臺灣博碩士論文加值系統

目錄
摘要 i
Abstract iii
致謝 v
目錄 vi
表目錄 x
圖目錄 xi
一、緒論 1
二、文獻回顧 2
2.1 太陽能電池 2
2.2 染料敏化太陽能電池簡介 4
2.2.1 太陽能電池之參數介紹 4
2.2.2 光電轉換原理 4
2.2.3 透明導電層 7
2.2.4 多孔奈米級二氧化鈦電子傳輸層 8
2.2.5 染料 8
2.2.6 電解質 9
2.2.7 對電極 10
2.2.8 添加劑(共吸附劑、共敏化) 10
共敏化 11
共吸附劑 13
2.3 樹枝狀高分子簡介 17
2.3.1 樹枝狀高分子合成路徑 17
2.3.2 樹枝狀高分子應用 20
2.3.3 加速樹枝狀高分子合成 20
2.4 反應選擇性官能基樹枝狀高分子 24
2.4.1 Urethane官能基樹枝狀段高分子 24
2.4.2 Azetidine-2,4-dione官能基 25
2.4.3 雙官能基構築單元合成樹枝狀分子 27
2.5 研究動機 30
三、實驗方法 32
3.1 實驗架構 32
3.2 藥品及溶劑 33
3.3 實驗儀器 39
3.4實驗合成 42
3.4.1 IDD之合成 42
3.4.2 C18系列樹枝狀分子之合成 42
G0.5-C18之合成 42
G1-C18之合成 43
G1.5-C18之合成 43
G2-C18之合成 44
G2.5-C18之合成 44
3.4.3 C3系列之樹枝狀分子合成 45
G0.5-C3之合成 45
G1-C3之合成 45
G1.5-C3之合成 45
3.4.4 末端為C18、C3與C10系列樹枝狀共吸附劑之合成 46
GA6-0.5-C18之合成 46
GA6-1.5-C18之合成 46
GA6-2.5-C18之合成 47
GA6-1.5-C3之合成 47
GA4-1.5-C10之合成 48
GA12-1.5-C10之合成 48
四、結果與討論 50
4.1 單體合成與鑑定 50
4.1.1 反應選擇性單體IDD之合成與鑑定 50
4.1.2 C18系列樹枝狀分子之合成與鑑定 51
G0.5-C18之合成與鑑定 52
G1-C18之合成與鑑定 54
G1.5-C18之合成與鑑定 56
G2-C18之合成與鑑定 58
G2.5-C18之合成與鑑定 60
4.1.3 C3系列樹枝狀分子之合成與鑑定 64
G0.5-C3之合成與鑑定 64
G1-C3之合成與鑑定 67
G1.5-C3之合成與鑑定 69
4.1.3 GA 系列樹枝狀共吸附劑之合成與鑑定 71
GA6-0.5-C18 71
GA6-1.5-C18 74
GA6-2.5-C18 75
GA6-1.5-C3 78
GA4-1.5-C10 81
GA12-1.5-C10 83
GA系列樹枝狀共吸附劑GPC之鑑定 85
4.2 物理性質測試 87
4.2.1 溶解度測試 87
4.2.2 熱重分析 87
4.2.3 差示掃描量熱法 88
4.3 光電測試 90
4.3.1 元件製作 90
4.3.2 電池元件性能討論 90
五、結論 98
六、參考文獻 99

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