects. Chemosphere, 294, 133801.

Tab, A., Bellal, B., Belabed, C., Dahmane, M., & Trari, M. (2020). Visible light assisted photocatalytic degradation and mineralization of Rhodamine B in aqueous solution by Ag3PO4. Optik, 214, 164858.

Tan, Y., Yin, C., Zheng, S., Di, Y., Sun, Z., & Li, C. (2021). Design and controllable preparation of Bi2MoO6/attapulgite photocatalyst for the removal of tetracycline and formaldehyde. Applied Clay Science, 215, 106319.

Teng, P., Li, Z., Gao, S., Li, K., Bowkett, M., Copner, N., Liu, Z., & Yang, X. (2021). Fabrication of one-dimensional Bi2WO6/CuBi2O4 heterojunction nanofiber and its photocatalytic degradation property. Optical Materials, 121, 111508.

Uma, H. B., Ananda, S., & Kumar, M. S. V. (2021). Electrochemical synthesis and characterization of CuO/ZnO/SnO nano photocatalyst: Evaluation of its application towards photocatalysis, photo-voltaic and antibacterial properties. Chemical Data Collections, 32, 100658.

Varma, R., Chaurasia, S., Patel, N., & Bhanage, B. M. (2020). Interplay of adsorption, photo-absorption, electronic structure and charge carrier dynamics on visible light driven photocatalytic activity of Bi2MoO6/rGO (0D/2D) heterojunction. Journal of Environmental Chemical Engineering, 8, 104551.

Wang, D., Shen, H., Guo, L., Wang, C., Fu, F., & Liang, Y. (2018). Ag/Bi2MoO6-x with enhanced visible-light-responsive photocatalytic activities via the synergistic effect of surface oxygen vacancies and surface Plasmon. Applied Surface Science, 436, 536-547.

Wang, G., Li, G., Huan, Y., Hao, C., & Chen., W. (2020). Acrylic acid functionalized graphene oxide: High-efficient removal of cationic dyes from wastewater and exploration on adsorption mechanism. Chemosphere, 261, 127736.

Wang, L., Yang, G., Wang, D., Lu, C., Guan, W., Li, Y., Deng, J., & Crittenden, J. (2019). Fabrication of the flower-flake-like CuBi2O4/Bi2WO6 heterostructure as efficient visible-light driven photocatalysts: Performance, kinetics and mechanism insight. Applied Surface Science, 495, 143521.

Wang, S., Guan, Y., Wang, L., Zhao, W., He, H., Xiao, J., Yang, S., & Sun, C. (2015). Fabrication of a novel bifunctional material of BiOI/Ag3VO4 with high adsorption-photocatalysis for efficient treatment of dye wastewater. Applied Catalysis B: Environmental, 168-169, 448-457.

Wang, X., Liu, W., Wang, C., Zhang, S., Ding, M., & Xu, X. (2021). Enhanced formaldehyde gas sensing performance of ternary CuBi2O4 oxides through oxygen vacancy manipulation and surface platinum decoration. Sensors and Actuators: B. Chemical, 344, 130190.

Wilczewska, P., Bielicka-Giełdoń, A., Ryl, J., Sobaszek, M., Sawczak, M., Bogdanowicz, R., Szczodrowski, K., Malankowska, A., Qi, F., & Siedlecka, E.M. (2022). Development of novel (BiO)2OHCl/BiOBr enriched with boron doped-carbon nanowalls for photocatalytic cytostatic drug degradation: Assessing photocatalytic process utilization in environmental condition. Applied Surface Science, 586, 152664.

Wu, C. H. (2004). Comparison of azo dye degradation efficiency using UV/single semiconductor and UV/coupled semiconductor system. Chemosphere, 57, 601-608.

Xie, Y., Dai, Y., Yuan, X., Jiang, L., Zhou, L., Wu, Z., Zhang, J., Wang, H., & Xiong, T. (2018). Insight on the plasmonic Z-scheme mechanism underlying the highly efficient photocatalytic activity of silver molybdate/silver vanadate composite in rhodamine B degradation. Journal of Colloid and Interface Science, 530, 493-504.

Xu, J., Liu, Y., & Chen, M. (2021). Preparation of Cd-doped Bi2MoO6 photocatalyst for efficient degradation of ofloxacin under the irradiation of visible light. Surfaces and Interfaces, 25, 101246.

Yan, J., Wang, C., Xu, H., Xu, Y., She, X., Chen, J., Song, Y., Li, H., & Zhang, Q. (2013). AgI/Ag3PO4 heterojunction composites with enhanced photocatalytic activity under visible light irradiation. Applied Surface Science, 287, 178-186.

Yang, F., Yu, X., Liu, Z., Niu, J., Zhang, T., Nie, J., Zhao, N., Li, J., & Yao, B. (2021). Preparation of Z-scheme CuBi2O4/Bi2O3 nanocomposites using electrospinning and their enhanced photocatalytic performance. Materials Today Communications, 26, 101735.

Yao, Z., Sun, H., Xiao, S., Hu, Y., Liu, X., & Zhang, Y. (2021). Synergetic piezo-photocatalytic effect in a Bi2MoO6/BiOBr composite for decomposing organic pollutants. Applied Surface Science, 560, 150037.

Yuan, H., Liu, J., Li, J., Li, Y., Wang, X., Zhang, Y., Jiang, J., Chen, S., Zhao, C., & Qian, D. (2015). Designed synthesis of a novel BiVO4-Cu2O-TiO2 as an efficient visible-light-responding photocatalyst. Journal of Colloid and Interface Science, 444, 58-66.

Yuan, Y., Guo, R. T., Hong, L. F., Ji, X. Y., Lin, Z. D., Li, Z. S., & Pan, W. G. (2021). A review of metal oxide-based Z-scheme heterojunction photocatalysts: actualities and developments. Materials Today Energy, 21, 100829.

Yuvaraj, S., Karthikeyan, K., Kalpana, D., Lee, Y. S., & Selvan, R. K. (2016). Surfactant-free hydrothermal synthesis of hierarchically structured spherical CuBi2O4 as negative electrodes for Li-ion hybrid capacitors. Journal of Colloid and Interface Science, 469, 47-56.

Zeng, J., Zhong, J., Li, L., Xiang, Z., Liu, X., & Chen, J. (2014). Improvement of photocatalytic activity under solar light of BiVO4 microcrystals synthesized by surfactant-assisted hydrothermal method. Materials Science in Semiconductor Processing, 27, 41-46.

Zhang, C., Wang, L., Yuan, F., Meng, R., Chen, J., Hou, W., & Zhu, H. (2020a). Construction of p-n type Ag3PO4/CdWO4 heterojunction photocatalyst for visible-light-induced dye degradation. Applied Surface Science, 534, 147544.

Zhang, H., Nengzi, L. C., Li, X., Wang, Z., Li, B., Liu, L., & Cheng, X. (2020b). Construction of CuBi2O4/MnO2 composite as Z-scheme photoactivator of peroxymonosulfate for degradation of antibiotics. Chemical Engineering Journal, 386, 124011.

Zhang, J., & Ma, Z. (2017). Flower-like Ag3VO4/BiOBr n-p heterojunction photocatalysts with enhanced visible-light-driven catalytic activity. Molecular Catalysis, 436, 190-198.

Zhang, J., Yan, M., Yuan, X., Si, M., Jiang, L., Wu, Z., Wang, H., & Zeng, G. (2018). Nitrogen doped carbon quantum dots mediated silver phosphate/bismuth vanadate z-scheme photocatalyst for enhanced antibiotic degradation. Journal of Colloid and Interface Science, 529, 11-22.

Zhang, J., Yu, K., Yu, Y., Lou, L. L., Yang, Z., Yang, J., & Liu, S. (2014a). Highly effective and stable Ag3PO4/WO3 photocatalysts for visible light degradation of organic dyes. Journal of Molecular Catalysis A: Chemical, 391, 12-18.

Zhang, S., Zhang, S., & Song, L. (2014b). Super-high activity of Bi3+ doped Ag3PO4 and enhanced photocatalytic mechanism. Applied Catalysis B:Environmental, 152-153, 129-139.

Zhang, X. B., Dong, W. Y., & Yang, W. (2013). Decolorization efficiency and kinetics of typical reactive azo dye RR2 in the homogeneous Fe(II) catalyzed ozonation process. Chemical Engineering Journal, 233, 14–23.

Zhang, X., Li, M., He, L., Tian, D., Zhang, L., Zhang, J., & Liu, M. (2021). Highly sensitive and selective photoelectrochemical sensor for mercury(II) detection based on efficient Bi2MoO6 photoanode decorated with CuS. Journal of Alloys and Compounds, 864, 157905.

Zhang, X., Zhang, C., Yang, Y., Zhang, H., Huang, X., Hang, R., & Yao, X. (2019). Light-assisted rapid sterilization by a hydrogel incorporated with Ag3PO4/MoS2 composites for efficient wound disinfection. Chemical Engineering Journal, 374, 596-604.

Zhao, C., Shao, C., Li, X., Li, X., Tao, R., Zhou, X., & Liu, Y. (2018). Magnetically separable Bi2MoO6/ZnFe2O4 heterostructure nanofibers: Controllable synthesis and enhanced visible light photocatalytic activity. Journal of Alloys and Compounds, 747, 916-925.

Zhao, W., Feng, Y., Huang, H., Zhou, P., Li, J., Zhang, L., Dai, B., Xu, J., Zhu, F., Sheng, N., & Leung, D. Y. C. (2019). A novel Z-scheme Ag3VO4/BiVO4 heterojunction photocatalyst Study on the excellent photocatalytic performance and photocatalytic mechanism. Applied Catalysis B: Environmental, 245, 448-458.

Zhao, W., Wang, A., Wang, Y., Lv, C., Zhu, W., Dou, S., Wang, Q., & Zhong, Q. (2017). Accessible fabrication and mechanism insight of heterostructured BiOCl/Bi2MoO6/g-C3N4 nanocomposites with efficient photosensitized activity. Journal of Alloys and Compounds, 726, 164-172.

Zhao, X., Xu, T., Yao, W., & Zhu, Y. (2009). Photodegradation of dye pollutants catalyzed by γ-Bi2MoO6 nanoplate under visible light irradiation. Applied Surface Science, 255, 8036-8040.

Zheng, Y., Duan, F., Wu, J., Liu, L., Chen, M., & Xie, Y. (2009). Enhanced photocatalytic activity of bismuth molybdates with the preferentially exposed {010} surface under visible light irradiation. Journal of Molecular Catalysis A: Chemical, 303, 9-14.

Zhou, G., Tian, Z., Sun, H., Zhang, J., Zhao, H., Li, P., & Sun, H. (2020). Understanding the photocatalytic mechanisms of the BiOI/Bi2MoO6 and BiOCl/Bi2MoO6 heterostructures: First-principles study. Journal of Physics and Chemistry of Solids, 146, 109577.

Zhou, L., Wang, W., & Zhang, L. (2007). Ultrasonic-assisted synthesis of visible-light-induced Bi2MO6(M = W, Mo) photocatalysts. Journal of Molecular Catalysis A: Chemical, 268, 195-200.

林永輝，(2018)三氧化二鉍複合釩酸鹽氧化物為可見光激發觸媒之研究，國立高雄應用科技大學，碩士論文。

朱軒儒，(2020)釩酸銀/鎢酸鉍複合材料之光催化應用及表面特性分析，國立高雄科技大學，碩士論文。

張簡鈺嬿，(2021)磷酸銀/鉬酸鉍複合材料之光催化活性及表面特性分析研究，國立高雄科技大學，碩士論文。

羅修彣，(2021)磷酸銀/氧化銅鉍複合光觸媒之表面特性及廢水處理應用研究，國立高雄科技大學，碩士論文。