臺灣博碩士論文加值系統

本篇論文研究透過溶膠-凝膠法成功地在經過溴化或醋酸處理後的碳-碳複合材料上塗覆了一層二氧化矽，使得在650°C時，該塗層樣本的氧化速率約為原始樣本的五倍低。然而，經過溴或醋酸處理後，碳-碳複合材料的拉伸模數分別下降了6%或17%，拉伸強度分別下降了5%或20%，但其延展性沒有受到影響。值得注意的是，這些拉伸性質並不會因為塗層過程而受到影響。塗層導致碳-碳複合材料的摩擦係數提高，但同時也提升了其硬度，所以並沒有因為增加了摩擦係數而增加磨耗。

The sol-gel coating was successfully used to coat a layer of silica on the carbon-carbon composites that were either brominated or acetic acid treated. The oxidation rate of the coated sample was about five times lower than that of the pristine sample at 650°C. However, the treatment of composites with bromine or acetic acid decreased the tensile modulus by 6% or 17% and the tensile strength by 5% or 20% respectively; it did not affect the ductility of the composites. These tensile properties of the carbon-carbon composite were not affected by the coating process. The coating resulted in an increase in the friction coefficient of the carbon-carbon composite. However, it also enhanced its hardness, so there was no significant increase in wear despite the higher friction coefficient.

摘要.....................................i
Abstract.................................ii
誌謝.....................................iii
目錄.....................................iv
表目錄...................................v
圖目錄...................................vi
第一章 緒 論.............................1
1.1 研究動機.............................1
1.2 研究目的與方法........................1
1.3 論文架構.............................2
第二章 文獻探討...........................3
2.1 碳纖維...............................3
2.1.1 碳纖維簡介..........................3
2.1.2 碳纖維的結構與性質...................3
2.1.3 聚丙烯腈(PAN)碳纖維簡介..............5
2.2 碳-碳複合材料的表面塗覆................7
2.2.1 超高溫陶瓷(UHTC)塗層的製作方法........9
2.2.2 碳化物UHTC塗層......................11
2.2.3 二氧化矽塗層........................13
2.2.3 塗層厚度的影響......................15
2.3 材料的磨耗............................16
第三章 實驗方法...........................18
3.1 實驗材料製作..........................18
3.2 碳-碳複合材料的表面處理................18
3.3 拉伸試驗..............................19
3.4 抗氧化性研究..........................20
3.4 磨耗試驗..............................21
第四章 結果與討論..........................23
4.1 機械性能..............................23
4.2 抗氧化性..............................26
4.3 磨耗比較..............................29
第五章 結論...............................30
5.1 結論..................................30
5.2 未來展望..............................30
參考文獻..................................31
Extended Abstract.........................37

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