臺灣博碩士論文加值系統

Abstract i
摘要 iii
誌謝 iv
List of Tables ix
List of Figures x
Chapter 1：Introduction 1
Chapter 2：Literature Review 4
2.1 Introduction to Metal air battery 4
2.2 Structure and working principle of zinc-air battery 5
2.3 Zinc metal anode: 8
2.3.1 Zinc alloy 9
2.3.2 Microstructure of zinc metal 12
2.4 Electrolyte 13
2.4.1 Aqueous electrolyte 13
2.4.1.1 Alkaline electrolyte 14
2.4.1.2 Neutral electrolyte 14
2.4.1.3 Acid electrolyte 14
2.4.2 Gel electrolyte 14
2.4.3 Ionic liquid electrolyte 15
2.4.4 Solid polymer electrolyte 15
2.5 Air cathode 16
2.5.1 Precious metal catalysts 16
2.5.2 Transition metal catalysts and metal-free catalysts 17
2.5.3 Carbon black supports 20
2.6 Motivation 24
Chapter 3：Experimental 25
3.1 Equipment 25
3.2 Experimental materials 26
3.3 Experimental procedure 27
3.3.1 Preparation of carbon/metal composite catalyst by oil bath method 27
3.3.2 Preparation of carbon/metal composite catalyst for urea treatment 28
3.3.3 Preparation of carbon/metal composite catalyst by high temperature hydrothermal method 30
3.3.4 Preparation of NiFe-LDH catalyst 31
3.3.5 Preparation of air electrode 32
3.3.6 Water-based zinc-air battery components 33
3.4 Analysis of cyclic charge and discharge of zinc-air battery 34
3.5 Material determination method and analysis 35
3.5.1 X-ray diffraction (XRD) powder diffraction analysis 35
3.5.2 Scanning electron microscope (SEM) analysis 35
3.5.3 Energy Dispersive Spectroscopy (EDS) analysis 35
3-5-4 X-ray photoelectron spectroscopy (XPS) analysis 35
3-5-5 Raman spectrometer (RAMAN) analysis 36
Chapter 4：Results and discussion 37
4.1 System 1: Different carbon blacks use oil bath synthesis catalysts 37
4.1.1 Physical characterization 37
4.1.1.1 Powder X-ray diffraction (XRD) analysis 37
4.1.1.2 Raman spectroscopy investigation to various carbon supports 38
4.1.1.3 Raman spectroscopy analysis to VXC-72R catalyst 41
4.1.2 Electrochemical zinc-air batteries performance 42
4.1.3 Summary of system 1: Oil bath synthesis of different carbon black catalysts 49
4.2 System 2: The impact of urea addition on the catalyst 50
4.2.1 Material structure and composition 50
4.2.1.1 Powder diffraction analysis by X-ray diffractometer (XRD) 50
4.2.1.2 SEM/EDS analysis 52
4.2.1.3 X-ray photoelectron spectroscopy (XPS) analysis 54
4.2.2 Electrochemical zinc-air battery performance 57
4.2.3 System 2: The impact of urea addition on catalyst summary 65
4.3 System 3: The influence of different preparation methods on the catalyst 66
4.3.1 Material structure and composition 66
4.3.1.1 X-ray diffraction (XRD) powder diffraction analysis 66
4.3.2 Electrochemical zinc-air batteries performance 67
4.3.3 System 3: The influence of different preparation methods on catalyst summary 68
4.4 Summary of systems 1 to 3 69
4.4.1 Material structure and composition 69
4.4.1.1 X-ray diffraction (XRD) powder diffraction analysis 69
4.4.2 Electrochemical zinc-air batteries performance 71
Chapter 5：Conclusions and future perspective 74
5.1 Conclusions 74
5.2 Future perspective 76
Reference 77

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