臺灣博碩士論文加值系統

本研究選用我國公共設施或工業系統常用之管線，如SS400一般結構用低碳鋼、SUS304鎳鉻不銹鋼與AA1100鋁合金，分別於其表面熔射不同之鎳層、鋁層、鋅化鋁層、銅層，完成熔射處理之試件分別進行塔弗(Tafle)極化曲線實驗、電化學阻抗實驗(EIS)，藉以進行腐蝕機制之研究。
經Tafle極化曲線實驗表明，SS400碳鋼熔射鍍層腐蝕電流密度：Base material＞ZnAl-coated＞Al-coated＞Ni-coated。SUS304不銹鋼熔射鍍層腐蝕電流密度：Cu-coated＞Al-coated＞Base material＞Ni-coated。AA1100鋁合金熔射鍍層腐蝕電流密度：Ni-coated＞ZnAl-coated＞Base material＞Al-coated。
SS400各鍍層塗佈底漆在3.5%NaCl溶液下之電化學阻抗譜 ，各鍍層塗佈底漆阻抗值以Al-primer coated最高346kΩ，防蝕效果Al-primer coated＞Ni-primer coated＞ZnAl-primer coated。SS400各鍍層塗佈面漆在3.5%NaCl溶液下之電化學阻抗譜，各鍍層塗佈底面漆阻抗值以Al-primer-top coated最高1.46 MΩ，防蝕效果Al-primer-top coated＞ZnAl-primer-top coated＞Ni-primer-top coated。

This study uses domestic public facilities or industrial systems commonly used pipelines. Such as SS400 (low-carbon steel), SUS304 (Ni-Cr stainless steel) and AA1100 (Aluminum alloy) which thermal spraying Ni-coated or Al-coated or ZnAl-coated or Cu-coated on the surface. The sample which complete thermal spraying were subjected to the tafle experiment and electrochemical impedance spectroscopy (EIS) to conduct research and analysis of the corrosion mechanism.
The results from the Tafle experiment show that SS400 (low-carbon steel) which have thermal spraying coated, corrosion current density：Base material＞ZnAl-coated＞Al-coated＞Ni-coated. Corrosion current density of SUS304 (Ni-Cr stainless steel) which have thermal spraying coated：Cu-coated＞Al-coated＞Base material＞Ni-coated. Corrosion current density of AA1110 (Aluminum alloy) which have thermal spraying coated：Ni-coated＞ZnAl-coated＞Base material＞Al-coated.
The SS400 which have thermal spraying was coated paint primer and soaked in 3.5% NaCl solution to electrochemical impedance spectroscopy, wherein the Al-coated has the highest resistance of 346kΩ, the corrosion resistance：Al-primer coated＞Ni-primer coated＞ZnAl-primer coated. The SS400 which have thermal spraying was coated paint primer-top coated and soaked in 3.5% NaCl solution to electrochemical impedance spectroscopy, wherein the Al-coated has the highest resistance of 1.46 MΩ, the corrosion resistance： Al-primer-top coated＞ZnAl-primer-top coated＞Ni-primer-top coated.

摘要 i
ABSTRACT ii
誌謝 iv
目錄 v
圖目錄 viii
表目錄 xii
符號說明 xiv
第一章 緒論 1
1.1 前言 1
1.2 研究動機與目的 3
1.3 論文架構 5
第二章 文獻回顧與探討 7
2.1 金屬材料之腐蝕機理 7
2.1.1 一般結構用低碳鋼之腐蝕相關文獻探討 8
2.1.2 鎳鉻不銹鋼之腐蝕相關文獻探討 12
2.1.3 鋁及鋁合金之氧化相關文獻探討 17
2.2 塔弗極化曲線(Tafle Polarization Curve)實驗相關文獻回顧 21
2.3 電化學阻抗頻譜實驗相關文獻回顧與探討 23
2.4 熔射防蝕處理相關技術發展 26
第三章 實驗方法與設備 31
3.1 實驗規劃 31
3.2 電化學原理 35
3.2.1 腐蝕電池 36
3.2.2 金屬腐蝕的電化學歷程 37
3.3 電化學試驗方法 39
3.3.1 極化曲線(Polarisation curves) 39
3.3.2 電化學阻抗譜 39
3.4實驗設備 41
3.4.1 恒電位儀 41
3.4.2 電化學阻譜儀 43
第四章 結果與討論 45
4.1 SS400低碳鋼熔射鍍層電化學特性 45
4.1.1 各鍍層材料在3.5%NaCl溶液下之極化曲線 45
4.1.2 各鍍層材料於3.5%NaCl溶液下之電化學阻抗譜 46
4.1.3 各鍍層材料在不同pH值下之極化曲線 50
4.2 SUS304不銹鋼熔射鍍層電化學特性 60
4.2.1 各鍍層材料在3.5% NaCl溶液下之極化曲線 60
4.2.2 各鍍層材料在3.5%NaCl溶液下之電化學阻抗譜 61
4.2.3 各鍍層材料在不同pH值下之極化特性 65
4.3 AA1100鋁合金熔射鍍層電化學特性 76
4.3.1 各鍍層材料在3.5% NaCl溶液下之極化曲線 76
4.3.2 各鍍層材料在3.5%NaCl溶液下之電化學阻抗譜 77
4.3.3 各鍍層材料在不同pH值下之極化特性 81
4.4 SS400各鍍層塗佈底、面漆後之電化學阻抗譜 91
4.4.1 低碳鋼SS400各鍍層塗佈底漆在3.5%NaCl溶液下電化學阻抗譜 91
4.4.2 低碳鋼SS400各鍍層塗佈面漆在3.5%NaCl溶液下電化學阻抗譜 93
第五章 結論及未來展望 96
5.1結論 96
5.1.1 SS400低碳鋼熔射鍍層電化學特性 96
5.1.2 SUS304不銹鋼熔射鍍層電化學特性 96
5.1.3 AA1100鋁合金熔射鍍層電化學特性: 97
5.1.4 各鍍層塗佈底漆及面漆在3.5%NaCl溶液下電化學阻抗譜 98
5.2 未來展望 98
參考文獻 99

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