摘要 i
Abstract ii
誌謝 iv
Table of Contents v
List of Tables vii
List of Figures viii
Chapter 1 Introduction 1
1.1 Background 1
1.2 Aluminum-ion battery 3
Chapter 2 Literature review 7
2.1 Carbon materials cathode 7
2.2 In-situ Raman Spectra 20
2.3 The reaction of carbon capacitive 24
2.4 Motivation 27
Chapter 3 Experimental section 28
3.1 Experimental materials 28
3.2 Analytical instruments 28
3.3 Preparation of cathode 29
3.4 Preparation of electrolyte 34
3.5 Assembly of battery 40
3.6 Physical characterization 41
3.6.1 Scanning electron microscopy analysis (SEM) 41
3.6.2 X-Ray Diffraction analysis (XRD) 42
3.6.3 Specific surface area analysis 42
3.6.4 Raman spectra analysis 42
3.7 Electrochemical measurement 43
3.7.1 Galvanostatic charge - discharge test 43
3.7.2 Cyclic voltammetry analysis (CV curve) 43
3.8 Battery mechanism analysis 44
3.8.1 In-situ Raman spectra analysis 44
3.8.2 Capacitive contribution analysis 44
Chapter 4 Results and discussion 45
4.1 Physical characterization 45
4.2 Electrolyte analysis 50
4.3 Electrochemical property analysis 52
4.3.1 CV curve analysis 52
4.3.2 Charge and discharge performance test 54
4.3.3 In-situ Raman spectra 70
4.3.4 Capacitive contribution analysis 77
4.3.5 Analysis of the working mechanism at different voltage windows 82
4.3.6 Capacitive and in-situ Raman analysis for natural graphite with 1.4 EMIC and 1.6 Til 89
Chapter 5 Conclusions 96
Chapter 6 Future work 98
Reference 99

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