臺灣博碩士論文加值系統

摘要 i
Abstract iii
誌謝 v
目錄 vi
表目錄 x
圖目錄 xi
第一章 緒論 1
1.1 前言 1
1.2 研究動機 2
第二章 文獻回顧 3
2.1 燃料電池簡介 3
2.2 燃料電池發電原理 4
2.3 燃料電池優點 5
2.4 燃料電池種類與應用 7
2.5 陰離子交換膜燃料電池(AEMFC) 9
2.5.1 AEMFC之原理 10
2.5.2 陰離子交換膜燃料電池之構造及元件 10
2.5.3 陰離子交換膜 11
2.5.4 觸媒層(Catalyst Layer；CL) 12
2.5.5 氣體擴散層(Gas Diffusion Layer; GDL) 13
2.5.6 雙極板(Bipolar Plates; BP) 14
2.5.7 膜電極組(Membrane Electrode Assembly; MEA) 15
2.6 氧氣還原反應 15
2.7 非貴金屬觸媒 17
2.7.1 氮摻雜於碳材料(Nitrogen-doped carbon materials) 18
2.8 電極動力學與電池極化反應現象 21
第三章 實驗 23
3.1實驗藥品 23
3.2儀器設備 26
3.3實驗步驟 30
3.3.1觸媒前驅物製備 30
3.3.2煅燒溫度之觸媒製備 30
3.3.3線性掃描伏安法(LSV)測定 34
3.3.4膜電極組(MEA)製備 35
第四章 結果與討論 38
4.1官能基分析(FTIR) 38
4.2表面型態分析 39
4.2.1 TEM分析 39
4.2.2 HR-TEM分析 41
4.2.2 SEM分析 42
4.3結晶性分析(XRD) 43
4.4有序性分析(RAMAN) 44
4.5能量色散X-射線光譜分析(EDS，mapping) 45
4.5.1 SEM之能量色散X-射線光譜分析(EDS，mapping) 45
4.5.2 HR-TEM之能量色散X-射線光譜分析(EDS，mapping) 47
4.6表面性質分析(BET) 48
4.7導電度測試 51
4.8觸媒之電化學分析 52
4.8.1 LSV(Linear Sweep Voltammetry，LSV) 52
4.8.2 CV測試 (Cyclic voltammetry) 53
4.8.3 單電池分析 54
第五章 結論 55
第六章 參考文獻 56

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