摘要 i
Abstract iii
致謝 v
目錄 vi
表目錄 ix
圖目錄 x
第一章　緒論 1
1-1 前言 1
1-2 研究動機 2
第二章　研究背景與理論 4
2-1 奈米科技 4
2-2 金屬奈米粒子及核殼型奈米金屬 5
2-3 表面電漿共振 6
2-4 奈米粒子熔點與粒徑的關係 8
2-5 奈米粒子的燒結機制 9
2-6 製備銅銀核殼奈米粒子之文獻回顧 11
2-6-1 奈米粒子的製備方法 11
2-6-2 製備核殼奈米粒子 12
2-7 微胞合成法 16
2-7-1 界面活性劑 16
2-7-2 功能型界面活性劑 17
2-7-3 微胞及逆微胞 18
2-7-4 單相微胞 19
第三章　實驗程序 20
3-1 實驗藥品 20
3-2 儀器設備 23
3-3 實驗步驟 26
3-3-1 共還原法 26
3-3-2 兩步法 29
3-3-3 銅銀奈米粒子製備反應機制 33
第四章　結果與討論 35
4-1 合成手法之選擇 35
4-2 DBSA與氧化物(I)(II)金屬反應機制 38
4-3 Capping agent量的調整 41
4-4 還原劑選擇及濃度的調整 42
4-5 共還原法合成Ag-Cu NPs之鑑定 42
4-5-1 X射線衍射儀(XRD)分析 42
4-5-2 紫外/可見光譜儀(UV-vis)分析 44
4-5-3 熱重分析儀(TGA)分析 46
4-5-4 高解析穿透式電子顯微鏡(HR-TEM)分析 49
4-6 兩步法合成Cu-Ag core-shell NPs之鑑定 52
4-6-1 實驗原理討論 52
4-6-2 X射線衍射儀(XRD)分析 55
4-6-3 紫外/可見光譜儀(UV-vis)分析 58
4-6-4 熱重分析儀(TGA)分析 60
4-6-5 高解析穿透式電子顯微鏡(HR-TEM)分析 64
4-6-6 微示差掃描熱卡分析儀(DSC)分析 69
4-6-7 高解析場發射掃描式電子顯微鏡(FE-SEM)分析 76
4-6-7-1 未經燒結銅銀核殼奈米粒子表徵分析 76
4-6-7-2 銅銀核殼奈米粒子燒結後的表徵分析 83
4-6-8 油墨表面電阻及燈泡實驗 91
第五章　結論 95
參考文獻 97

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