臺灣博碩士論文加值系統

廢鍍液處理一直是令人頭痛的問題，但其所含的高濃度金屬卻又充滿了回收再利用的價值。以鐵氧磁體程序(Ferrite Process, FP)將廢鍍液中的重金屬合成鐵氧磁體(Ferrite)堪稱最佳的再利用途徑，其產品可以作為電磁波吸收材料、磁性標示或觸媒。然而，廢鍍液中往往含有大量的有機物，其中螯合劑和界面活性劑會嚴重干擾FP之進行必須事先去除。
雙流加藥半批式芬頓法(Two Dosing Streams Semibatch Fenton Method, TDSSFM)是一種新發展的芬頓反應型式，其優勢在於能藉由控制H2O2和Fe2+的添加速率使反應溶液的溫度產生一高峰值以作為有機物完全被礦化的指標。
本研究利用TDSSFM作為FP的前處理程序，針對電鍍鎳、鹼性化學鍍鎳、酸性化學鍍鎳、電鍍鋅…等各種來自工廠的廢鍍液進行處理。實驗結果顯示實施TDSSFM時，50%的H2O2溶液和20%（w/w）的FeSO4.7H2O溶液以每公升廢液每分鐘各添加6 mL之速率為最佳操作參數。FP則固定在溫度85oC、pH9.5之下曝氣反應兩小時即可完成。經以上程序所製得的產品以X光繞射圖譜比對可證明為鐵氧磁體，且處理後的放流水無論是重金屬或化學需氧量均能符合法規標準。

The treatment of waste plating liquid has always been a question ,but the high concentration of metal contain in it is full of recycle value. The ferrite process (Ferrite Process, FP)is used to synthesize the metal in the waste plating liquid into Ferrite is the best way to reuse. Its products can be use as electromagnetic wave absorbing materials, magnetic signs or catalysts. However, the waste plating liquid often contains a large amount of organic matter, in which the chelating agent and surfactant will seriously interfere with the FP and must be removed in advance. Two Dosing Streams Semibatch Fenton Method (TDSSFM) is a newly developed Fenton reaction type. Its advantage is that it can produce a peak in the temperature of the reaction by controlling the addition rate of H2O2 and Fe2+. The value is used as an indicator that the organic matter is completely mineralized. In this study, TDSSFM was used as the pre-treatment procedure for FP to deal with various types of waste plating liquid from the factory such as electroplating nickel, alkaline electroless plating nickel, acidic electroless plating nickel, electroplating zinc. The results show that when TDSSFM is implemented, 50%H2O2 solution and 20%(w/w) FeSO4.7H2O solution are the best operating parameters at a rate of 6 mL per litter of waste plating liquid add per minute. FP is mixed at a temperature of 85oC and a pH of 9.5 to keep reaction for two hours. The obtained products were proved to be ferrite by X-ray, and the discharge water after treatment can meet the regulations and standards whether it is metals or chemical oxygen demand.

摘 要 i
Abstract iii
誌謝 iv
圖目錄 vii
表目錄 xi
第一章 緒論 1
1-1研究目的 1
1-2 研究方法 2
第二章 文獻回顧 3
2-1 台灣現行放流水標準法規 3
2-2 電鍍工廠排放廢鍍液之處理 5
2-2-1 廢鍍液處理方法 5
2-2-2 工業廢水處理技術 7
2-3 芬頓法 12
2-3-1 FM簡介 12
2-3-2 影響FM反應效率之因子 20
2-4 鐵氧磁體程序 30
2-4-1 鐵氧磁體特性 33
2-4-2 鐵氧磁體的應用 33
2-5 COD的分析方法 35
2-5-1 重鉻酸鉀迴流法 36
2-5-2 密閉式重鉻酸鉀迴流法 39
2-5-3 高錳酸鉀滴定法 39
第三章 研究方法與實驗設備 41
3-1 實驗藥品及設備 41
3-1-1 FM 41
3-1-2 COD 42
3-1-3 FP 43
3-2 研究規劃 44
3-2-1 實驗規劃 44
3-3 研究方法 45
3-3-1 TDSSFM 45
3-3-2 FP 46
第四章 結果與討論 51
4-1 廢鍍液基本性質分析 51
4-2 廢鍍液處理之成效 52
4-2-1 電鍍鎳廢液 52
4-2-2 鹼性化學鍍鎳廢液 54
4-2-3 酸性化學鍍鎳廢液a 56
4-2-4 酸性化學鍍鎳廢液b 58
4-2-5 電鍍鋅廢液 62
4-2-6 處理後的放流水水質 64
4-3 TDSSFM之最佳操作參數 65
第五章 結論 68
參考文獻 69

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