臺灣博碩士論文加值系統

本論文研究海水電池運用於能源的發展，在電化學的電池系統，陽極與
陰極的金屬反應極片形狀與兩電極間距的發電，有最佳的能源效率。實驗結
果發現，圓形的幾何形狀極片，發電時間可達到72 小時；遠超過目前的海水
電池8 小時。研究為使發電的電壓，可依照系統的運用更有利用性，特別設
計微電壓升壓器 (Booster)，使單一組反應池的發電，升壓至3.3V 與5V；同
時點亮發光二極體的照明；此外反應之陰陽極片發電運作中所產生的氫氣與
氧氣可各別收集，以利於燃料電池的二次發電，提供更多能源，該發電方式
合乎綠能發電。本文利用Arduino 程式的架構，可即時監控氫氣與氧氣之產
出量，並結合庫倫計提供發電瓦數的紀錄。陽極端產生之副產品為氫氧化
鎂，由於該金屬氧化物脫離極片表面後，所產生的反應物若不處理將會汙染
發電系統，因此，實驗設計利用壓力反向裝置，將汙染物自動轉至收集槽。
論文研究以海水電池發電模式結合燃料電池的二次供電設計，可為目前能源
短缺下，提供微小電量的設備所採用。

This paper studies the application of seawater batteries to energy
development. In the electrochemical battery system, the shape of the
metal reaction pole of the anode and the cathode and the distance between
the two electrodes optimize energy efficiency. The experimental results
found that the circular geometry of the pole is the best candidate among
the metal poles. The power generation time can reach 72 hours, far more
than the current seawater battery of 8 hours. The power generation
voltage is more usable. The experiment takes a micro-voltage booster
specially designed for the power generation of a single group that can
be boosted to 3.3V and 5V; at the same time, the light-emitting diodes
are lit. In addition, the hydrogen and oxygen generated during the power
generation operation of the cathode and anode sheets can be collected
separately to provide secondary power, such as fuel cells and other
energy sources. This active seawater battery can generate electronic
power as same as green energy. This article utilizes the structure of
the Arduino program to monitor the output of hydrogen and oxygen
simultaneously. The architecture combines the coulomb meter to provide
a record of the wattage of power generation. The by-product produces at
the anode end is magnesium hydroxide. Since the metal oxide is separated
from the surface of the pole piece, the generated reactant will pollute
the power generation system if it is not treated. Therefore, the
experimental design automatic pressure reverse device transfers the
pollutants to the collection tank. The paper studies the secondary power
supply design of the seawater battery power generation combined with the
iii
fuel cell, which can be used for the equipment that provides a small
amount of electricity under the current energy shortage.
Keywords: Seawater activate the battery, Magnesium anode of the metal
electrode, a Copper cathode of the metal electrode, Fuel cell, Green
energy power

目錄
中文摘要 i
英文摘要 ii
圖目錄 vi
表目錄 viii
符號說明 ix
第一章 緒論 1
1-1 燃煤 3
1-2 核能 4
1-3 再生能源 6
1-4 文獻回顧 12
第二章 電化學原理 15
第三章 實驗架構與研究步驟 21
3-1 產電實驗方式 21
3-2 鎂片產氫量與發電量 22
3-3 氫氣產生後期增多 22
3-4 使用設備 23
3-5 實驗內容 29
3-6 實驗程序 30
第四章 結果與討論 32
4-1 極片形狀與發電量 37
4-2 反應間隔材質 42
4-3 反應距離與發電關係 44
4-4 海水更新與發電關係 48
4-5 海水電池副產品 49
4-6 逆向電壓除附著物實驗 50
4-7 實驗結果討論綜整 58
第五章 結論 63
5-1 論文成果 63
5-2 未來研究方向 64
參考文獻 65
附件一 鎂金屬與銅金屬的電極材料合格證書 68
附件二 中華民國專利證書 69

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