本研究以探討6063 鋁合金陽極處理所生成多孔陽極皮膜為主軸。經由退火、
時效硬化與輥軋變形後，觀察其微結構、晶界角度分佈與析出物型態。再陽極處
理，並討論基地結構對陽極皮膜的影響。分析陽極過程中電壓與時間(V-t)變化曲
線，透過SEM 觀察前製程的微結構對陽極多孔皮膜生長行為的影響。並在V-t 曲
線的第四階段使用二次離子質譜儀(SIMS)與第二階段使用光電子能譜儀(XPS)分
析陽極皮膜組成成分。
由實驗結果發現到，EBSD 分析(O, O-T4-T6, O-rolling40%-T4-T6)晶界在中
高角度; O-T4-rolling40%-T6 觀察，晶界從中高角度大量轉變為低角度，因此6063
鋁合金經輥軋後微結構發生變化會影響Mg2Si 析出相變化。觀察V-t 曲線，經輥軋
後的試片在第二階段時電壓較高而第三階段所消耗能量較低，因此陽極孔洞數量
少而孔徑較大。觀察陽極皮膜的成份分析，因為輥軋變形後基地中產生差排和氫
氣，使氧化鋁膜矽(Si)離子減少，並且影響氫氧化鋁(AlOH)離子增加。X 光電子能
譜分析陽極氧化鋁膜主要由非晶氧化鋁Al-O-H 與水合氧化鋁Al(OH)3所組成。O 1s
部分分析退火材主要由非晶氧化鋁組成和少量Al-O 約10.5 %，O-rolling40%-T4-T6
與O-T4-rolling40%-T6 發現Al-O 增多。觀察Si 2p 部份分析6063 鋁合金陽極皮膜
中成分含有Al2SiO5。

The aim of the study is to investigate the effect of the anodic aluminum oxide film
(AAO film) formed on the 6063 aluminum alloy by using anodizing treatment. Through
the manufacturing process including annealing, artificial ageing treatment and
cold-rolling, the variation of AAO film of 6063 aluminum alloy revealed especially on
its microstructure, the angle of grain boundaries and the status of precipitate materials.
Furthermore, the anodizing was utilized to explore the influence on the AAO film from
the base structure. Also, voltage-time (V-t) curve in the process of anodizing was
recorded. After the above manufacturing process, the effect of the microstructure on the
growing behavior of the porous AAO film was observed by using SEM. In addition, the
SIMS was used to examine element the depth profiles of AAO film in the step 4 of V-t
curve. Then, the XPS was utilized to analyze the composition of AAO film surface in
the step 2 of V-t curve.
As the EBSD results indicated that the grain boundary was at medium/ high angle
present in O, O-T4-T6, O-rolling40%-T4-T6 specimens. In comparison, the main grain
boundary was low angle with O-T4-rolling40%-T6 specimen. Thus, the microstructure
of 6063 aluminum alloy significantly changed during the cold-rolling process. It
affected the Mg2Si precipitate particles, and the phase transformation occurred. In
respect to the variation of V-t curve, the voltage of the test fragment with cold-rolling
process became higher in the step 2. Moreover, the above test fragment consumed less
energy in the step 3. Concerning the cold-rolled 6063 aluminum alloy, therefore, it is
suggested that the decreasing of pore population, and increasing the pore diameter of the
AAO films.
As SIMS analysis, the distribution of Si ion reduced with depth of AAO film, and
AlOH was raised. Consequently, there were several findings from the XPS analysis as
III
following. In the O 1s analysis, the AAO film mainly contains of Al-O-H bonding phase,
Al(OH)3 hydrated oxide and several Al-O bonding phase. O-rolling40%-T4-T6 and
O-T4-rolling40%-T6 obtained higher Al-O bonding phase. Because of the dislocation
and hydrogen were produced in the Al matrix after the cold rolling process. Regarding
with the dimension of Si 2p, it was investigated that the main composition of AAO film
is Al2SiO5.

目錄
中文摘要 I
Abstract II
致謝 IV
目錄 V
圖目錄 VII
表目錄 XI
第一章 前言 1
第二章 理論探討與文獻回顧 2
2-1 鋁合金的簡述 2
2-1-1 鋁合金的類型 2
2-2 鋁合金熱處理簡述 3
2-3 Al-Mg-Si簡介 4
2-4 Al-Mg-Si 合金的析出強化熱處理 6
2-4-1 Al-Mg-Si合金時效分析與析出過程 7
2-4-2 Al-Mg-Si合金兩段時效探討 10
2-4-3 金屬材料再結晶理論與過程 12
2-4-4 Al-Mg-Si合金輥軋(rolling)簡介 13
2-5 陽極處理 16
2-5-1 陽極皮膜種類與成長機制 17
2-5-2 陽極皮膜生成的電壓-時間曲線(V-t curve) 19
2-5-3 Al-Mg-Si合金時效後陽極之影響 22
第三章 實驗方法與步驟 23
3-1 實驗目的 23
3-2 實驗材料及試片準備 23
3-3 實驗儀器 23
3-4 實驗步驟 24
第四章 結果與討論 29
4-1 熱處理與輥軋變形的分析 29
4-1-1 6063-O微結構分析 29
4-1-2 6063-O-T4-T6微結構分析 36
4-1-3 退火-輥軋-T4-T6與退火-T4-輥軋-T6 微結構分析 39
4-1-4 6063鋁合金微結構綜論 46
4-2 陽極皮膜性質分析 47
4-2-1 二次離子質譜儀(SIMS)分析陽極皮膜 55
4-2-2 陽極皮膜X射線光電子能譜(XPS)分析 60
4-2-3 陽極皮膜色澤的變化 67
第五章 結論 68
參考文獻 69
附錄 76

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