本篇論文主要分為兩個部分。第一部分使用了低溫且低成本之水熱法在90°C下成長製作氧化鋅奈米柱作為基準。 第二部分使用直流濺鍍系統將鉑奈米粒子濺鍍於氧化鋅奈米柱表面上，並將其研製為非酶葡萄糖感測器與第一部分做相比。
使用物性分析(SEM、TEM、XRD、PL、EDS、XPS)，觀察其表面形貌、材料結構、元素含量，也確切知道影響感測器之因素。在電化學部分利用循環伏安法(CV)觀察氧化鋅奈米柱與吸附鉑奈粒子後的特性，測量不同濃度下葡萄糖溶液(0~8mM)與氫氧化鈉 (0.1M)之循環伏安圖，其靈敏度分別為 5.5736μA/cm 2-mM 及31.7693μA/cm 2-mM，可觀察到吸附鉑奈米粒子後氧化鋅奈米柱有明顯的提升靈敏度反應以及對葡萄糖分子的感測能力，也利用I-T Curve去觀察葡萄糖感測器之穩定度、抗干擾以及選擇性的能力，發現有吸附鉑奈米粒子的氧化鋅奈米柱皆比純氧化鋅奈米柱來的好，代表鉑奈米粒子可以有效的提升對葡萄糖分子的靈敏度以及選擇性。

This research was divided into two phases. The first stage is ZnO nanorods were synthesized by a low temperature and low-cost process hydrothermal method. The second stage uses a DC sputter system to sputter platinum nanoparticles on the surface of ZnO nanorods and development of non-enzyme glucose sensor. Compared with the first stage.
By physical property analysis (SEM, TEM, XRD, PL, EDS, XPS), the surface morphology and elemental content were observed. Sensing response to compared in a 0~8mM glucose solution and 0.1mM sodium hydroxide solution pure ZnO nanorods and ZnO nanorods decorated with Pt nanoparticles by using cyclic voltammetry method. The sensitivities of the glucose sensor were 5.5736μA/cm 2-mM and 31.7693μA/cm 2-mM,respectively.It can be observed that ZnO nanorods decorated with Pt nanoparticles can effectively improve the sensitivity and enhance its catalytic properties for glucose molecules, also used I-T Curve to observed the stability, anti-interference and selectivity of the glucose sensor. It was found that the ZnO nanorods decorated with Pt nanoparticles are better than pure ZnO nanorods, which represents platinum nanoparticles can effectively improve sensitivity and selectivity for glucose molecules.

摘要.......i
Abstract.......ii
誌謝.......iii
目錄.......iv
表目錄.......vii
圖目錄.......viii
第一章 緒論.......1
1.1前言.......1
1.2研究動機.......2
第二章 文獻回顧.......4
2.1何謂生物感測器.......4
2.2葡萄糖感測器歷史.......5
2.2.1第一代葡萄糖感測器.......5
2.2.2第二代葡萄糖感測器.......6
2.2.3第三代葡萄糖感測器.......6
2.3第四代非酶葡萄糖感測器.......7
2.3.1奈米材料應用於非酶葡萄糖感測器.......7
2.3.2氧化鋅奈米結構修飾電極.......7
2.3.3 IHOAM模型.......7
2.4電化學原理.......9
2.4.1三極式電化學量測系統.......10
2.4.2循環伏安法.......11
2.5氧化鋅奈米材料簡介.......13
2.6薄膜製成.......15
2.7氧化鋅奈米結構之合成方式.......17
2.7.1化學氣相沉積法(CVD).......17
2.7.2水溶液法(Aqueous solution method).......18
2.7.3水熱法(Hydrothermal method).......19
第三章 實驗步驟與量測設備分析.......21
3.1實驗室藥品.......21
3.2儀器介紹.......22
3.2.1電化學分析儀器(Electrochemistry Workstation).......22
3.2.2場發射掃描式電子顯微鏡(Field Emission Scanning Electron Microscopy, FE-SEM).......23
3.2.3穿透式電子顯微鏡(Transmission Electron Microscopy，TEM).......24
3.2.4能量散佈分析儀(Energy Dispersive Spectrometer，EDS).......25
3.2.5 射頻磁控濺鍍系統(RF Sputter).......26
3.2.6 X射線繞射儀(X-ray diffraction,XRD).......28
3.2.7光致發光(Photoluminescence,PL).......29
3.2.8 X射線光電子能譜學(X-ray photoelectron spectroscopy,XPS).......30
3.2.9直流濺鍍(DC Sputter).......30
3.3氧化鋅奈米柱實驗步驟.......31
3.3.1基板清洗.......32
3.3.2氧化鋅晶種層製程.......33
3.3.3氧化鋅奈米柱生長.......34
3.3.4氧化鋅奈米奈米結構製作葡萄糖感測器.......36
3.3.5氧化鋅奈米柱及吸附鉑奈米粒子氧化鋅奈米柱材料特徵分析.......38
3.3.6葡萄糖電解質溶液的調配.......38
3.3.7電化學量測系統.......39
3.3.8循環伏安法(Cyclic Voltammetry).......39
3.3.9穩定度測試.......39
3.3.10電流-時間曲線圖(I-T Curve).......40
3.3.11干擾與選擇性測試.......40
第四章 結果與討論.......41
4.1氧化鋅奈米柱材料特徵分析.......41
4.1.1氧化鋅奈米柱場發射電子顯微鏡分析.......41
4.1.2氧化鋅奈米柱吸附鉑奈米粒子之場發射電子顯微鏡分析.......43
4.1.3 氧化鋅奈米柱吸附鉑奈米粒子之穿透式掃描式電子顯微鏡.......44
4.1.4 X-ray繞射儀之氧化鋅奈米柱分析.......47
4.1.5光致發光之氧化鋅奈米柱分析.......48
4.1.6化學分析電子光譜之氧化鋅奈米柱吸附鉑奈米粒子分析.......49
4.2氧化鋅奈米柱葡萄糖感測器之電化學分析.......52
4.2.1氧化鋅奈米柱之CV掃描-濃度對電流值之量測.......52
4.2.2氧化鋅奈米柱之不同掃描速率量測.......54
4.2.3氧化鋅奈米柱之穩定性量測.......55
4.2.4氧化鋅奈米柱之電流-時間(I-t curve)量測.......56
4.2.5氧化鋅奈米柱之干擾物質和選擇性量測.......57
4.3氧化鋅奈米柱吸附鉑奈米粒子之葡萄糖感測器之電化學分析.......58
4.3.1鉑表面氧化還原機制.......58
4.3.2氧化鋅奈米柱吸附鉑奈米粒子CV掃描-濃度對電流值之量測.......59
4.3.3氧化鋅奈米柱吸附鉑奈米粒子之不同掃描速率量測.......61
4.3.4氧化鋅奈米柱吸附鉑奈米粒子之穩定性量測.......62
4.3.5氧化鋅奈米柱吸附鉑奈米粒子之電流-時間圖(I-T curve)量測.......63
4.3.6氧化鋅奈米柱吸附鉑奈米粒子之干擾物質和選擇性量測.......64
4.3.7氧化鋅奈米柱與吸附鉑奈米粒子之能帶圖.......65
第五章 結論.......67
5.1結論.......67
5.2未來展望.......67
參考文獻.......68
Extended Abstract.......74

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