臺灣博碩士論文加值系統

中文摘要 ....................................................................................................................... Ⅰ
ABSTRACT ...................................................................................................................... Ⅱ
誌謝 ...................................................................................................................... Ⅳ
目錄 ....................................................................................................................... Ⅴ
表目錄 ...................................................................................................................... Ⅸ
圖目錄 ....................................................................................................................... Ⅹ
一、 緒論與文獻回顧 ....................................................................................................................... 2
1.1 咖啡渣 ....................................................................................................................... 2
1.1.1 咖啡渣的成份 ....................................................................................................................... 2
1.1.1.1 碳水化合物 ....................................................................................................................... 3
1.1.1.2 蛋白質 ....................................................................................................................... 4
1.1.1.3 脂質 ....................................................................................................................... 4
1.1.1.4 酚類化合物 ....................................................................................................................... 5
1.1.2 咖啡渣之應用 ....................................................................................................................... 6
1.1.2.1 重金屬的吸附 ....................................................................................................................... 6
1.1.2.2 生質燃料 ....................................................................................................................... 8
1.2 奈米銀 ...................................................................................................................... 10
1.2.1 銀的特性 ...................................................................................................................... 10
1.2.2 奈米銀的基本性質 ...................................................................................................................... 10
1.2.3 奈米銀的製備 ...................................................................................................................... 12
1.2.3.1 蒸發-冷凝法 ...................................................................................................................... 12
1.2.3.2 激光燒蝕法 ...................................................................................................................... 13
1.2.3.3 化學合成方法 ...................................................................................................................... 14
1.2.3.4 綠色化學合成方法 ................................................................... 14
1.2.4 奈米銀的應用 ...................................................................................................................... 18
1.3 研究動機與目的 ...................................................................................................................... 23
二、 實驗藥品與儀器 ...................................................................................................................... 25
2.1 實驗藥品 ...................................................................................................................... 25
2.1.1 咖啡渣的前處理 ...................................................................................................................... 25
2.1.2 咖啡渣/奈米銀的製備 ......................................................................... 25
2.1.3 抗菌測試 ...................................................................................................................... 25
2.2 實驗器材 ...................................................................................................................... 25
2.3 實驗儀器及原理 ...................................................................................................................... 26
2.3.1 掃描式電子顯微鏡 ...................................................................................................................... 27
2.3.2 能量散射X射線光譜儀 ..................................................................... 28
2.3.3 X射線繞射儀 ...................................................................................................................... 29
2.3.4 傅立葉轉換紅外線光譜儀 .................................................................. 30
2.3.5 熱重分析儀 ...................................................................................................................... 31
2.4 溶液配製 ...................................................................................................................... 32
2.4.1 PBS(Phosphate buffered saline) pH 7.4 ................................................ 32
2.4.2 50 mM AgNO3水溶液 ........................................................................ 32
2.4.3 0.1M HCl .............................................................................................. 32
2.4.4 0.1M NaOH .......................................................................................... 32
三、 實驗方法 ............................................................................................................... 34
3.1 實驗架構 ......................................................................................................... 34
3.2 咖啡渣取得與預處理 ......................................................................................... 35
3.3 咖啡渣/奈米銀粒子複合材料之製備 ................................................................ 35
3.4 複合材料之分析 ............................................................................................. 36
3.4.1 掃描式電子顯微鏡 ...................................................................................... 36
3.4.2 X射線繞射分析 .......................................................................................... 37
3.4.3 傅立葉轉換紅外線光譜儀 .......................................................................... 37
3.4.4 熱重分析儀 .................................................................................................. 37
3.5 抗菌試驗 ......................................................................................................... 37
3.5.1 平板計數法 .......................................................................................... 37
3.5.2 抑制圈法 .............................................................................................. 38
四、 結果與討論 ........................................................................................................... 40
4.1 合成AgNPs@SCGs的條件 ........................................................................... 40
4.2 複合材料之鑑定 ............................................................................................. 44
4.3 抗菌測試 ......................................................................................................... 45
五、 結論 ....................................................................................................................... 61
六、 參考文獻 ............................................................................................................... 62

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