臺灣博碩士論文加值系統

摘要...........................................................................i
Abstract.....................................................................iii
誌謝...........................................................................v
目錄..........................................................................vi
表目錄.........................................................................x
圖目錄.......................................................................xii
第一章 緒論....................................................................1
1-1 研究動機...................................................................1
1-2 研究目的及內容..............................................................2
第二章 文獻回顧.................................................................4
2-1 高級氧化處理法..............................................................4
2-1.1 光催化(Photocatalysis)...................................................4
2-1.2 過氧化氫.................................................................5
2-1.3 過硫酸鹽.................................................................6
2-2 抗生素(antibiotic).........................................................6
2-3 層狀雙氫氧化物(Layered Double Hydroxides, LDHs)............................11
2-3.1 銅鐵層狀雙氫氧化物(CuFe-LDHs)............................................12
2-3.2 CuFe-LDHs複合觸媒.......................................................16
2-3.3 銅鐵氧化物(CuFe-LDO)....................................................20
2-3.4 添加PMS之LDHs研究.......................................................23
2-3.5 添加H2O2之LDHs研究......................................................26
2-3.6 微波水熱法之LDHs研究.....................................................29
2-4 二氧化鈦(Titanium Dioxide, TiO2)..........................................31
2-4.1 LDHs/TiO2複合觸媒.......................................................31
2-5 奈米碳管(Carbon Nanotubes, CNTs)..........................................35
2-5.1 LDHs/CNTs複合觸媒.......................................................35
第三章 實驗方法................................................................38
3-1 研究架構..................................................................38
3-2 藥品與儀器................................................................42
3-3 觸媒命名及實驗流程.........................................................45
3-3.1 觸媒之命名..............................................................45
3-3.2 觸媒合成流程............................................................48
3-4 物性分析..................................................................61
3-4.1 紫外-可見光光譜儀(Ultraviolet-Visible Spectroscopy, UV-Vis)..............61
3-4.2 X射線光電子能譜(X-Ray Photoelectron Spectroscopy, XPS)...................62
3-4.3 X光繞射分析儀(X-Ray Diffraction, XRD)....................................62
3-4.4 掃描式電子顯微鏡(Scanning Electron Microscope, SEM)......................62
3-4.5 穿透式電子顯微鏡(Transmission Electron Microscope, TEM)..................63
3-4.6 光激螢光光譜儀(Photoluminescence, PL)....................................63
3-4.7 比表面積分析儀(Brunauer-Emmett-Teller, BET).............................63
3-4.8 感應耦合電漿發射光譜儀(Inductively Coupled Plasma Optical Emission Spectrometry, ICP-OES).......................................................65
3-4.9 粒徑分析儀(Particle Size Analyzer)......................................65
3-4.10 界達電位(Zeta Potential)...............................................66
3-4.11 熱重分析儀(Thermal gravity Analysis, TGA)..............................66
3-4.12 高效液相層析儀（High Performance Liquid Chromatography, HPLC）..........66
3-4.13 TOC總有機碳分析儀（Total Organic Carbon，TOC）.........................67
3-4.14 微波消化器（Microwave Digestion）.......................................69
3-5 光催化活性實驗.............................................................69
3-5.1 暗吸附實驗..............................................................72
3-5.2 紫外光催化實驗...........................................................72
3-5.3 可見光催化實驗...........................................................72
3-5.4 pH效應實驗..............................................................73
3-5.5 活性物種捕捉實驗.........................................................73
3-5.6 重複使用性實驗...........................................................74
3-5.7 金屬溶出試驗.............................................................74
3-5.8 太陽光催化實驗...........................................................75
3-5.9 反應動力學模擬...........................................................75
第四章 實驗結果................................................................76
4-1 觸媒樣品說明...............................................................76
4-2 表面特性分析...............................................................77
4-2.1 晶相分析................................................................77
4-2.2 掃描式電子顯微鏡分析.....................................................99
4-2.3 穿透式電子顯微鏡分析....................................................108
4-2.4 比表面積分析............................................................111
4-2.5 電子-電洞再結合率分析...................................................115
4-2.6 表面電性分析............................................................117
4-2.7 觸媒光譜吸收範圍及能隙值鑑定.............................................118
4-2.8 元素組成與鍵結分析......................................................121
4-2.9 熱重損失分析............................................................141
4-3 光催化活性實驗............................................................142
4-3.1 Cu3Fe1合成方法測試......................................................142
4-3.2 CuFe-LDHs觸媒之合成方法測試.............................................143
4-3.3 Cu3Fe1光觸媒最佳條件測試................................................146
4-3.4 Cu3Fe1(cal)三重覆實驗..................................................151
4-3.5 Cu3Fe1(cal)添加H2O2之光催化實驗.........................................152
4-3.6 Cu3Fe1(cal)添加PMS之光催化實驗..........................................154
4-3.7 Cu3Fe1/TiO2複合觸媒之光催化實驗.........................................157
4-3.8 Cu3Fe1/CNT複合觸媒之光催化實驗..........................................164
4-3.9 pH效應實驗 .............................................................170
4-3.10 溫度效應實驗...........................................................172
4-3.11 重複再使用實驗.........................................................173
4-3.12 金屬溶出分析...........................................................174
4-3.13 活性物種捕捉實驗.......................................................176
4-3.14 觸媒光催化反應動力學模擬................................................179
4-3.15 太陽光實驗............................................................181
4-4 光觸媒催化反應機制........................................................183
4-5 光催化反應實驗後之表面分析.................................................185
4-5.1 反應後觸媒之晶相分析....................................................185
4-5.2 反應後觸媒之掃描式電子顯微鏡分析.........................................187
4-5.3 反應後觸媒之穿透式電子顯微鏡分析.........................................188
4-5.4 反應後觸媒之元素組成與鍵結分析...........................................188
4-5.5 反應後觸媒之比表面積分析.................................................193
第五章 結論與建議.............................................................195
5-1 結論.....................................................................195
5-2 建議.....................................................................197
參考文獻 .....................................................................198

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