臺灣博碩士論文加值系統

目錄
摘要 I
ABSTRACT II
致謝 III
目錄 IV
圖目錄 VII
表目錄 X
第一章 前言 1
1.1研究起源 1
1.2研究目的 2
第二章 文獻回顧 3
2.1染料概論 3
2.1.1染料種類 3
2.1.2偶氮染料 5
2.1.3偶氮染料廢水處理技術 7
2.2光催化劑和光催化反應 9
2.2.1光催化原理 9
2.2.2二氧化鈦光催化劑 10
2.2.3光催化反應動力模式 11
2.3二氧化鈦製備方法 13
2.3.1二氧化鈦光催化影響因子 14
2.3.2摻雜金屬 15
2.4多孔性材料 20
2.4.1多孔性材料 20
2.4.2多孔性材料 20
2.4.3漂浮型光催化材料 22
2.5田口實驗設計法 28
2.5.1田口法實驗規劃 29
2.5.2田口法直交表 30
2.5.3田口法數據分析 29
第三章 研究方法 32
3.1研究架構 32
3.2研究材料與設備 34
3.2.1實驗藥品 34
3.2.2實驗儀器與設備 34
3.3研究與分析方法 35
3.3.1田口法實驗設計 35
3.3.2 Ce-TiO2光催化劑及無機多孔性光催化材料製備 37
3.3.4光催化實驗 38
3.3.5儀器分析方法 40
第四章 結果與討論 43
4.1田口式實驗設計製備Ce-TiO2 43
4.2 Ce摻雜量對TiO2光催化特性之影響 43
4.2.1甲基橙之光催化降解 48
4.2.2表面型態鑑定（SEM） 60
4.2.3 官能基、晶相及比表面積分析(FTIR&XRD&BET) 67
4.3鍛燒溫度對Ce-TiO2光催化特性之影響 70
4.3.1甲基橙之光催化降解 70
4.3.2表面型態鑑定（SEM） 78
4.3.3官能基、晶相及比表面積分析(FTIR&XRD&BET) 81
4.4 Ce-TiO2無機多孔性光催化材料 84
4.4.1 Ce-TiO2對無機多孔性材料最適添加量 87
4.4.2 Ce-TiO2無機多孔性光催化材料再利用試驗 91
4.5 甲基橙光催化降解之降解途徑及機制 93
第五章 結論與建議 95
5.1 結論 95
5.2 建議 96
第六章 參考文獻 97

英文文獻
Aboukaïs. (2013). Supported manganese oxide on TiO2 for total oxidation of toluene and polycyclic aromatic hydrocarbons (PAHs): characterization and catalytic activity. Materials Chemistry and Physics, 142(2-3), 564-571.
Aeimbhu, A. (2018). Effect of calcination temperature on morphology, wettability and anatase/rutile phase ratio of titanium dioxide nanotube arrays. Materials Today: Proceedings, 5(7), 14950-14954.
Asghar, A.; Raman, A. A. A.; & Daud, W. M. A. W. (2015). Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review. Journal of cleaner production, 87, 826-838.
Astinchap, B.; & Laelabadi, K. G. (2019). Effects of substrate temperature and precursor amount on optical properties and microstructure of CVD deposited amorphous TiO2 thin films. Journal of Physics and Chemistry of Solids, 129, 217-226.
Atout, H.; Álvarez, M. G.; Chebli, D.; Bouguettoucha, A.; Tichit, D.; Llorca, J.; & Medina, F. (2017). Enhanced photocatalytic degradation of methylene blue: Preparation of TiO2/reduced graphene oxide nanocomposites by direct sol-gel and hydrothermal methods. Materials Research Bulletin, 95, 578-587.
Bauer, C.; Jacques, P.; & Kalt, A. (2001). Photooxidation of an azo dye induced by visible light incident on the surface of TiO2. Journal of Photochemistry and Photobiology A: Chemistry, 140(1), 87-92.
Bui, V. K. H.; Nguyen, T. N.; Van Tran, V.; Hur, J.; Kim, I. T.; Park, D.; & Lee, Y.-C. (2021). Photocatalytic materials for indoor air purification systems: An updated mini-review. Environmental Technology & Innovation, 22, 101471.
Cai, W.; Chen, F.; Shen, X.; Chen, L.; & Zhang, J. (2010). Enhanced catalytic degradation of AO7 in the CeO2–H2O2 system with Fe3+ doping. Applied Catalysis B: Environmental, 101(1-2), 160-168.
Cano-Franco, J. C.; & Álvarez-Láinez, M. (2019). Effect of CeO2 content in morphology and optoelectronic properties of TiO2-CeO2 nanoparticles in visible light organic degradation. Materials Science in Semiconductor Processing, 90, 190-197.
Cao, X.; Yang, X.; Li, H.; Huang, W.; & Liu, X. (2017). Investigation of Ce-TiO2 photocatalyst and its application in asphalt-based specimens for NO degradation. Construction and Building Materials, 148, 824-832.
Chen, Q.; Wu, S.; & Xin, Y. (2016). Synthesis of Au–CuS–TiO2 nanobelts photocatalyst for efficient photocatalytic degradation of antibiotic oxytetracycline. Chemical Engineering Journal, 302, 377-387.
Chen, Y.-F.; Lee, C.-Y.; Yeng, M.-Y.; & Chiu, H.-T. (2003). The effect of calcination temperature on the crystallinity of TiO2 nanopowders. Journal of crystal growth, 247(3-4), 363-370.
Choudhury, B.; Borah, B.; & Choudhury, A. (2012). Extending photocatalytic activity of TiO2 nanoparticles to visible region of illumination by doping of cerium. Photochemistry and photobiology, 88(2), 257-264.
Cullity, B.; & Stock, S. (2001). Elements of X-ray diffraction third edition prentice hall upper saddle river. Prince Hall.
Diebold, U. (2003). The surface science of titanium dioxide. Surface science reports, 48(5-8), 53-229.
Gürsoy, M.; & Karaman, M. (2016). Hydrophobic coating of expanded perlite particles by plasma polymerization. Chemical Engineering Journal, 284, 343-350.
Gao, L.; Gan, W.; Xiao, S.; Zhan, X.; & Li, J. (2016). A robust superhydrophobic antibacterial Ag–TiO2 composite film immobilized on wood substrate for photodegradation of phenol under visible-light illumination. Ceramics International, 42(2), 2170-2179.
Gao, Y.; Wang, L.; Zhou, A.; Li, Z.; Chen, J.; Bala, H.; Hu, Q.; & Cao, X. (2015). Hydrothermal synthesis of TiO2/Ti3C2 nanocomposites with enhanced photocatalytic activity. Materials Letters, 150, 62-64.
Gnanasekaran, L.; Rajendran, S.; Priya, A.; Durgalakshmi, D.; Vo, D.-V. N.; Cornejo-Ponce, L.; Gracia, F.; & Soto-Moscoso, M. (2021). Photocatalytic degradation of 2, 4-dichlorophenol using bio-green assisted TiO2–CeO2 nanocomposite system. Environmental Research, 195, 110852.
Hot, J.; Topalov, J.; Ringot, E.; & Bertron, A. (2017). Investigation on parameters affecting the effectiveness of photocatalytic functional coatings to degrade NO:TiO2 amount on surface, illumination, and substrate roughness. International Journal of Photoenergy, 2017.
Hu, Y.; Ren, X.; Qiao, H.; Huang, Z.; Qi, X.; & Zhong, J. (2017). Exploring co-catalytic graphene frameworks for improving photocatalytic activity of Tin disulfide nanoplates. Solar Energy, 157, 905-910.
Huo, Y.; Jin, Y.; Zhu, J.; & Li, H. (2009). Highly active TiO2− x− yNxFy visible photocatalyst prepared under supercritical conditions in NH4F/EtOH fluid. Applied Catalysis B, Environmental, 89(3-4), 543-550.
Jia, L.; Wu, C.; Li, Y.; Han, S.; Li, Z.; Chi, B.; Pu, J.; & Jian, L. (2011). Enhanced visible-light photocatalytic activity of anatase TiO2 through N and S codoping. Applied Physics Letters, 98(21).
Jia, Z.-M.; Zhao, Y.-R.; & Shi, J.-N. (2023). Adsorption kinetics of the photocatalytic reaction of nano-TiO2 cement-based materials: a review. Construction and Building Materials, 370, 130462.
Jiang, B.; Tian, C.; Zhou, W.; Wang, J.; Xie, Y.; Pan, Q.; Ren, Z.; Dong, Y.; Fu, D.; & Han, J. (2011). In situ growth of TiO2 in interlayers of expanded graphite for the fabrication of TiO2–graphene with enhanced photocatalytic activity. Chemistry–A European Journal, 17(30), 8379-8387.
Jiang, D.; Otitoju, T. A.; Ouyang, Y.; Shoparwe, N. F.; Wang, S.; Zhang, A.; & Li, S. (2021). A review on metal ions modified TiO2 for photocatalytic degradation of organic pollutants. Catalysts, 11(9), 1039.
Karakurt, C.; Kurama, H.; & Topcu, I. B. (2010). Utilization of natural zeolite in aerated concrete production. Cement and Concrete Composites, 32(1), 1-8.
Kasinathan, K.; Kennedy, J.; Elayaperumal, M.; Henini, M.; & Malik, M. (2016). Photodegradation of organic pollutants RhB dye using UV simulated sunlight on ceria based TiO2 nanomaterials for antibacterial applications. Scientific reports, 6(1), 38064.
Keerthana, S.; Yuvakkumar, R.; Ravi, G.; Hong, S.; Al-Sehemi, A. G.; & Velauthapillai, D. (2022). Fabrication of Ce doped TiO2 for efficient organic pollutants removal from wastewater. Chemosphere, 293, 133540.
Khairy, M.; & Zakaria, W. (2014). Effect of metal-doping of TiO2 nanoparticles on their photocatalytic activities toward removal of organic dyes. Egyptian Journal of Petroleum, 23(4), 419-426.
Komaraiah, D.; Madhukar, P.; Vijayakumar, Y.; Reddy, M. R.; & Sayanna, R. (2016). Photocatalytic degradation study of methylene blue by brookite TiO2 thin film under visible light irradiation. Materials Today: Proceedings, 3(10), 3770-3778.
Komaraiah, D.; Radha, E.; Reddy, M. R.; Kumar, J. S.; & Sayanna, R. (2019). Structural, Optical Properties and Photocatalytic Activity of Nanocrystalline TiO2 Thin Films Deposited by Sol–Gel Spin Coating. i-Manager's Journal on Material Science, 7(1), 28.
Li, G.; Li, J.; Li, G.; & Jiang, G. (2015). N and Ti 3+ co-doped 3D anatase TiO2 superstructures composed of ultrathin nanosheets with enhanced visible light photocatalytic activity. Journal of Materials Chemistry A, 3(44), 22073-22080.
Linsebigler, A. L.; Lu, G.; & Yates Jr, J. T. (1995). Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results. Chemical reviews, 95(3), 735-758.
Lutic, D.; Petrovschi, D.; Ignat, M.; Creţescu, I.; & Bulai, G. (2018). Mesoporous cerium-doped titania for the photocatalytic removal of persistent dyes. Catalysis Today, 306, 300-309.
Madriz, L.; Tatá, J.; Carvajal, D.; Núñez, O.; Scharifker, B. R.; Mostany, J.; Borrás, C.; Cabrerizo, F. M.; & Vargas, R. (2020). Photocatalysis and photoelectrochemical glucose oxidation on Bi2WO6: Conditions for the concomitant H2 production. Renewable Energy, 152, 974-983.
Magalhães, F.; & Lago, R. (2009). Floating photocatalysts based on TiO2 grafted on expanded polystyrene beads for the solar degradation of dyes. Solar Energy, 83(9), 1521-1526.
Maira, A.; Yeung, K. L.; Lee, C.; Yue, P. L.; & Chan, C. K. (2000). Size effects in gas-phase photo-oxidation of trichloroethylene using nanometer-sized TiO2 catalysts. Journal of catalysis, 192(1), 185-196.
Makdee, A.; Unwiset, P.; Chanapattharapol, K. C.; & Kidkhunthod, P. (2018). Effects of Ce addition on the properties and photocatalytic activity of TiO2, investigated by X-ray absorption spectroscopy. Materials Chemistry and Physics, 213, 431-443.
Maki, L. K.; Maleki, A.; Rezaee, R.; Daraei, H.; & Yetilmezsoy, K. (2019). LED-activated immobilized Fe-Ce-N tri-doped TiO2 nanocatalyst on glass bed for photocatalytic degradation organic dye from aqueous solutions. Environmental Technology & Innovation, 15, 100411.
Maksod, I. H.; Al-Shehri, A.; Bawaked, S.; Mokhtar, M.; & Narasimharao, K. (2017). Structural and photocatalytic properties of precious metals modified TiO2-BEA zeolite composites. Molecular Catalysis, 441, 140-149.
Marcos, C.; & Rodriguez, I. (2015). Vermiculites irradiated with ultraviolet radiation. Applied Clay Science, 109, 127-135.
Mills, A.; Wang, J.; & Ollis, D. F. (2006). Dependence of the kinetics of liquid-phase photocatalyzed reactions on oxygen concentration and light intensity. Journal of catalysis, 243(1), 1-6.
Mohammadi, Z.; Sharifnia, S.; & Shavisi, Y. (2016). Photocatalytic degradation of aqueous ammonia by using TiO2ZnO/LECA hybrid photocatalyst. Materials Chemistry and Physics, 184, 110-117.
Mutuma, B. K.; Shao, G. N.; Kim, W. D.; & Kim, H. T. (2015). Sol–gel synthesis of mesoporous anatase–brookite and anatase–brookite–rutile TiO2 nanoparticles and their photocatalytic properties. Journal of colloid and interface science, 442, 1-7.
Nasir, A. M.; Goh, P. S.; Abdullah, M. S.; Ng, B. C.; & Ismail, A. F. (2019). Adsorptive nanocomposite membranes for heavy metal remediation: recent progresses and challenges. Chemosphere, 232, 96-112.
Nasir, A. M.; Jaafar, J.; Aziz, F.; Yusof, N.; Salleh, W. N. W.; Ismail, A. F.; & Aziz, M. (2020). A review on floating nanocomposite photocatalyst: fabrication and applications for wastewater treatment. Journal of Water Process Engineering, 36, 101300.
Ni, M.; Leung, M. K.; Leung, D. Y.; & Sumathy, K. (2007). A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production. Renewable and Sustainable Energy Reviews, 11(3), 401-425.
Nuasaen, S.; Opaprakasit, P.; & Tangboriboonrat, P. (2014). Hollow latex particles functionalized with chitosan for the removal of formaldehyde from indoor air. Carbohydrate polymers, 101, 179-187.
Nur, A. S.; Sultana, M.; Mondal, A.; Islam, S.; Robel, F. N.; Islam, A.; & Sumi, M. S. A. (2022). A review on the development of elemental and codoped TiO2 photocatalysts for enhanced dye degradation under UV–vis irradiation. Journal of Water Process Engineering, 47, 102728.
Paul, K. K.; Ghosh, R.; & Giri, P. (2016). Mechanism of strong visible light photocatalysis by Ag2O-nanoparticle-decorated monoclinic TiO2 (B) porous nanorods. Nanotechnology, 27(31), 315703.
Rapsomanikis, A.; Apostolopoulou, A.; Stathatos, E.; & Lianos, P. (2014). Cerium-modified TiO2 nanocrystalline films for visible light photocatalytic activity. Journal of Photochemistry and Photobiology A: Chemistry, 280, 46-53.
Reli, M.; Ambrožová, N.; Šihor, M.; Matějová, L.; Čapek, L.; Obalová, L.; Matěj, Z.; Kotarba, A.; & Kočí, K. (2015). Novel cerium doped titania catalysts for photocatalytic decomposition of ammonia. Applied Catalysis B: Environmental, 178, 108-116.
Saad, A. M.; Abukhadra, M. R.; Ahmed, S. A.-K.; Elzanaty, A. M.; Mady, A. H.; Betiha, M. A.; Shim, J.-J.; & Rabie, A. M. (2020). Photocatalytic degradation of malachite green dye using chitosan supported ZnO and Ce–ZnO nano-flowers under visible light. Journal of environmental management, 258, 110043.
Shan, A. Y.; Ghazi, T. I. M.; & Rashid, S. A. (2010). Immobilisation of titanium dioxide onto supporting materials in heterogeneous photocatalysis: A review. Applied Catalysis A: General, 389(1-2), 1-8.
Sharifi, E.; Sadjadi, S. J.; Aliha, M.; & Moniri, A. (2020). Optimization of high-strength self-consolidating concrete mix design using an improved Taguchi optimization method. Construction and Building Materials, 236, 117547.
Shayegan, Z.; Haghighat, F.; & Lee, C.-S. (2020). Surface fluorinated Ce-doped TiO2 nanostructure photocatalyst: A trap and remove strategy to enhance the VOC removal from indoor air environment. Chemical Engineering Journal, 401, 125932.
Spasiano, D.; Marotta, R.; Malato, S.; Fernandez-Ibanez, P.; & Di Somma, I. (2015). Solar photocatalysis: Materials, reactors, some commercial, and pre-industrialized applications. A comprehensive approach. Applied Catalysis B: Environmental, 170, 90-123.
Tong, T.; Zhang, J.; Tian, B.; Chen, F.; He, D.; & Anpo, M. (2007). Preparation of Ce–TiO2 catalysts by controlled hydrolysis of titanium alkoxide based on esterification reaction and study on its photocatalytic activity. Journal of colloid and interface science, 315(1), 382-388.
Wang, X.; Wang, X.; Zhao, J.; Song, J.; Wang, J.; Ma, R.; & Ma, J. (2017). Solar light-driven photocatalytic destruction of cyanobacteria by F-Ce-TiO2/expanded perlite floating composites. Chemical Engineering Journal, 320, 253-263.
Xing, Z.; Zhang, J.; Cui, J.; Yin, J.; Zhao, T.; Kuang, J.; Xiu, Z.; Wan, N.; & Zhou, W. (2018). Recent advances in floating TiO2-based photocatalysts for environmental application. Applied Catalysis B: Environmental, 225, 452-467.
Yahya, N.; Aziz, F.; Jamaludin, N.; Mutalib, M.; Ismail, A.; Salleh, W.; Jaafar, J.; Yusof, N.; & Ludin, N. (2018). A review of integrated photocatalyst adsorbents for wastewater treatment. Journal of environmental chemical engineering, 6(6), 7411-7425.
Zhang, L.; Xing, Z.; Zhang, H.; Li, Z.; Zhang, X.; Zhang, Y.; Li, L.; & Zhou, W. (2015). Multifunctional floating titania‐coated macro/mesoporous photocatalyst for efficient contaminant removal. ChemPlusChem, 80(3), 623-629.
Zhang, Y.; Bao, H.; Miao, F.; Shen, Y.; He, Y.; Gu, W.; Meng, Q.; Wang, W.; & Zhang, J. (2013). Characterization of a monoclonal antibody to Spiroplasma eriocheiris and identification of a motif expressed by the pathogen. Veterinary microbiology, 161(3-4), 353-358.
Zheng, F.; Dong, F.; Zhou, L.; Yu, J.; Luo, X.; Zhang, X.; Lv, Z.; Jiang, L.; Chen, Y.; & Liu, M. (2023). Cerium and carbon-sulfur codoped mesoporous TiO2 nanocomposites for boosting visible light photocatalytic activity. Journal of Rare Earths, 41(4), 539-549.
Zong, E.; Wang, C.; Yang, J.; Zhu, H.; Jiang, S.; Liu, X.; & Song, P. (2021). Preparation of TiO2/cellulose nanocomposites as antibacterial bio-adsorbents for effective phosphate removal from aqueous medium. International Journal of Biological Macromolecules, 182, 434-444.
中文文獻
李輝煌，2013。田口方法品質設計的原理與實務，第四版，新北市：高立圖書有限公司。
工研院IEK化材組，2006。特用化學品工業年鑑，工研院產業經濟與資訊服務中心。
黃國軒，2006。利用TiO2結合奈米碳管降解偶氮系染料之研究，國立雲林科技大學，環境與安全衛生工程系，碩士論文。
盧明俊，1993。毒性化學物質經二氧化鈦催化之光氧化反應，國立交通大學土木工程學系，碩士論文。
鍾朝全，2001。以UV/TiO2程序進行甲基橙溶液脫色反應之研究，第二十六屆廢水處理技術研討會論文集，頁1-105。
侯冠任，2019。摻鈰二氧化鈦光催化及降解剛果紅之效能研究，國立雲林科技大學，碩士論文。