目錄
摘要 i
Abstract ii
誌謝 iv
目錄 v
表目錄 viii
圖目錄 ix
第一章 緒論 1
1.1 前言 1
1.2 研究動機 1
1.3 研究架構 2
1.3.1 探討不同鍛燒溫度下觸媒的電化學表現 2
1.3.2 對比20%商用白金碳觸媒之性能 2
第二章 文獻回顧 3
2.1 燃料電池的發展 3
2.2 燃料電池的發電原理 4
2.3 燃料電池的優點 6
2.4 燃料電池的種類 6
2.5 陰離子交換膜燃料電池(AEMFC) 8
2.5.1 AEMFC之原理 8
2.5.2 燃料電池極化 9
2.5.3 陰極子交換膜燃料電池構造與元件 10
2.5.4 陰極子交換膜(Anion Exchange Membrane, AEM) 10
2.5.5 觸媒層(Catalyst Layer, CL) 11
2.5.6 氣體擴散層(Gas Diffusion, GDL) 11
2.5.7 雙極板(Bipolar Plates, BP) 12
2.5.8 集電板(Current Collector) 13
2.5.9 膜電極組(Membrance Electrode Assembly, MEA) 13
2.6 氧氣還原反應 15
2.7 電子轉移數 16
2.8 非貴重金屬觸媒 17
2.9 氮摻雜於碳材料 17
2.10 三乙烯四胺應用於觸媒 17
第三章 實驗 18
3.1 實驗藥品 18
3.2 儀器設備 21
3.3 實驗步驟 24
3.3.1 觸媒前驅物製備 24
3.3.2 不同鍛燒溫度之觸媒製備 24
3.4 線性掃描福安法(LSV)測定 26
3.5 膜電極組(MEA)製作及分析 28
3.5.1 陰離子交換膜活化 28
3.5.2 觸媒漿料製備 28
3.5.3 觸媒層與氣體擴散層製備 28
3.5.4 膜電極組裝 28
3.5.5 MEA單電池效率分析 29
第四章 結果與討論 30
4.1 官能基分析(FTIR) 30
4.2 熱重量分析(TGA) 32
4.3 型態分析 33
4.3.1 掃描式電子顯微鏡(SEM)分析 33
4.3.2 掃描式電子顯微鏡之能量色散X-射線光譜分析(EDS, Mapping) 34
4.3.3 穿透式電子顯微鏡(TEM)分析 38
4.4 結晶性分析(XRD) 39
4.5 表面性質分析(BET) 40
4.6 體積電阻值分析 43
4.7 有序性分析(Raman) 44
4.8 循環伏安法測試(Cyclic Voltammetry, CV) 45
4.9 線性伏安法測試(Linear Sweep Voltammetry, LSV) 46
4.10 電池轉移數與塔佛斜率 47
4.11 耐久性測試 50
4.12 單電池分析 51
第五章 結論 52
第六章 參考文獻 53

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