臺灣博碩士論文加值系統

摘要 III
Abstract IV
誌謝 VI
目錄 VIII
表目錄 XI
圖目錄 XII
第一章 緒論 1
1.1前言 1
1.2研究動機 3
1.3研究架構 5
第二章 文獻回顧 7
2.1燃料電池的發展 7
2.2燃料電池發電原理 8
2.3燃料電池的優點 10
2.4燃料電池的種類與應用 13
2.5陰離子交換膜燃料電池(AEMFC) 16
2.5.1 AEMFC之原理 17
2.5.2陰離子交換膜燃料電池之構造及元件 18
2.5.3陰離子交換膜 18
2.5.4觸媒層(Catalyst Layer; CL) 19
2.5.5氣體擴散層(Gas Diffusion Layer; GDL) 21
2.5.6雙極板(Bipolar Plates; BP) 23
2.5.7膜電極組(Membrane Electrode Assembly; MEA) 24
2.6氧氣還原反應(Oxygen Reduction Reaction; ORR) 25
2.6.1電子轉移數 28
2.7非貴重金屬觸媒 29
2.7.1氮摻雜於碳材料(Nitrogen-doped carbon materials) 30
2.8乙二胺應用觸媒 31
2.9電極動力學與電池極化反應現象 32
第三章 實驗 34
3.1實驗藥品 34
3.2儀器設備 38
3.3實驗步驟 42
3.3.1觸媒製備 42
3.3.2線性掃描伏安法(LSV)測定 45
第四章 結果與討論 47
4.1 FeNxC不加甲苯系列 47
4.1.1官能基分析(FT-IR) 47
4.1.2表面型態分析(TEM) 48
4.1.3結晶性分析(XRD) 50
4.1.4有序性分析(Raman) 51
4.1.5表面性質分析(BET) 52
4.1.6能量散射X-射線光譜分析(EDS、Mapping) 56
4.1.7電化學分析(Linear Sweep Voltammetrys; LSVs) 58
4.2 FeNxC加甲苯系列 61
4.2.1表面型態分析(TEM) 61
4.2.2結晶性分析(XRD) 62
4.2.3有序性分析(Raman) 64
4.2.4表面性質分析(BET) 67
4.2.5束縛能分析(XPS) 71
4.2.6電化學分析(Linear Sweep Voltammetrys; LSVs) 74
第五章 結論 78
參考文獻 80

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