臺灣博碩士論文加值系統

隨著科技業的蓬勃發展，UV單體等材料在製造過程中會產生大量工業副產品下層液，若能將此工業副產物加以循環利用，讓身為工業副產物的UV單體製成下層液用以作為化學摻料添加於混凝土改善之工程性質，不僅可以有效減少工業副產物後續處理等問題，更能讓下層液有效利用創造全新的價值，達到工業副產物資源化和永續循環之經濟目標。本研究以UV單體製成下層液分三階段，第一階段以不同水灰比0.3、0.4及0.5，及UV單體製成下層液以不同添加量0%、5%、10%及15%；第二階段固定水灰比0.5，及UV單體製成下層液以不同添加量0%、5%、10%及15%；第三階段固定水灰比0.5，及UV單體製成下層液以不同添加量0%、1%、2%及4%，製成混凝土試體，探討添加後對於工程性質之影響，評估UV單體製成下層液添加之可行性，將工業副產物做充分有效之資源再利用。
研究結果顯示，以UV單體製成下層液作為化學摻料添加於混凝土提升新拌性質，坍度以水灰比0.5第二階段添加量5%之UV單體製成下層液和第三階段添加量4%之UV單體製成下層液為最佳22.5 cm，減水率以水灰比0.3第一階段添加量15%之UV單體製成下層液為最佳25.01%，凝結時間以水灰比0.5第二階段添加量15%之UV單體製成下層液為最佳初凝為425分鐘，終凝為712分鐘。工程性質也同樣有明顯提昇之趨勢，以第三階段水灰比0.5，添加量4%之UV單體製成下層液有最佳力學性質。當齡期91天時，此組超音波波速達到4784m/s與電阻值35.6 kΩ-cm，顯示UV單體製成下層液能使混凝土試體有最佳之耐久性，同時具有最佳抗硫酸鹽侵蝕能力，重量損失率為-0.44%。

With the vigorous development of the technology industry, materials such as UV monomers will produce a large number of industrial by-products in the manufacturing process. If the industrial by-products can be recycled, the industrial by-products can be used as chemical admixtures to improve concrete The nature of the project can not only effectively reduce the follow-up treatment of industrial by-products, but also effectively use them to create new value and achieve the economic goals of recycling industrial by-products and sustainable recycling. In this study, UV monomer by-products are divided into three stages. In the first stage, different water-cement ratios are 0.3, 0.4 and 0.5, and UV monomer by-products are added in different amounts of 0%, 5%, 10% and 15%. The water-cement ratio is 0.5, and UV monomer by-products are added in different amounts of 0%, 5%, 10% and 15%; in the third stage, the water-cement ratio is fixed at 0.5, and UV monomer by-products are added in different amounts of 0%, 1%, 2% and 4%, made into concrete test body, discussing the impact on engineering properties after adding, evaluating the feasibility of adding UV monomer by-products, and making full and effective resource reuse of industrial by-products.
The research results show that the addition of UV monomer by-products as chemical admixtures to concrete can effectively improve the fresh-mixed properties. The slump is based on the water-cement ratio of 0.5, the addition of 5% UV monomer by-products in the second stage and the addition of 4% in the third stage. The best UV monomer by-product is 22.5 cm, and the water-cement ratio is 0.3. The best water-cement ratio is 15%. The UV monomer by-product is the best 25.01%. The setting time is 0.5. The UV monomer by-product is the best initial setting of 425 minutes, final setting of 712 minutes. The engineering properties also have a tendency to be significantly improved. In the third stage, the water-cement ratio is 0.5, and the by-product of UV monomer with an addition amount of 4% has the best mechanical properties. When the age was 91 days, the ultrasonic wave velocity of this group reached 4784m/s and the resistance value was 35.6 kΩ-cm, showing that the by-product of UV monomer can make the concrete specimen have the best durability and the best resistance to sulfate erosion. , and the weight loss rate was -0.44%.

摘要 i
ABSTRACT ii
誌謝 iv
目錄 v
表目錄 viii
圖目錄 ix
第一章 緒論 1
1-1 研究動機 1
1-2 研究目的 2
1-3 研究流程 3
第二章 文獻回顧 4
2-1 波特蘭水泥 4
2-1-1水泥製程與基本性質 4
2-1-2水泥水化反應 4
2-1-3水泥漿體孔隙結構生成物 7
2-2化學摻料種類及用途 10
2-3強塑劑 10
2-3-1強塑劑介紹 10
2-3-2常見強塑劑種類 11
2-3-3強塑劑減水機理 11
2-4化學摻料對混凝土性質影響 13
2-4-1工作度 13
第三章 試驗計畫 20
3-1 試驗材料 20
3-2 試驗變數及配比 21
3-3 試驗項目與規範 22
3-4 試驗儀器與設備 25
第四章 結果與分析 35
4-1第一階段試驗(Type1) 35
4-1-1新拌性質 35
4-1-2抗壓強度 38
4-1-3劈裂強度 40
4-1-4超音波波速 42
4-2第二階段試驗(Type2) 44
4-2-1新拌性質 44
4-2-2抗壓強度 45
4-3第三階段試驗(Type3) 46
4-3-1新拌性質 47
4-3-2抗壓強度 48
4-3-3劈裂強度 49
4-3-4超音波波速 50
4-3-5四極式電阻試驗 50
4-3-6吸水率試驗 51
4-3-7耐硫酸鹽侵蝕試驗 52
4-3-8微觀分析 52
4-4各階段試驗小結 53
4-4-1坍度 53
4-4-2減水率 53
4-4-3氯離子檢測 54
4-4-4抗壓強度 54
第五章 結論與建議 77
5-1 結論 77
5-1-1 第一階段試驗 77
5-1-2 第二階段試驗 77
5-1-3 第三階段試驗 78
5-1-4 各階段試驗 78
5-2 建議 78
參考文獻 79
作者簡歷 83

1.黃兆龍，2006，混凝土性質與行為，詹氏書局。
2.陳昱文，2020，爐石粉與不銹鋼還原碴取代水泥製成水泥(砂)漿工程性質之研究，國立高雄科技大學土木工程科技研究所，碩士論文。
3.Ibrahim, S., & Meawad, A. (2022). Towards green concrete: Study the role of waste glass powder on cement/superplasticizer compatibility. Journal of Building Engineering, 47, 103751.
4.Breilly, D., Fadlallah, S., Froidevaux, V., Colas, A., & Allais, F. (2021). Origin and industrial applications of lignosulfonates with a focus on their use as superplasticizers in concrete. Construction and Building Materials, 301, 124065.
5.羅心妤，2003，強塑劑質與量對混凝土性質之影響，國立台灣科技大學營建工程系，碩士論文。
6.陳昱仁，2017，常溫合成緩釋保坍型聚羧酸強塑劑特性探討，國立高雄第一科技大學營建研究所，碩士論文。
7.黃彥傑，2015，常溫合成泛用型高保塑羧酸強塑劑之開發研究，國立高雄第一科技大學營建研究所，碩士論文。
8.鄭任軒，2022，以飛灰取代爐石粉改善超硫酸鹽水泥漿體之可行性，國立高雄科技大學土木工程系，碩士論文。
9.周俊佑，2021，含爐石粉之再生瀝青水泥砂漿工程性質研究，國立高雄科技大學土木工程系，碩士論文。
10.Macphee, D. E., & Folli, A. (2016). Photocatalytic concretes—The interface between photocatalysis and cement chemistry. Cement and Concrete Research, 85, 48-54.
11.Jiang, Y., Ling, T. C., Shi, C., & Pan, S. Y. (2018). Characteristics of steel slags and their use in cement and concrete—A review. Resources, Conservation and Recycling, 136, 187-197.
12.黃兆龍，2012，新編混凝土材料品質控制試驗，詹氏書局。
13.曾仕文，2012，電弧爐還原硫應用於控制性低強度材料及其安定化成效評估研究，國立中央大學土木工程學系，碩士論文。
14.林柏彰，2012，還原爐確取代水泥性質之研究，國立台北科技大學土木與防災研究所，碩士論文。
15.吳悅婷，2015，添加不銹鋼還原碴自充填混凝土工程性質預測模式之探討，國立高雄應用科技大學土木工程與防災科技研究所，碩士論文。
16.Dang, J., Du, H., & Dai Pang, S. (2020). Hydration, strength and microstructure evaluation of eco-friendly mortar containing waste marine clay. Journal of Cleaner Production, 272, 122784.
17.Mohamed, A. K., Parker, S. C., Bowen, P., & Galmarini, S. (2018). An atomistic building block description of CSH-Towards a realistic CSH model. Cement and Concrete Research, 107, 221-235.
18.Patel, R. A., Perko, J., Jacques, D., De Schutter, G., Ye, G., & Van Bruegel, K. (2018). Effective diffusivity of cement pastes from virtual microstructures: Role of gel porosity and capillary pore percolation. Construction and Building Materials, 165, 833-845.
19.Abid, M., Hou, X., Zheng, W., & Hussain, R. R. (2017). High temperature and residual properties of reactive powder concrete–A review. Construction and Building Materials, 147, 339-351.
20.Zhang, Y., Chang, J., & Ji, J. (2018). AH3 phase in the hydration product system of AFt-AFm-AH3 in calcium sulfoaluminate cements: A microstructural study. Construction and Building Materials, 167, 587-596.
21.Durgun, M. Y., & Sevinc, A. H. (2019). High temperature resistance of concretes with GGBFS, waste glass powder, and colemanite ore wastes after different cooling conditions. Construction and Building Materials, 196, 66-81.
22.Whittaker, M., Zajac, M., Haha, M. B., Bullerjahn, F., & Black, L. (2014). The role of the alumina content of slag, plus the presence of additional sulfate on the hydration and microstructure of Portland cement-slag blends. Cement and Concrete Research, 66, 91-101.
23.留銘駿，2012，石材貼覆混凝土試體火害承載行為研究，逢甲大學土木工程所，碩士論文。
24.Zhang, Q., Ye, G., & Koenders, E. (2013). Investigation of the structure of heated Portland cement paste by using various techniques. Construction and Building Materials, 38, 1040-1050.
25.Yamini, G., Shakeri, A., Zohuriaan-Mehr, M. J., & Kabiri, K. (2018). Cyclocarbonated lignosulfonate as a bio-resourced reactive reinforcing agent for epoxy biocomposite: from natural waste to value-added bio-additive. Journal of CO2 Utilization, 24, 50-58.
26.Yu, G., Li, B., Wang, H., Liu, C., & Mu, X. (2013). Preparation of concrete superplasticizer by oxidation-sulfomethylation of sodium lignosulfonate. BioResources, 8(1), 1055-1063.
27.黃兆龍，2001，強塑劑的質與量對混凝土性質的影響，強塑劑於混凝土應用，PP129-154，台灣營建研究院。
28.賴瑞星，2020，高性能混凝土，詹氏書局。
29.Ghosal, M., & Chakraborty, A. K. (2022). Superplasticizer compatibility with cement properties–A study. Materials Today: Proceedings, 56, 568-573.
30.Zhang, J., Ma, Y., Wang, J., Gao, N., Hu, Z., Liu, J., & Wang, K. (2022). A novel shrinkage-reducing polycarboxylate superplasticizer for cement-based materials: Synthesis, performance and mechanisms. Construction and Building Materials, 321, 126342.
31.Altun, M. G., Özen, S., & Mardani-Aghabaglou, A. (2020). Effect of side chain length change of polycarboxylate-ether based high range water reducing admixture on properties of self-compacting concrete. Construction and Building Materials, 246, 118427.
32.Liu, J., Yu, C., Shu, X., Ran, Q., & Yang, Y. (2019). Recent advance of chemical admixtures in concrete. Cement and Concrete Research, 124, 105834.
33.Wang, C., Kong, F., & Pan, L. (2021). Effects of polycarboxylate superplasticizers with different side-chain lengths on the resistance of concrete to chloride penetration and sulfate attack. Journal of Building Engineering, 43, 102817.
34.Alaka, H. A., & Oyedele, L. O. (2016). High volume fly ash concrete: The practical impact of using superabundant dose of high range water reducer. Journal of Building Engineering, 8, 81-90.
35.Yaphary, Y. L., Lam, R. H., & Lau, D. (2020). Reduction in cement content of normal strength concrete with used engine oil (UEO) as chemical admixture. Construction and Building Materials, 261, 119967.
36.Benaicha, M., Alaoui, A. H., Jalbaud, O., & Burtschell, Y. (2019). Dosage effect of superplasticizer on self-compacting concrete: correlation between rheology and strength. Journal of Materials Research and Technology, 8(2), 2063-2069.
37.Talukdar, S., & Heere, R. (2019). The effects of pumping on the air content and void structure of air-entrained, wet mix fibre reinforced shotcrete. Case Studies in Construction Materials, 11, e00288.
38.Zhang, X., Akber, M. Z., & Zheng, W. (2022). Predicting the slump of industrially produced concrete using machine learning: A multiclass classification approach. Journal of Building Engineering, 58, 104997.
39.Lei, L., Hirata, T., & Plank, J. (2022). 40 years of PCE superplasticizers-History, current state-of-the-art and an outlook. Cement and Concrete Research, 157, 106826.
40.江奇成、蔡明達、顏翻竫、黃兆龍，2014，高強度高性能混凝土工作性與水化熱之研究，第十六屆全國技術及職業教育研討會，p41~50，工業類，土木建築組論文集。
41.Łaźniewska-Piekarczyk, B. (2014). The methodology for assessing the impact of new generation superplasticizers on air content in self-compacting concrete. Construction and Building Materials, 53, 488-502.
42.Nowak-Michta, A. (2019). Impact analysis of air-entraining and superplasticizing admixtures on concrete compressive strength. Procedia Structural Integrity, 23, 77-82