臺灣博碩士論文加值系統

目錄
摘要 III
Abstract V
目錄 VII
表目錄 VII
圖目錄 XI
第一章 緒論 XI
1.1前言 1
1.2研究動機 2
1.3研究架構 3
第二章 文獻回顧 4
2.1燃料電池的發展 4
2.2燃料電池發電相關原理 5
2.3燃料電池的優性 6
2.4燃料電池的種類與應用 8
2.4.1各種燃料電池系統簡稱介紹 8
2.5陰離子交換膜燃料電池(AEMFC) 9
2.5.1陰離子交換膜燃料電池(AEMFC)的反應機制 10
2.5.2陰離子交換膜燃料電池之構造及元件 11
2.5.3陰離子交換膜 12
2.5.4觸媒層(Catalyst Layer; CL) 13
2.5.5氣體擴散層(Gas Diffusion Layer; GDL) 14
2.5.6雙極板(Bipolar Plates; BP) 15
2.5.7膜電極組(Membrane Electrode Assembly; MEA) 16
2.6氧氣還原反應(Oxygen Reduction Reaction; ORR) 17
2.6.1電子轉移數 19
2.7非貴重金屬觸媒 20
2.7.1氮摻雜於碳材料(Nitrogen-doped carbon materials) 20
第三章 實驗 21
3.1實驗藥品 21
3.2儀器設備 24
3.3實驗步驟 26
3.3.1觸媒製備 26
3.3.2不同鍛燒溫度之觸媒製備 27
3.3.3線性掃描伏安法(LSV)測定 30
3.3.4碳紙塗佈與熱壓 31
3.3.5 MEA單電池效率分析 32
第四章 結果與討論 34
4.1官能基分析(FT-IR) 34
4.2表面型態分析 35
4.2.1穿透式電子顯微鏡(TEM)分析 35
4.2.2掃描式電子顯微鏡(SEM)分析 35
4.2.3 HR-TEM型態分析 36
4.3結晶性分析(XRD) 38
4.4表面性質分析(BET) 39
4.5體積電阻分析 42
4.6有序性分析(Raman) 43
4.7循環伏安法測試(Cyclic voltammetry) 45
4.8線性伏安法分析(Linear Sweep Voltammetry; LSV) 46
4.9單電池分析 49
第五章 結論 52
參考文獻 53

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