臺灣博碩士論文加值系統

本研究利用陽極蝕刻技術通過不同的蝕刻條件可在短時間內完成鈦基奈米柱陣列電極，解決了以往製作高比表面積電極費時的問題。我們發現利用80V電壓進行蝕刻所製備出的陣列電極表現出優異的電化學性能。以三明治結構將柱狀陣列電極、凝膠態電解質與隔膜三者組裝成超級電容器，在0.02V/s的掃描速率下，其比電容值、能量密度與功率密度分別為130.29 F/g、8.87 Wh/kg、692 W/kg。此外，在0.2mA恆電流下進行500,000次的循環充放電測試後發現此超級電容器仍保有初始電容量的94.81%，顯示出其擁有良好的循環壽命及穩定性。

In this study, the anodic etching technique was utilized to produce titanium-based nanoarray electrodes in a short period of time by using different etching conditions, which solved the problem of time-consuming fabrication of high specific surface area electrodes in the past. The array electrodes prepared by etching at 80V showed excellent electrochemical properties. A sandwich structure of cylindrical array electrodes, gel electrolyte, and diaphragm was used to form a supercapacitor, and the specific capacitance, energy density, and power density of the supercapacitor were found to be 130.29 F/g, 8.87 Wh/kg, and 692 W/kg, respectively, at a scan rate of 0.02 V/s. In addition, the supercapacitor retained its initial capacitance after 500,000 cyclic charging and discharging tests at a constant current of 0.2 mA. The supercapacitor still retains 94.81% of the initial capacitance, showing that it has good cycle life and stability.

中文摘要........................................................................................... i
英文摘要........................................................................................... ii
誌謝 ........................................................................................... iii
目錄 ........................................................................................... iv
表目錄........................................................................................... v
圖目錄........................................................................................... vi
第一章緒論................................................................................... 1
1.1 前言................................................................................... 1
1.2 專利檢索........................................................................... 3
第二章實驗內容........................................................................... 5
2.1 實驗藥品........................................................................... 5
2.2 實驗儀器........................................................................... 6
2.3 實驗流程........................................................................... 7
2.3.1 奈米柱陣列電極之製備與分析....................................... 7
2.3.2 具鈦基奈米柱陣列電極之超級電容器的製備與分析... 8
2.4 實驗步驟與分析............................................................... 9
2.4.1 鈦基板前處理................................................................... 9
2.4.2 蝕刻溶液之製備............................................................... 9
2.4.3 鈦基奈米柱陣列電極之製備........................................... 9
2.4.4 TiO2奈米柱陣列電極之製備........................................... 9
2.4.5 表面結構分析................................................................... 10
2.4.6 凝膠電解質之製備........................................................... 10
2.4.7 具有鈦基奈米柱陣列電極的超級電容器之組立與封
裝....................................................................................... 10
2.4.8 電極電化學特性分析....................................................... 10
2.4.9 超級電容器電化學特性分析........................................... 11
第三章結果與討論....................................................................... 12
3.1 電極表面結構分析........................................................... 12
3.2 不同奈米柱陣列電極之X 射線繞射分析結果(XRD)... 13
3.3 不同奈米柱陣列電極電化學分析結果........................... 13
3.4 超級電容器電化學分析結果........................................... 15
第四章結論................................................................................... 16
第五章未來展望........................................................................... 17
參考文獻........................................................................................... 18
英文論文........................................................................................... 41

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