臺灣博碩士論文加值系統

碩士論文 1
摘要 i
Abstract iii
誌謝 v
目錄 vi
表目錄 ix
圖目錄 x
第一章 緒論 1
1.1 前言 1
1.2 二次電池發展 1
第二章 文獻回顧與原理 3
2.1 水性鋅離子二次電池簡介及原理 3
2.2 水性電解質類型 5
2.3 離子液體與深共熔液 10
2.4 研究動機 14
第三章 實驗部份 16
3.1 實驗材料 16
3.2 實驗儀器 17
3.3 實驗流程圖 18
3.4 實驗步驟 18
3.4.1 電解液配製 18
3.4.2 對稱電池組裝 20
3.4.3 非對稱電池組裝 20
3.4.4 半電池組裝 21
3.5 電解液分析 23
3.5.1 拉曼光譜儀(Raman Spectrometer) 23
3.5.2 傅立葉轉換紅外光譜儀(Fourier transform infrared spectrometer，FTIR) 24
3.5.3 示差掃描熱量分析儀(Differential Scanning Calorimeter，DSC） 24
3.5.4 導電度計(conductivity meter) 25
3.6 極片分析 26
3.6.1 X-光繞射分析(X-ray diffraction analysis，XRD) 26
3.6.2 掃描電子顯微鏡(Scanning electron microscope，SEM) 26
3.7 電化學量測 27
3.7.1 循環充放電測試(Cyclic charging-discharging test) 27
3.7.2 交流阻抗分析(Electrochemical impedance spectroscopy, EIS) 27
3.7.3 線性掃描伏安法(Linear Sweep Voltammetry) 28
第四章 結果與討論 29
4.1 單鹽類系統 29
4.1.1 乙醯胺濃度之影響 29
4.1.2 水濃度之影響 33
4.1.3 乙腈濃度之影響 37
4.1.4水與乙腈共同混合之影響 41
4.1.5電解液性質分析 43
4.1.6 最佳組成電解液之性能測試與電解液性質 49
4.1.6.1 性能測試 49
4.1.6.2 電解液性質分析 52
4.1.6.2 電極表面分析 54
4.1.6.3 半電池 56
4.1.7 單鹽類系統綜合討論 62
4.2 雙鹽類系統 62
4.2.1 水與乙腈混合濃度之影響 62
4.2.2 電解液性質分析 67
4.2.3 電極表面分析 69
4.2.4 半電池 73
4.2.5 雙鹽類系統綜合討論 90
第五章 結論 91
第六章 未來工作 93
參考文獻 94

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